Method for dissolving metals by photocatalysis

Patent metadata

Field	Value
Publication number	US-11920212-B2
Application number	US-201917042775-A
Country	US
Kind code	B2
Filing date	Oct 10, 2019
Priority date	Apr 12, 2019
Publication date	Mar 5, 2024
Grant date	Mar 5, 2024

Abstract

The present invention relates to a method for dissolving metals by photocatalysis. A metal-containing material to be dissolved is dispersed in a mixed solution of photocatalyst-containing cyanide and organic chloride; then, a photocatalyst is added; next, an oxygen-containing gas or a substance which is capable of generating oxygen is introduced; and irradiation is applied for a period of time to dissolve metals. Compared with the prior method, the present invention is advantageous in moderate reaction condition, energy conservation, environmental protection, low cost, and convenient operation, and is suitable for mass industrial treatment on metal dissolution.

First claim

What is claimed is:

1. A method for dissolving metals by photocatalysis, characterized in that the method comprises steps of dispersing a metal-containing material to be dissolved in a mixed solution of photocatalyst-containing cyanide and organic chloride, and performing irradiation for a period of time to dissolve metals.

2. The method for dissolving metals by photocatalysis according to claim 1 , wherein the metals contained in the metal-containing material to be dissolved comprise a noble metal.

3. The method for dissolving metals by photocatalysis according to claim 2 , wherein the noble metal comprises one or several ones of ruthenium, rhodium, iridium, gold, silver, platinum and palladium.

4. The method for dissolving metals by photocatalysis according to claim 1 , wherein a photocatalyst of the mixed solution of photocatalyst-containing cyanide and organic chloride comprises organic, inorganic and semiconductor photocatalytic materials and their modified, surface finished and mutually compounded photocatalytic materials.

5. The method for dissolving metals by photocatalysis according to claim 4 , wherein the organic photocatalytic materials comprise carbon nitride, PDI, porphyrin or enzyme; the inorganic photocatalytic materials comprise titanium dioxide, zinc oxide, copper oxide, bismuth oxide, ferric oxide, gallium oxide, molybdenum disulfide, cadmium sulfide, bismuth bromide, indium oxide and tungsten oxide; the semiconductor photocatalytic materials and their modified, surface finished and mutually compounded photocatalytic materials comprise titanium dioxide material with an oxygen vacancy, hydroxyl modified titanium dioxide material, two-dimensional titanium dioxide material, nitrogen doped titanium dioxide material, porphyrin-sensitized titanium dioxide, self-assembled porphyrin material where porphyrin includes protoporphyrin, iron porphyrin, magnesium porphyrin or zinc porphyrin, titanium-dioxide and amino-modified metallic organic compound material, molybdenum disulfide loaded titanium dioxide, cadmium sulfide, cadmium sulfide quantum dot material, in-situ vulcanized tungsten oxide composite material, phosphorus-doped indium oxide material, carbon nitride composite material with nitrogen defects, carbon nitride material modified by carbon material where the carbon material includes carbon dots, graphene or carbon nano-tubes, layered bismuth bromide material, bismuth bromide material with oxygen defects, catalyzing enzyme material, and composite material of organic optical system and an inorganic catalyst.

6. The method for dissolving metals by photocatalysis according to claim 1 , wherein the cyanide comprises one or several ones of acrylonitrile, acetonitrile, phenylacetonitrile, cyanoacetic acid, malononitrile, benzyl cyanide and melamine; and the organic chloride includes one or several ones of dichloromethane, trichlormethane, dichloroethylene, trichloroethane, trichlorethanol and tetrachlormethane.

7. The method for dissolving metals by photocatalysis according to claim 1 , wherein the mass ratio of the cyanide to the organic chloride is (10-10000):(0-1000).

8. The method for dissolving metals by photocatalysis according to claim 1 , wherein the content of a photocatalyst in the mixed solution is (0.25-4) mg/mL, and the mass ratio of the metal-containing material to be dissolved to the photocatalyst is 1:(0.1-0.4).

9. The method for dissolving metals by photocatalysis according to claim 1 , wherein the light wavelength of the irradiation is 150-1500 nm, covering deep ultraviolet light, ultraviolet light, visible light and near infrared light; and the irradiation time is 4-8 h.

10. The method for dissolving metals by photocatalysis according to claim 1 , wherein an oxygen-containing gas or a chemical substance which can generate oxygen is introduced into the mixed solution in the dissolution process, such that the oxygen content in the mixed solution reaches 5%-100%; and the chemical substance which is capable of generating oxygen comprises one or several ones of ozone, hydrogen peroxide and sodium peroxide.

11. The method for dissolving metals by photocatalysis according to claim 1 , wherein the metals contained in the metal-containing material to be dissolved comprises a metal selected from the group consisting of iron, manganese, chromium, zinc, tin, lead, aluminum, copper, nickel, or cobalt, or a combination thereof.

12. The method for dissolving metals by photocatalysis according to claim 1 , wherein the photocatalyst includes an organic or inorganic semiconductor photocatalytic material, a modified semiconductor photocatalytic material, or a surface modified semiconductor photocatalytic material.

Assignees

• Univ Shanghai

Inventors

• Bian Zhenfeng
• Chen Yao
• Xu Mengjiao
• Lin Lili
• Wen Jieya
• Wan Yu
• Liu Li
• Li Hexing

Classifications

• B01J35/20

  characterised by their non-solid state · CPC title

• C22B3/16 Primary

  in organic solutions · CPC title

• B01J21/063

  Titanium; Oxides or hydroxides thereof · CPC title

• B01J35/004

  Operations & Transport · mapped topic

• C22B11/04 Primary

  by wet processes (extraction of metal compounds by leaching in organic solutions C22B3/16; treatment or purification of solutions by liquid-liquid extraction C22B3/26) · CPC title