Mesophase pitch for carbon fiber production using supercritical carbon dioxide
US-2020299588-A1 · Sep 24, 2020 · US
US11920099B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-11920099-B2 |
| Application number | US-202117534165-A |
| Country | US |
| Kind code | B2 |
| Filing date | Nov 23, 2021 |
| Priority date | Nov 23, 2021 |
| Publication date | Mar 5, 2024 |
| Grant date | Mar 5, 2024 |
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Systems and methods for production for consistently sized and shaped petroleum coke from vacuum residue, one method including supplying processed vacuum residue to an extruder; heating the processed vacuum residue throughout a horizontal profile of the extruder from an inlet to an outlet of the extruder; venting hydrocarbon off-gases from the extruder along the horizontal profile of the extruder from the inlet to the outlet of the extruder; and cutting consistently sized and shaped petroleum coke at the outlet of the extruder.
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The invention claimed is: 1. A method of production for consistently sized and shaped petroleum coke from vacuum residue, the method comprising the steps of: fractionating vacuum residue in a coker fractionator, where the vacuum residue is produced in a vacuum distillation column at a temperature between about 430° C. to about 450° C. and a pressure of about 0.1 kPa, where fractionating the vacuum residue removes liquid propane gas, fuel gas, coker naphtha, light coker gas oil, and heavy coker gas oil to produce a processed vacuum reside, where the coker fractionator operates at a pressure between 1 psig to 50 psig and a temperature in a fractionator flash zone between 650° F. and 950° F.; supplying the processed vacuum residue to an extruder; heating the processed vacuum residue throughout a horizontal profile of the extruder from an inlet to an outlet of the extruder, wherein a temperature along the horizontal profile is between about 350° C. and about 450° C. and a pressure along the horizontal profile is 0.1 kPa and is consistent; venting hydrocarbon off-gases from the extruder along the horizontal profile of the extruder from the inlet to the outlet of the extruder; and recycling the hydrocarbon off-gases to the coker fractionator; and cutting consistently sized and shaped petroleum coke at the outlet of the extruder comprises the use of an automatically timed blade to cut the consistently sized and shaped petroleum coke. 2. The method according to claim 1 , wherein the method is carried out without the application of steam, hydrogen, or water. 3. The method according to claim 1 , where the step of venting is carried out in multiple stages along the horizontal profile of the extruder from the inlet to the outlet of the extruder. 4. The method according to claim 1 , wherein the speed of the automatically timed blade is adjusted based on rotational speed of an extrusion screw in the extruder and residence time of the processed vacuum residue in the extruder. 5. The method according to claim 1 , wherein the extruder includes an extrusion screw in an annulus, the extrusion screw selected from the group consisting of: a cylindrically-shaped extrusion screw and a conically-shaped extrusion screw. 6. The method according to claim 1 , wherein the step of heating the processed vacuum residue throughout a horizontal profile of the extruder from an inlet to an outlet of the extruder comprises a series of variable temperature heaters external to the extruder disposed along the horizontal profile of the extruder. 7. The method according to claim 1 , wherein the consistently sized and shaped petroleum coke is substantially circular in the cross section with a consistent depth and in the form of a puck shape. 8. The method according to claim 1 , wherein the steps of heating and venting require no vacuum or vacuum distillation and wherein coking reactions take place along the entire horizontal profile from the inlet to the outlet of the extruder. 9. The method according to claim 1 , wherein the method does not require the application of chemical additives during processing. 10. The method of claim 1 , wherein coking reactions occur along the entire horizontal profile of the extruder from the inlet to the outlet of the extruder.
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