Synthetic functionalized additives, methods of synthesizing, and methods of use

Patent metadata

Field	Value
Publication number	US-11912926-B2
Application number	US-202217722779-A
Country	US
Kind code	B2
Filing date	Apr 18, 2022
Priority date	Sep 4, 2018
Publication date	Feb 27, 2024
Grant date	Feb 27, 2024

Abstract

Synthetic functionalized additives may comprise a layered magnesium silicate. The layered magnesium silicate may comprise a first functionalized silicate layer comprising a first tetrahedral silicate layer covalently bonded to at least two different functional groups, an octahedral brucite layer, and a second functionalized silicate layer comprising a second tetrahedral silicate layer covalently bonded to at least two different functional groups. A drilling fluid may comprise the synthetic functionalized additive.

First claim

What is claimed is:

1. A synthetic functionalized additive comprising:
a layered magnesium silicate, the layered magnesium silicate comprising:
a first functionalized silicate layer comprising a first tetrahedral silicate layer covalently bonded to at least two different functional groups,
an octahedral brucite layer, the octahedral brucite layer comprising magnesium, and
a second functionalized silicate layer comprising a second tetrahedral silicate layer covalently bonded to at least two different functional groups,
where the octahedral brucite layer is positioned between the first functionalized silicate layer and the second functionalized silicate layer;
where the at least two different functional groups covalently bonded to the first tetrahedral silicate layer have different chemical structures from one another; and
where the at least two different functional groups covalently bonded to the first tetrahedral silicate layer are the same or different than the at least two different functional groups covalently bonded to the second tetrahedral silicate layer.

2. The synthetic functionalized additive of claim 1 , where a thickness of the layered magnesium silicate is at least 1 nanometer, and where a lateral dimension of the layered magnesium silicate is from 2 nm to 5 microns.

3. The synthetic functionalized additive of claim 1 , where the at least two different functional groups covalently bonded to the first tetrahedral silicate layer, the second tetrahedral silicate layer, or both are selected from the group consisting of hydroxyl groups (—OH), saturated alkyl groups having the formula (—CH 2 (CH 2 ) x CH 3 ), where x is an integer between 0 and 18, phenyl groups, amine groups, diamine groups, carboxylate groups, amide groups, acrylate groups, thiol groups, methacrylate groups, isocyanate groups, and combinations of the same.

4. A drilling fluid comprising:
an aqueous base fluid; and
a synthetic functionalized additive comprising:
a layered magnesium silicate, the layered magnesium silicate comprising:
a first functionalized silicate layer comprising a first tetrahedral silicate layer covalently bonded to at least two different functional groups,
an octahedral brucite layer, the octahedral brucite layer comprising magnesium, and
a second functionalized silicate layer comprising a second tetrahedral silicate layer covalently bonded to at least two different functional groups,
where the octahedral brucite layer is positioned between the first functionalized silicate layer and the second functionalized silicate layer; and
where the at least two different functional groups covalently bonded to the first tetrahedral silicate layer are the same or different than the at least two different functional groups covalently bonded to the second tetrahedral silicate layer.

5. The drilling fluid of claim 4 , further comprising a viscosifier.

6. The drilling fluid of claim 5 , wherein the viscosifier comprises a partially-hydrolyzed polyacrylamide/polyacrylate (PHPA).

7. The drilling fluid of claim 5 , where a ratio of the viscosifier to the synthetic functionalized additive by weight is from 1:5 to 5:1.

8. The drilling fluid of claim 5 , where the drilling fluid comprises from 0.1 wt. % to 5 wt. % of the viscosifier.

9. The drilling fluid of claim 4 , where the drilling fluid comprises from 0.1 wt. % to 10 wt. % of the synthetic functionalized additive.

10. The drilling fluid of claim 4 , where the drilling fluid has a plastic viscosity of greater than 10 cP when measured at 120° F. (48.9° C.) using a FANN® Model 35 viscometer.

11. The drilling fluid of claim 4 , where the drilling fluid has a yield point (YP) of greater than 1 lb/100 ft 2 when measured at 78° F. (25.6° C.) using a FANN® Model 35 viscometer.

12. The drilling fluid of claim 4 , where the drilling fluid has a low shear yield point (LSYP) of greater than 1 lb/100 ft 2 when measured at 78° F. (25.6° C.) using a FANN® Model 35 viscometer.

13. The synthetic functionalized additive of claim 1 , where the at least two different functional groups covalently bonded to the first tetrahedral silicate layer comprise hydroxyl groups (—OH) and amine groups.

14. The synthetic functionalized additive of claim 1 , where the at least two different functional groups covalently bonded to the second tetrahedral silicate layer comprise hydroxyl groups (—OH) and amine groups.

15. The drilling fluid of claim 4 , where a thickness of the layered magnesium silicate is at least 1 nanometer, and where a lateral dimension of the layered magnesium silicate is from 2 nm to 5 microns.

16. The drilling fluid of claim 4 , where the at least two different functional groups covalently bonded to the first tetrahedral silicate layer, the second tetrahedral silicate layer, or both are selected from the group consisting of hydroxyl groups (—OH), saturated alkyl groups having the formula (—CH 2 (CH 2 ) x CH 3 ), where x is an integer between 0 and 18, phenyl groups, amine groups, diamine groups, carboxylate groups, amide groups, acrylate groups, thiol groups, methacrylate groups, isocyanate groups, and combinations of the same.

17. The drilling fluid of claim 4 , where the at least two different functional groups covalently bonded to the first tetrahedral silicate layer are the same as the at least two different functional groups covalently bonded to the second tetrahedral silicate layer.

18. The synthetic functionalized additive of claim 1 , where the layered magnesium silicate has a silicon to magnesium ratio of from 0.7:1 to 1.5:1 by mole.

19. The drilling fluid of claim 4 , where the synthetic functionalized additive is a synthetically produced additive.

20. The synthetic functionalized additive of claim 1 , where the at least two different functional groups covalently bonded to the second tetrahedral silicate layer have different chemical structures from one another.

21. The drilling fluid of claim 4 , where:
the at least two different functional groups covalently bonded to the first tetrahedral silicate layer have different chemical structures from one another; and
where the at least two different functional groups covalently bonded to the second tetrahedral silicate layer have different chemical structures from one another.

Assignees

• Saudi Arabian Oil Co

Inventors

• Patel Hasmukh A
• Thaemlitz Carl J
• Santra Ashok

Classifications

• C09K8/145 Primary

  characterised by the composition of the clay · CPC title

• C01B33/405

  not containing aluminium · CPC title

• C01B33/44 Primary

  Products obtained from layered base-exchange silicates by ion-exchange with organic compounds such as ammonium, phosphonium or sulfonium compounds or by intercalation of organic compounds, e.g. organoclay material · CPC title

• C09K8/24

  Polymers · CPC title

• C01P2002/22

  layered hydroxide-type, e.g. of the hydrotalcite-type · CPC title