HFO-1234ZE, HFO-1225ZC and HFO-1234YF containing compositions and processes for producing and using the compositions
US-11718775-B2 · Aug 8, 2023 · US
US11912923B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-11912923-B2 |
| Application number | US-202318206127-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jun 6, 2023 |
| Priority date | Jun 27, 2006 |
| Publication date | Feb 27, 2024 |
| Grant date | Feb 27, 2024 |
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A process is disclosed for making CF 3 CF═CHF. The process involves reacting CF 3 CClFCCl 2 F with H 2 in a reaction zone in the presence of a catalyst to produce a product mixture comprising CF 3 CF═CHF. The catalyst has a catalytically effective amount of palladium supported on a support selected from the group consisting of alumina, fluorided alumina, aluminum fluoride and mixtures thereof and the mole ratio of H 2 to CF 3 CClFCCl 2 F fed to the reaction zone is between about 1:1 and about 5:1. Also disclosed are azeotropic compositions of CF 3 CClFCCl 2 F and HF and azeotropic composition of CF 3 CHFCH 2 F and HF.
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What is claimed is: 1. A composition comprising HFO-1225ye, CFO-1215yb, and CFO-1234yf, and optionally one or more of HFO-1243zf, HFC-245eb, HCFC-244eb, HCFC-226ea, HCFC-235bb and HFC-263fb. 2. The composition of claim 1 wherein the member comprises HCFC-226ea. 3. The composition of claim 1 wherein the member comprises HFC-245eb. 4. The composition of any of claim 1 , 2 or 3 , wherein the HFO-1225ye comprises E-HFO-1225ye and Z-HFO-1225ye. 5. The composition of claim 4 wherein the E-HFO-1225ye is present in an amount greater than Z-HFO-1225ye. 6. The composition of claim 4 wherein the E-HFO-1225ye is present in an amount less than Z-HFO-1225ye. 7. A composition comprising Z-HFO-1225ye, CFO-1215yb, and HFO-1234yf, and optionally one or more of E-HFO-1225ye, HFC-263fb, HFO-1243zf, HFC-254eb, HCFC-226ea and HCFC-235bb. 8. A process comprising distilling the composition of any of claims 1 - 3 and isolating HFO-1225ye. 9. A process comprising distilling the composition of claim 4 and isolating E-HFO-1225ye and Z-HFO-1225ye.
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