Cross-flow interconnect and fuel cell system including same

Patent metadata

Field	Value
Publication number	US-11916263-B2
Application number	US-202217662956-A
Country	US
Kind code	B2
Filing date	May 11, 2022
Priority date	May 31, 2018
Publication date	Feb 27, 2024
Grant date	Feb 27, 2024

Abstract

A cross-flow interconnect and a fuel cell stack including the same, the interconnect including fuel inlets and outlets that extend through the interconnect adjacent to opposing first and second peripheral edges of the interconnect; an air side; and an opposing fuel side. The air side includes an air flow field including air channels that extend in a first direction, from a third peripheral edge of the interconnect to an opposing fourth peripheral edge of the interconnect; and riser seal surfaces disposed on two opposing sides of the air flow field and in which the fuel inlets and outlets are formed. The fuel side includes a fuel flow field including fuel channels that extend in a second direction substantially perpendicular to the first direction, between the fuel inlets and outlets; and a perimeter seal surface surrounding the fuel flow field and the fuel inlets and outlets.

First claim

What is claimed is:

1. A fuel cell stack, comprising:
interconnects stacked over one another;
fuel cells disposed between the interconnects, facing fuel and air flow fields of adjacent interconnects;
a fuel inlet riser at least partially defined by the inlets of the interconnects and configured to provide fuel to the fuel flow fields;
a fuel outlet riser at least partially defined by fuel outlets of the interconnects and configured to receive anode exhaust from the fuel flow fields;
riser seals disposed on a riser seal region of each interconnect and configured to prevent fuel in the fuel inlet and outlet risers from entering the air flow fields; and
perimeter seals disposed on a perimeter seal region of each interconnect and configured to prevent air from entering the fuel flow fields;
wherein the riser and perimeter seals are formed of a seal material comprising, by weight:
SiO 2 in an amount ranging from 35% to about 55%;
B 2 O 3 in an amount ranging from about 0.5% to about 15%;
Al 2 O 3 in an amount ranging from about 0.5% to about 5%;
CaO in an amount ranging from about 5% to about 30%;
MgO in an amount ranging from about 2% to about 25%;
La 2 O 3 in an amount ranging from about 2% to about 12%; and
at least 0.5% of at least one of BaO and SrO.

2. The fuel cell stack of claim 1 , wherein each fuel cell comprises:
an electrolyte disposed between adjacent first and second interconnects;
a cathode covering a first surface of the electrolyte and facing the air flow field of the first interconnect; and
an anode covering an opposing second surface of the electrolyte and facing the fuel flow field of the second interconnect, wherein,
adjacent manifold seals contact portions of the first surface of the electrolyte that are not covered by the cathode, and
each fuel cell further comprises an electrolyte reinforcement layer that extends from the anode and overlaps with the manifold seals in a stacking direction of the interconnects.

3. The fuel cell stack of claim 2 , wherein:
the fuel cells comprise solid oxide fuel cells;
the electrolyte reinforcement layer comprises a ceramic material; and
a coefficient of thermal expansion of the interconnects is within +/−10% of a coefficient of thermal expansion of the fuel cells.

4. The fuel cell stack of claim 1 , wherein the fuel cells are free of through holes.

5. The fuel cell stack of claim 1 , further comprising conductive layers disposed between the fuel cells and adjacent fuel flow fields,
wherein a portion of each conductive layer extends beyond the adjacent flow field and overlaps with an adjacent manifold seal in a stacking direction of the interconnects.

6. The fuel cell stack of claim 1 , wherein the fuel cell stack comprises at least 40 fuel cells and does not comprise an anode splitter plate.

7. The fuel cell stack of claim 1 , further comprising curved ceramic baffle plates disposed on opposing sides of the fuel cell stack that curve around edges of the fuel cell stack.

8. The fuel cell stack of claim 1 , wherein the seal material comprises, by weight:
BaO in an amount ranging from about 0.5% to about 35%;
SrO in an amount ranging from about 0.5% to about 20%; or
BaO in an amount ranging from about 0.5% to about 35% and SrO in an amount ranging from about 0.5% to about 20%.

9. The fuel cell stack of claim 1 , further comprising:
dielectric layers disposed on riser seal surfaces of the interconnects in the riser seal regions; and
a coating layer comprising at least one of lanthanum strontium manganite (LSM) and (Mn, Co) 3 O 4 spinel (MCO) located directly on air channels and ribs in the air flow field but not on the riser seal surfaces of the interconnect.

10. The fuel cell stack of claim 9 , wherein the seal material comprises, by weight:
BaO in an amount ranging from about 20% to about 30%;
SrO in an amount ranging from about 10% to about 20%; or
BaO in an amount ranging from about 20% to about 30% and SrO in an amount ranging from about 10% to about 20%.

11. The fuel cell stack of claim 10 , wherein each dielectric layer comprises an alumina layer formed by atmospheric plasma spray directly on the corresponding riser seal surface of the interconnect and directly on only an edge portion of the coating layer located adjacent to the riser seal surface.

Assignees

• Bloom Energy Corp

Inventors

• Gasda Michael
• Srivatsan Vijay
• Hintz Robert M
• Venkataraman Swaminathan
• Anantha Padiadpu Shankara
• El Batawi Emad
• Lin Cheng-Yu
• Mainkar Sagar
• Richards Gilbert
• Scholl Jonathan

Classifications

• Y02E60/50

  Fuel cells · CPC title

• C23C4/134

  Plasma spraying · CPC title

• H01M8/2483

  characterised by internal manifolds · CPC title

• H01M8/2432

  Grouping of unit cells of planar configuration · CPC title

• H01M8/0273

  with sealing or supporting means in the form of a frame · CPC title