Method and device for cooling a synthesis gas flow

Patent metadata

Field	Value
Publication number	US-11925895-B2
Application number	US-201917259763-A
Country	US
Kind code	B2
Filing date	Jul 4, 2019
Priority date	Jul 19, 2018
Publication date	Mar 12, 2024
Grant date	Mar 12, 2024

Abstract

The invention relates to a method and to a device for performing a process (P) having at least one heat-consuming process step (F). A first fluid (2), which arises in the process and contains acid gases and water vapor, is cooled indirectly against a second fluid (7), an acidic condensate thus being formed. The invention is characterized in that the first fluid (2) is cooled in at least two successive steps (E1, E2), between which heat for use in the heat-consuming process step (V) is indirectly drawn from the second fluid (10).

First claim

The invention claimed is:

1. A method for performing a process comprising:
at least one heat-consuming process step, wherein a first fluid, which arises in the process and contains acid gases and water vapor, is cooled indirectly against a second fluid thus forming an acidic condensate,
wherein the indirect cooling of the first fluid is performed in at least two successive steps, between which heat for use in the at least one heat-consuming process step is indirectly withdrawn from the second fluid.

2. The method according to claim 1 , wherein a chemically neutral fluid is used as said second fluid and heat intended for use in the at least one heat-consuming process step is transferred to a chemically neutral medium.

3. The method according to claim 1 , wherein the process is a synthesis gas generation process in which a carbon-containing feedstock is thermochemically converted, in order to obtain a raw synthesis gas containing water vapor and acid gases as said first fluid, which is cooled in the at least one heat-consuming process step against demineralized water as said second fluid to obtain export steam.

4. The method according to claim 3 , wherein, in the at least one heat-consuming process step, heat is withdrawn from the demineralized water between said at least two successive steps for cooling said first fluid, and the heat withdrawn from the demineralized water is used to produce stripping steam, which is used for degassing demineralized water.

5. The method according to claim 3 , wherein, in the at least one heat-consuming process step, heat is withdrawn from the demineralized water between said at least two successive steps for cooling the first fluid, and the heat withdrawn from the demineralized water is used to produce stripping steam which is used for degassing process condensate.

6. The method according to claim 3 , wherein, in the at least one heat-consuming process step, heat is withdrawn from the demineralized water between said at least two successive steps for cooling said first fluid, and the heat withdrawn from the demineralized water is used to produce stripping steam, which is used for degassing demineralized water and for degassing of process condensate.

7. The method according to claim 3 , wherein, in the at least one heat-consuming process step, heat is withdrawn from the demineralized water in an intercooler between said at least two successive steps for cooling said first fluid, wherein the intercooler is arranged in a sump chamber of a degasifier for degassing mineralized water, so that degassed demineralized water accumulating in the sump chamber can be converted into stripping steam by heat exchange with the demineralized water to be cooled in the intercooler, and said stripping steam is used for degassing demineralized water in said gasifier.

8. The method according to claim 3 , wherein, in the at least one heat-consuming process step, heat is withdrawn from the demineralized water in an intercooler between said at least two successive steps for cooling said first fluid, wherein the intercooler is arranged in a sump chamber of a degasifier for degassing mineralized water, and degassed demineralized water accumulating in the sump chamber can be converted into stripping steam and at least part of the stripping steam is used for degassing of process condensate.

9. The method according to claim 3 , wherein, in the at least one heat-consuming process step, heat is withdrawn from the demineralized water in an intercooler between said at least two successive steps for cooling said first fluid, wherein the intercooler is arranged in a sump chamber of a degasifier for degassing mineralized water, so that degassed demineralized water accumulating in the sump chamber can be converted into stripping steam by heat exchange with the demineralized water to be cooled in the intercooler, and at least part of the stripping steam is used for degassing process condensate.

10. A device for performing a process comprising at least one heat-consuming process step (F), said device comprising:
a cooling device by means of which a first fluid that arises in the process and contains acid gases and water vapor can be cooled indirectly against a second fluid thus forming an acidic condensate
wherein the cooling device comprises two cooling stages arranged in series and each of which allowing passage of the first and second fluids therethrough, between which a heat exchanger, referred to as an intercooler, is arranged, via which heat can be indirectly drawn from the second fluid and supplied to the at least one heat-consuming process step.

11. The device according to claim 10 , wherein said device is suitable for performing a synthesis gas generation, in which a carbon-containing feedstock can be thermochemically converted in order to obtain as said first fluid a raw synthesis gas containing the acid gases and water vapor, which said first fluid can be cooled against demineralized water as said second fluid in the cooling device to obtain export steam from the at least one heat-consuming process step.

12. The device according to claim 11 , wherein the cooling device further comprises a degasifier for degassing demineralized water provided for export steam production, wherein the intercooler is arranged in a sump chamber of the degasifier, so that degassed demineralized water accumulating in the sump chamber can be converted against the demineralized water to be cooled in the intercooler into stripping steam for degassing the demineralized water for export steam production.

13. The device according to claim 11 , further comprising a fractionating column by means of which the acidic condensate formed during cooling of the raw synthesis gas can be degassed using stripping steam before the acidic condensate is further processed to process steam, wherein the fractionating column is fluidically connected to a sump chamber of a degasifier, so that demineralized water vapor generated in the sump chamber from degassed demineralized water can be introduced as the stripping steam into the fractionating column.

14. The device according to claim 11 , wherein the cooling device further comprises a degasifier for degassing demineralized water, said degasifier comprising a sump chamber and a fractionating column for degassing the acidic condensate formed during cooling of the raw synthesis gas, wherein the intercooler is arranged in said sump chamber of the degasifier, and wherein degassed demineralized water accumulating in the sump chamber is heated, by heat exchange against the demineralized water to be cooled in the intercooler, and converted into stripping steam which is used for degassing demineralized water and for degassing the acidic condensate.

Assignees

• Linde Gmbh

Inventors

• Lang Martin
• Hirsch Alexander

Classifications

• B01D53/002 Primary

  by condensation · CPC title

• B01D19/0015

  in contact columns containing plates, grids or other filling elements · CPC title

• B01D19/0036

  Flash degasification (the other groups take precedence) · CPC title

• C01B3/02

  Production of hydrogen; Production of gaseous mixtures containing hydrogen · CPC title

• C10K1/003

  of acid contaminants, e.g. acid gas removal · CPC title