Heat storage in chemical reactors

Patent metadata

Field	Value
Publication number	US-11920078-B2
Application number	US-202017100708-A
Country	US
Kind code	B2
Filing date	Nov 20, 2020
Priority date	Nov 20, 2019
Publication date	Mar 5, 2024
Grant date	Mar 5, 2024

Abstract

A process for producing olefins may include dehydrogenating a first alkane in a first reactor to produce a first effluent comprising at least one of a first n-olefin or a first diolefin; removing the first effluent from the first reactor; and regenerating the first reactor. The first reactor may include a first dehydrogenation catalyst and a first phase change material.

First claim

What is claimed is:

1. A process for producing olefins, the process comprising:
dehydrogenating a first alkane in a first reactor to produce a first effluent comprising at least one of a first n-olefin or a first diolefin;
removing the first effluent from the first reactor; and
regenerating the first reactor,
wherein the first reactor comprises a fixed bed reaction zone containing first dehydrogenation catalyst particles disposed around sealed containers housing a first phase change material, wherein the sealed containers comprise sealed tubes that are spaced apart and arranged in a grid pattern within the fixed bed reaction zone; and
wherein the dehydrogenation of the first alkane results in the temperature of the first phase change material to drop such that the first phase change material undergoes a phase transition.

2. The process of claim 1 , wherein the phase transition of the first phase change material provides thermal energy to the first dehydrogenation catalyst that is sufficient to maintain the dehydrogenation of the first alkane.

3. The process of claim 1 , wherein the dehydrogenation of the first alkane is performed for at least 1.2 times the duration of the regeneration of the first reactor.

4. The process of claim 1 , wherein the first reactor contains the first phase change material in an amount of 5 to 30 wt. %, relative to the total weight of the dehydrogenation catalyst.

5. The process of claim 1 , wherein the first reactor contains the first phase change material in an amount of 5 to 30 vol. %, relative to the total volume of the dehydrogenation catalyst.

6. The process of claim 1 , wherein the first phase change material undergoes a phase transition at a temperature of 600° C. or more and 620° C. or less.

7. The process of claim 1 , wherein the first alkane is one of the group consisting of propane, butane, and isobutane.

8. The process of claim 1 , wherein the first phase change material comprises barium chloride and calcium chloride.

9. The process of claim 1 , further comprising:
dehydrogenating a second alkane in a second reactor to produce a second effluent comprising at least one of a second n-olefin or a second diolefin,
removing the second effluent from the second reactor; and
regenerating the second reactor,
wherein the second reactor comprises a fixed bed reaction zone containing particles of a second dehydrogenation catalyst disposed around sealed containers housing a second phase change material, wherein the sealed containers are spaced apart within the second reactor fixed bed reaction zone and wherein the particles of second dehydrogenation catalyst fill a space between the sealed containers;
wherein the second alkane is different from the first alkane; and
wherein the dehydrogenation of the second alkane results in the temperature of the second phase change material to drop such that the second phase change material undergoes a phase transition.

10. The process of claim 9 , wherein the second phase change material has a phase transition temperature different from that of the first phase change material.

11. The process of claim 1 , wherein the sealed tubes comprise sealed cylindrical tubes.

12. A process for producing olefins, the process comprising:
dehydrogenating a first alkane in a first reactor to produce a first effluent comprising at least one of a first n-olefin or a first diolefin;
removing the first effluent from the first reactor; and
regenerating the first reactor,
wherein the first reactor comprises a first dehydrogenation catalyst particles and a first phase change material, wherein the first phase change material comprises barium chloride and calcium chloride; and
wherein the dehydrogenation of the first alkane results in the temperature of the first phase change material to drop such that the first phase change material undergoes a phase transition.

13. The process of claim 12 , wherein the first reactor contains the first phase change material in an amount of 5 to 30 wt. %, relative to the total weight of the dehydrogenation catalyst.

14. The process of claim 12 , wherein the first reactor contains the first phase change material in an amount of 5 to 30 vol. %, relative to the total volume of the dehydrogenation catalyst.

15. The process of claim 12 , wherein the first phase change material undergoes a phase transition at a temperature of 600° C. or more and 620° C. or less.

16. The process of claim 12 , wherein the first alkane is one of the group consisting of propane, butane, and isobutane.

17. A process for producing olefins, the process comprising:
dehydrogenating a first alkane in a first reactor to produce a first effluent comprising at least one of a first n-olefin or a first diolefin;
removing the first effluent from the first reactor; and
regenerating the first reactor,
wherein the first reactor comprises a fixed bed reaction zone containing first dehydrogenation catalyst particles disposed around sealed containers housing a first phase change material, wherein the sealed containers are spaced apart and arranged in a grid pattern within the fixed bed reaction zone; and
wherein the dehydrogenation of the first alkane results in the temperature of the first phase change material to drop such that the first phase change material undergoes a phase transition.

Assignees

• Lummus Technology Inc

Inventors

• Podrebarac Gary George

Classifications

• C09K5/063 Primary

  Materials absorbing or liberating heat during crystallisation; Heat storage materials · CPC title

• C01F11/24

  Chlorides · CPC title

• C07C5/333

  Catalytic processes · CPC title

• C07C9/08

  Propane · CPC title

• C07C9/12

  Iso-butane · CPC title