Installation and method for supplying a fuel cell with hydrogen

Patent metadata

Field	Value
Publication number	US-11916267-B2
Application number	US-202117212680-A
Country	US
Kind code	B2
Filing date	Mar 25, 2021
Priority date	Mar 25, 2020
Publication date	Feb 27, 2024
Grant date	Feb 27, 2024

Abstract

An installation for supplying a fuel cell with hydrogen comprising a fuel cell, a liquefied hydrogen storage facility and a supply circuit that includes at least one upstream end connected to the storage facility and one downstream end connected to a fuel inlet of the fuel cell, the supply circuit including at least one system for heating hydrogen by heat exchange with a heat source and a set of control valves, the liquefied hydrogen storage facility being configured to keep the liquefied hydrogen in equilibrium with a gaseous phase at a determined nominal storage pressure of between 1.5 and 4.5 bar, the supply circuit including a buffer tank for pressurized gaseous hydrogen which is configured to store the hydrogen withdrawn from the storage facility and heated by the heating system, the set of valves being configured to accumulate pressurized gas in the buffer tank at a determined storage pressure of between 4 and 100 bar, for example between 6 and 8 bar.

First claim

What is claimed is:

1. A method for supplying a fuel cell with hydrogen using an installation for supplying the fuel cell with hydrogen, the installation comprising:
the fuel cell,
a liquefied hydrogen storage tank; and
a supply circuit comprising at least one upstream end connected to the liquefied hydrogen storage tank and one downstream end connected to a fuel inlet of the fuel cell, the supply circuit comprising a set of control valves and a hydrogen heating system configured to heat hydrogen by heat exchange with a heat source, the liquefied hydrogen storage tank being configured to keep the liquefied hydrogen in equilibrium with a gaseous phase at a determined nominal storage pressure of between 1.5 and 4.5 bar,
wherein the hydrogen heating system comprises first heating heat exchanger,
wherein the supply circuit further comprises a liquid withdrawal pipe and a buffer tank for pressurized gaseous hydrogen that is configured to store the hydrogen withdrawn from the storage tank and heated by the hydrogen heating system, the set of control valves being configured to accumulate pressurized gas in the buffer tank at a determined storage pressure of between 4 and 100 bar, the liquid withdrawal pipe connecting a lower portion of the storage tank to the fuel inlet of the fuel cell, the liquid withdrawal pipe comprising, arranged in series, the first heating heat exchanger and a first pressure- and/or flow rate-regulating valve, said first pressure- and/or flow rate-regulating valve being configured to feed the fuel inlet of the fuel cell at a determined operating pressure of between 1 and 3 bar wherein the fuel cell is fed with hydrogen by the storage tank,
the method comprising a step of transferring hydrogen from the storage tank to the buffer tank.

2. The method of claim 1 , wherein the step of transferring hydrogen from the storage tank to the buffer tank is performed during an interruption to the feeding of the fuel cell with hydrogen by the storage tank.

3. The method of claim 1 , wherein the step of transferring hydrogen from the storage tank to the buffer tank is performed during a shutdown of the fuel cell.

4. The method of claim 1 , further comprising, during the operation of the fuel cell, a step of detecting a fault in the feeding of the fuel cell with hydrogen by the storage tank and, in response, a step of backup feeding in which the fuel cell is fed with hydrogen by the buffer tank.

5. The method of claim 1 , wherein the supply circuit further comprises a gas withdrawal pipe connecting an upper portion of the storage tank to an inlet of the buffer tank.

6. The method of claim 5 , wherein the hydrogen heating system further comprises a second heating heat exchanger that is in fluid communication with the gas withdrawal pipe and is configured to heat gaseous hydrogen, wherein the has withdrawal pipe comprises, arranged in series, the second heating heat exchanger and a second pressure- and/or flow rate-regulating valve, said second pressure- and/or flow rate-regulating valve being configured to transfer gas at the storage pressure into the buffer tank.

7. The method of claim 6 , wherein the second pressure- and/or flow rate-regulating valve is configured to automatically transfer gas from the storage tank to the buffer tank only when the pressure in the storage tank exceeds a determined pressure threshold.

8. The method of claim 5 , wherein the supply circuit further comprises a set of isolation valves arranged at the inlet and the outlet of the buffer tank, the hydrogen heating system comprising an exchange of heat between the fluid contained in the buffer tank and a heat source such as the atmosphere for vaporizing and increasing the pressure of the fluid in the buffer tank when the isolation valves are closed, the supply circuit furthermore comprising an element for limiting the pressure in said buffer tank such as a discharge valve which opens above a determined pressure threshold.

9. The method of claim 8 , wherein the heat source is the atmosphere.

10. The method of claim 5 , wherein the supply circuit further comprises a backup feed pipe connecting an outlet of the buffer tank to the fuel inlet of the fuel cell, the backup feed pipe comprising at least one fourth pressure- and/or flow rate-regulating valve configured to provide gas at a determined pressure to the fuel cell and, arranged in series, a valve shutter, the first heating heat exchanger, and a pressure-sensitive safety valve for discharging the gas to the outside of the supply circuit in the event of pressure above a safety threshold.

11. The method of claim 10 , wherein the backup feed pipe is connected to the fuel inlet of the fuel cell via a connection to a portion of the liquid withdrawal pipe.

12. The method of claim 1 , wherein the supply circuit further comprises a gas filling pipe having an upstream end connected to an outlet of the first heating heat exchanger and a downstream end connected to an inlet of the buffer tank, the gas filling pipe comprising a third pressure- and/or flow rate-regulating valve, said third pressure and/or flow rate regulator being configured to transfer gas at the storage pressure into the buffer tank.

13. The method of claim 1 , wherein the supply circuit further comprises a liquid removal pipe having an upstream end connected to the lower portion of the storage tank and a downstream end connected to an inlet of the buffer tank.

14. The method of claim 1 , wherein the supply circuit further comprises a backup feed pipe connecting an outlet of the buffer tank to the fuel inlet of the fuel cell, the backup feed pipe comprising at least one fourth pressure- and/or flow rate-regulating valve configured to provide gas at a determined pressure to then fuel cell.

15. The method of claim 14 , wherein the backup feed pipe is connected to the fuel inlet of the fuel cell via a connection to a portion of the liquid withdrawal pipe.

16. The method of claim 1 , wherein the set of control valves is configured to accumulate pressurized gas in the buffer tank at a determined storage pressure of between 6 and 8 bar.

17. The method of claim 1 , wherein the heating system can be selected from the group consisting of the first heating heat exchanger, a second heating heat exchanger, and combinations thereof.

18. The method of claim 1 , wherein the installation is disposed onboard a vehicle.

19. The method of claim 18 , wherein the vehicle is selected from the group consisting of a boat and a train.

Assignees

• Air Liquide

Inventors

• Allidieres Laurent

Classifications

• H01M8/04089 Primary

  of gaseous reactants · CPC title

• F17C13/025

  having the pressure as the parameter · CPC title

• H01M8/04014

  Heat exchange using gaseous fluids; Heat exchange by combustion of reactants · CPC title

• H01M8/04208 Primary

  Cartridges, cryogenic media or cryogenic reservoirs · CPC title

• H01M8/04753

  of fuel cell reactants · CPC title