Coated proppants and methods of making and use thereof

Patent metadata

Field	Value
Publication number	US-11912938-B2
Application number	US-202318322668-A
Country	US
Kind code	B2
Filing date	May 24, 2023
Priority date	Aug 6, 2021
Publication date	Feb 27, 2024
Grant date	Feb 27, 2024

Abstract

Coated proppants include a proppant particle, a surface copolymer layer surrounding the proppant particle, and a resin layer surrounding the surface copolymer layer. The surface copolymer layer includes a copolymer of at least two monomers chosen from styrene, methyl methacrylate, ethylene, propylene, butylene, imides, urethanes, sulfones, carbonates, and acrylamides, where the copolymer is crosslinked by divinyl benzene. The resin layer includes a cured resin. Methods of preparing the coated proppants include preparing a first mixture including at least one polymerizable material, an initiator, and a crosslinker including divinyl benzene; contacting the first mixture to a proppant particle to form a polymerization mixture; heating the polymerization mixture to cure the polymerizable material and form a polymer-coated particulate; preparing a second mixture including the polymer-coated substrate, an uncured resin, and a solvent; and adding a curing agent to the second mixture to cure the uncured resin and form the coated proppant.

First claim

What is claimed is:

1. A method of preparing a coated proppant, the method comprising:
preparing a first mixture comprising a polymerizable material, an initiator, and a crosslinker comprising divinyl benzene;
contacting the first mixture to a proppant particle to form a polymerization mixture;
heating the polymerization mixture to cure the polymerizable material and form a polymer-coated proppant particle comprising the proppant particle and a surface copolymer layer crosslinked via divinyl benzene;
preparing a second mixture comprising the polymer-coated substrate and an uncured resin; and
adding a curing agent to the second mixture to cure the uncured resin and form the coated proppant, the coated proppant comprising the proppant particle, the surface copolymer layer surrounding the proppant particle, and a resin layer surrounding the surface copolymer layer, the resin layer comprising a cured resin, and wherein:
the surface copolymer layer has an interpenetrating 3D-crosslinked polymer network structure surrounding the proppant particle;
the coated proppant has a fine production of from 0.1% to 10% at a closure stress of 10,000 psi.

2. The method of claim 1 , wherein:
the polymerizable material comprises at least two monomers chosen from styrene, methyl methacrylate, ethylene, propylene, butylene, imides, urethanes, sulfones, carbonates, and acrylamides;
the initiator comprises 2,2′-Azobis(isobutyronitrile) (AIBN), 4,4′-Azobis(4-cyanovaleric Acid) (ACBA); 1,1′Azobis-(cyclohexanecarbonitrile) (ABCN); 2,2′-Azobis(2,4-dimethyl-4-methoxyvaleronitrile) (V-70); Di-Cert-butylhyponitrite (TBHN), peroxides, or combinations thereof;
the uncured resin is chosen from bisphenol A epoxy resins, bisphenol F epoxy resins, novolac epoxy resins, aliphatic epoxy resins, glycidylamine epoxy resins, and polyepoxide resins;
the proppant particle comprises oxide, silicate, sand, ceramic, resin, plastic, mineral, glass, silica, alumina, fumed carbon, carbon black, graphite, mica, titania, zirconia, boron, fly ash, or combinations thereof; or
combinations thereof.

3. The method of claim 1 , wherein:
the polymerizable material comprises styrene monomer and methyl methacrylate monomer;
the crosslinker comprises divinyl benzene; and
the initiator comprises 2,2′-Azobis(isobutyronitrile) (AIBN).

4. The method of claim 2 , wherein the resin layer further comprises a filler material comprising silica, alumina, mica, graphene, vanadium pentoxide, zinc oxide, calcium carbonate, zirconium oxide, and nano-reinforcing material.

5. The method of claim 4 , wherein the coated proppant has a fine production of from 0.1% to 2.1% at a closure stress of 10,000 psi.

6. The method of claim 2 , wherein the resin layer further comprises a nano-reinforcing material comprising carbon nanotubes, nano silica, nano alumina, nano mica, nanoclay, boron nitride nanotubes, nano vanadium pentoxide, nano zinc oxide, nano calcium carbonate, graphene nanoparticles, graphene oxide nanoparticles, reduced graphene oxide nanoparticles, heat-reduced graphene oxide nanoparticles, hexagonal boron nitride nanoparticles, silver nanoparticles, copper nanoparticles, zirconia nanoparticles, ZrG nanoparticles, ZrG5 nanoparticles, or combinations thereof.

7. The method of claim 6 , wherein the resin layer comprises from 0.01 to 10 wt. % nano-reinforcing material by weight of the resin layer.

8. The method of claim 1 , wherein the coated proppant has:
a hardness from 0.14 to 1 GPa, an elastic modulus from 3.9 to 10 GPa, or both;
a glass transition temperature (T g ) from 84.5° C. to 100° C.;
a degradation temperature (T deg ) from 396° C. to 450° C.; or
combinations thereof.

9. The method of claim 1 , wherein the coated proppant comprises from 0.1 to 20 wt. % divinyl benzene by weight of the surface copolymer layer.

10. The method of claim 1 , wherein the surface copolymer layer, the resin layer, or both further comprise a tracer material comprising thorium dioxide (ThO 2 ), barium sulfate (BaSO 4 ), diatrizoate, metrizoate, iothalamate, ioxaglate, iopamidol, iohexol, ioxilan, iopromide, iodixanol, ioversol, or combinations thereof.

11. A method for increasing a rate of hydrocarbon production from a subsurface formation comprising:
producing a first rate of production of hydrocarbons from the subsurface formation;
introducing a hydraulic fracturing fluid comprising a plurality of coated proppants into the subsurface formation; and
increasing hydrocarbon production from the subsurface formation by producing a second rate of production of hydrocarbons from the subsurface formation, in which the second rate of production of hydrocarbons is greater than the first rate of production of hydrocarbons, and wherein
each of the plurality of coated proppants comprises a proppant particle, a surface copolymer layer surrounding the proppant particle, and a resin layer surrounding the surface copolymer layer,
the surface copolymer layer comprises a copolymer of at least two monomers chosen from styrene, methyl methacrylate, ethylene, propylene, butylene, imides, urethanes, sulfones, carbonates, and acrylamides,
the resin layer comprises a cured resin,
the surface copolymer layer has an interpenetrating 3D-crosslinked polymer network structure crosslinked by divinyl benzene, and
each of the plurality of the coated proppants has a fine production of from 0.1% to 10% at a closure stress of 10,000 psi.

12. The method of claim 11 , wherein:
the polymerizable material comprises at least two monomers chosen from styrene, methyl methacrylate, ethylene, propylene, butylene, imides, urethanes, sulfones, carbonates, and acrylamides;
the initiator comprises 2,2′-Azobis(isobutyronitrile) (AIBN), 4,4′-Azobis(4-cyanovaleric Acid) (ALBA); 1,1′Azobis-(cyclohexanecarbonitrile) (ABCN); 2,2′-Azobis(2,4-dimethyl-4-methoxyvaleronitrile) (V-70); Di-tert-butylhyponitrite (TBHN), peroxides, Or combinations thereof;
the uncured resin is chosen from bisphenol A epoxy resins, bisphenol F epoxy resins, novolac epoxy resins, aliphatic epoxy resins, glycidylamine epoxy resins, and polyepoxide resins;
the proppant particle comprises oxide, silicate, sand, ceramic, resin, plastic, mineral, glass, silica, alumina, fumed carbon, carbon black, graphite, mica, titania, zirconia, boron, fly ash, or combinations thereof; or
combinations thereof.

13. The method of claim 11 , wherein:
the polymerizable material comprises styrene monomer and methyl methacrylate monomer;
the crosslinker comprises divinyl benzene; and
the initiator comprises 2,2′-Azobis(isobutyronitrile) (AIBN).

14. The method of claim 12 , wherein the resin layer further comprises a filler material comprising silica, alumina, mica, graphene, vanadium pentoxide, zinc oxide, calcium carbonate, zirconium oxide, and nano-reinforcing material.

15. The method of claim 14 , wherein the coated proppant has a fine production of from 0.1% to 2.1% at a closure stress of 10,000 psi.

16. The method of claim 12 , wherein the resin layer further comprises a nano-reinforcing material comprising carbon nanotubes, nano silica, nano alumina, nano mica, nanoclay, boron nitride nanotubes, nano vanadium pentoxide, nano zinc oxide, nano calcium carbonate, graphene nanoparticles, graphene oxide nanoparticles, reduced graphene oxide nanoparticles, heat-reduced graphene oxide nanoparticles, hexagonal boron nitride nanoparticles, silver nanoparticles, copper nanoparticles, zirconia nanoparticles, ZrG nanoparticles, ZrG5 nanoparticles, or combinations thereof.

17. The method of claim 16 , wherein the resin layer comp

Assignees

• Saudi Arabian Oil Co
• Alfaisal Univ

Inventors

• Li Wengang
• Alsharaeh Edreese
• Krishnan Mohan Raj

Classifications

• C09K8/805 Primary

  Coated proppants · CPC title

• C09K2208/10

  Nanoparticle-containing well treatment fluids · CPC title

• E21B43/267

  reinforcing fractures by propping · CPC title