Method of preparing superabsorbent polymer

Patent metadata

Field	Value
Publication number	US-11918978-B2
Application number	US-201916982292-A
Country	US
Kind code	B2
Filing date	Dec 10, 2019
Priority date	Dec 10, 2018
Publication date	Mar 5, 2024
Grant date	Mar 5, 2024

Abstract

Provided is a method of preparing a superabsorbent polymer. More specifically, provided is a method of preparing a superabsorbent polymer capable of exhibiting improved initial absorbency and a rapid absorption rate by polymerizing monomers having acidic groups, of which part is neutralized with a basic material including potassium hydroxide, in the presence of an encapsulated foaming agent.

First claim

The invention claimed is:

1. A method of preparing a superabsorbent polymer, comprising:
preparing a monomer composition by mixing water-soluble ethylenically unsaturated monomers comprising (meth)acrylic acid with a basic material comprising potassium hydroxide, an encapsulated foaming agent, an internal crosslinking agent, and a polymerization initiator, wherein at least part of the acidic groups of the water-soluble ethylenically unsaturated monomers is neutralized with the basic material comprising potassium hydroxide;
forming a water-containing gel polymer by performing thermal polymerization or photo-polymerization of the monomer composition;
forming a base polymer in the form of powder by drying and pulverizing the water-containing gel polymer; and
forming a surface-crosslinked layer by additionally crosslinking a surface of the base polymer in the presence of a surface crosslinking agent,
wherein the encapsulated foaming agent has a structure including a core which contains a hydrocarbon and a shell which surrounds the core and is formed using a thermoplastic resin, and has a mean diameter of 5 μm to 30 μm before expansion and a maximum expansion ratio of 5 times to 15 times in air.

2. The method of preparing a superabsorbent polymer of claim 1 ,
wherein the basic material comprises 50 mol % to 100 mol % of potassium hydroxide and 0 mol % to 50 mol % of sodium hydroxide.

3. The method of preparing a superabsorbent polymer of claim 1 ,
wherein the basic material is used in an amount of 0.5 mole to 0.9 mole with respect to 1 mole of the water-soluble ethylenically unsaturated monomer.

4. The method of preparing a superabsorbent polymer of claim 1 ,
wherein a pH of the monomer composition is 5 to 6.

5. The method of preparing a superabsorbent polymer of claim 1 ,
wherein the encapsulated foaming agent has a maximum expansion size of 20 μm to 190 μm in air.

6. The method of preparing a superabsorbent polymer of claim 1 ,
wherein the encapsulated foaming agent has a foaming start temperature (T start ) of 60° C. to 120° C., and a maximum foaming temperature (T max ) of 100° C. to 160° C.

7. The method of preparing a superabsorbent polymer of claim 1 ,
wherein the hydrocarbon is one or more selected from the group consisting of n-propane, n-butane, iso-butane, cyclobutane, n-pentane, iso-pentane, cyclopentane, n-hexane, iso-hexane, cyclohexane, n-heptane, iso-heptane, cycloheptane, n-octane, iso-octane, and cyclooctane.

8. The method of preparing a superabsorbent polymer of claim 1 ,
wherein the thermoplastic resin is a polymer formed from one or more monomers selected from the group consisting of (meth)acrylate, (meth)acrylonitrile, aromatic vinyl, vinyl acetate, vinyl halide, and vinylidene halide.

9. The method of preparing a superabsorbent polymer of claim 1 ,
wherein the encapsulated foaming agent is used in an amount of 0.01 parts by weight to 1.0 parts by weight with respect to 100 parts by weight of the water-soluble ethylenically unsaturated monomer.

10. The method of preparing a superabsorbent polymer of claim 1 ,
wherein the prepared superabsorbent polymer has a 1 min-absorbency of 170 g/g or more, and an absorption rate of 22 sec or less, measured by a vortex method.

Assignees

• Lg Chemical Ltd

Inventors

• Lee Seul Ah
• Kim Gicheul
• Nam Dae Woo
• Kim Ki Hyun
• Kim Jun Kyu
• Hur Young Jae

Classifications

• B01J20/261 Primary

  obtained by reactions only involving carbon to carbon unsaturated bonds (macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds per se C08F) · CPC title

• C08F2/44

  Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers · CPC title

• C08F220/06

  Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof · CPC title

• C08J3/12

  Powdering or granulating · CPC title

• C08J9/14

  organic · CPC title