Filter media and system using the same

Patent metadata

Field	Value
Publication number	US-11921046-B2
Application number	US-202017008290-A
Country	US
Kind code	B2
Filing date	Aug 31, 2020
Priority date	Aug 31, 2020
Publication date	Mar 5, 2024
Grant date	Mar 5, 2024

Abstract

In some examples, a method of making a filter includes heating a metal substrate to precipitate a first phase on a surface of the metal substrate from a metal alloy, the metal substrate defining a plurality of apertures configured to allow a gas to pass through the apertures. The metal substrate is the metal alloy including a first metal and a second metal. The method further includes growing a plurality of carbon nanotubes (CNTs) on the surface of the first metal of the first phase, and the CNTs are configured to capture at least one particle.

First claim

What is claimed is:

1. A method of making a filter, the method comprising:
heating a metal substrate comprising a metal alloy to precipitate a first phase out from a second phase on a surface of the metal substrate, wherein the metal substrate defines a plurality of apertures configured to allow a gas to pass through the apertures, wherein the metal substrate comprises the metal alloy, wherein the metal alloy comprises a first metal and a second metal, wherein the first phase comprises a gamma prime phase of nickel or cobalt, wherein the gamma prime phase of the nickel or the cobalt is part of a structure of the metal substrate; and
growing a plurality of carbon nanotubes (CNTs) on the surface of the first metal of the first phase, wherein the CNTs are configured to capture at least one particle.

2. The method of claim 1 , further comprising etching, following the heating, the metal substrate to remove the second metal from the first phase.

3. The method of claim 2 , wherein the first metal comprises one of nickel and cobalt.

4. The method of claim 2 , wherein the metal substrate comprises one of a two-dimensional (2D) metallic mesh, a 2D metallic open cell foam, and a three-dimensional (3D) metallic open cell foam.

5. The method of claim 1 , wherein the metal substrate is configured to allow the gas to pass through the apertures substantially without a pressure difference from one side of the filter relative to the other side of the filter.

6. The method of claim 2 , wherein the metal alloy comprises a nickel aluminum alloy and the first metal is nickel and the second metal is aluminum,
wherein the first phase is a gamma prime phase of the nickel aluminum alloy,
wherein etching the metal substrate comprises chemically etching the metal substrate to remove the aluminum from the gamma prime phase leaving nickel as an active site for the CNT
wherein growing the plurality of CNTs comprises growing the plurality of CNTs via chemical vapor deposition.

7. The method of claim 6 , wherein the CNTs define a plurality of apertures within a range from 5 nm to 500 nm.

8. The method of claim 1 , wherein heating the metal substrate precipitates the first phase in a predetermined spatial pattern, the predetermined spatial pattern comprising a plurality of regions of the first phase, wherein a spacing between each of the plurality of regions comprising the first phase is between from about 10 nm to about 500 nm and is less than a spacing between adjacent apertures of the plurality of apertures, wherein the first phase is configured to catalyze growth of the plurality of CNTs.

9. The method of claim 8 , wherein the predetermined spatial pattern comprises a plurality of substantially rectangular regions comprising the first phase, wherein the plurality of substantially rectangular regions comprising the first phase are distributed on the surface of the metal substrate substantially uniformly.

10. The method of claim 9 , wherein a spacing between each of the plurality of substantially rectangular regions comprising the first phase is between from about 10 nm to about 500 nm.

11. A filter comprising:
a metal substrate defining a plurality of apertures configured to allow a gas to pass through the apertures, the metal substrate comprising a metal alloy, the metal alloy comprising a first metal and a second metal; and
a plurality of carbon nanotubes (CNTs) grown on a surface of a first phase precipitated out from a second phase of the metal alloy, the plurality of carbon nanotubes configured to capture at least one particle contained in the gas passing through the metal substrate,
wherein the first phase comprises a gamma prime phase of nickel or cobalt, wherein the gamma prime phase of the nickel or the cobalt is part of a structure of the metal substrate.

12. The filter of claim 11 , wherein the first phase is precipitated from the metal alloy in a predetermined spatial pattern, the predetermined spatial pattern comprising a plurality of regions of the first phase, wherein a spacing between each of the plurality of regions comprising the first phase is between from about 10 nm to about 500 nm and is less than a spacing between adjacent apertures of the plurality of apertures, wherein the first phase is configured to catalyze growth of the plurality of CNTs.

13. The filter of claim 12 , wherein the predetermined spatial pattern comprises a plurality of substantially rectangular regions comprising the first phase, wherein the plurality of substantially rectangular regions comprising the first phase are distributed on a surface of the metal substrate substantially uniformly, wherein a spacing between each of the plurality of substantially rectangular regions comprising the first phase is between from about 10 nm to about 500 nm.

14. The filter of claim 11 , wherein the CNTs define a plurality of apertures within a range from 5 nm to 500 nm.

15. The filter of claim 11 , wherein the first metal comprises one of nickel and cobalt.

16. The filter of claim 11 , wherein the metal substrate comprises one of a two-dimensional (2D) metallic mesh, a 2D metallic open cell foam comprising a 2D metallic mesh extended in a direction perpendicular to a 2D area defined by the 2D metallic mesh, and a three-dimensional (3D) metallic open cell foam.

17. The filter of claim 11 , wherein the metal substrate is configured to allow the gas to pass through the apertures substantially without a pressure difference from one side of the filter relative to another side of the filter.

18. A method of detecting a pathogen, the method comprising:
capturing a pathogen via a filter from a volume of gas flowing through the filter, the filter comprising:
a metal substrate defining a plurality of apertures configured to allow the gas to pass through the apertures, the metal substrate comprising a metal alloy, the metal alloy comprising a first metal and a second metal; and
a plurality of carbon nanotubes on a surface of a first phase precipitated out from a second phase of the of the metal alloy, the plurality of carbon nanotubes configured to capture a pathogen,
wherein the first phase comprises a gamma prime phase of nickel or cobalt, wherein the gamma prime phase of the nickel or the cobalt is part of a structure of the metal substrate; and
detecting, via a detector, the at least one pathogen captured by the filter.

19. The method of claim 18 , wherein the metal substrate is configured to allow the gas to pass through the apertures substantially without a pressure difference from one side of the filter relative to the other side of the filter.

20. The method of claim 19 , further comprising:
heating the metal substrate so as to destroy the pathogen captured by the filter.

Assignees

• Honeywell Int Inc

Inventors

• Rateick Jr Richard George
• Evans Christopher
• Jadidian Bahram
• Mohajeri Mahdi
• Mehr Mehrad

Classifications

• G01N21/65 Primary

  Raman scattering · CPC title

• B01D39/2051

  Metallic foam · CPC title

• G01J3/0229

  using masks, aperture plates, spatial light modulators or spatial filters, e.g. reflective filters · CPC title

• G01J3/44

  Raman spectrometry; Scattering spectrometry {; Fluorescence spectrometry} · CPC title

• B01D2239/025

  comprising nanofibres · CPC title