Aqueous polymer dispersion and process of making the same

Patent metadata

Field	Value
Publication number	US-11912871-B2
Application number	US-201817251843-A
Country	US
Kind code	B2
Filing date	Jul 12, 2018
Priority date	Jul 12, 2018
Publication date	Feb 27, 2024
Grant date	Feb 27, 2024

Abstract

An aqueous dispersion comprising a silicone-acrylic polymer with reduced coagulum, a process of preparing the aqueous dispersion, and an aqueous coating composition comprising the aqueous dispersion and providing coatings with improved corrosion resistance.

First claim

What is claimed is:

1. An aqueous dispersion comprising a silicone-acrylic polymer with a number average molecular weight of from 5,000 to 50,000 g/mol, wherein the silicone-acrylic polymer comprises, based on the weight of the silicone-acrylic polymer,
(a) from 0.1% to 6.5% by weight of structural units of a (meth)acrylate functional siloxane having the structure of formula (I),

wherein R 1 is hydrogen or a methyl group, R 2 , R 3 , R 4 , R 5 and R 6 are each independently selected from the group consisting of methyl, ethyl and benzyl groups, n is an integer of from 0 to 20, p is an integer of from 0 to 20, provided that n+p>5;
(b) from 0.1% to 4.5% by weight of structural units of an ionic monomer;
(c) from 30% to 75% by weight of structural units of a hard monomer; and
(d) from 20% to 65% by weight of structural units of a soft monomer;
wherein the silicone-acrylic polymer comprises residues of an alkyl thiol containing a C 6 -C 24 alkyl or a substituted C 6 -C 24 alkyl; and
wherein the weight ratio of structural units of the (meth)acrylate functional siloxane to residues of the alkyl thiol is less than 5.0.

2. The aqueous dispersion of claim 1 , wherein the alkyl thiol is selected from the group consisting of n-dodecyl mercaptan, cetyl mercaptan, octadecanethiol, octyl mercaptan, hexanethiol, and decanethiol.

3. The aqueous dispersion of claim 1 , wherein the (meth)acrylate functional siloxane has the structure of formula (I), wherein n and p are each independently in the range of from 7 to 16.

4. The aqueous dispersion of claim 1 , wherein the weight ratio of structural units of the (meth)acrylate functional siloxane to residues of the alkyl thiol is 3.0 or less.

5. The aqueous dispersion of claim 1 , wherein the silicone-acrylic polymer comprises, based on the weight of the silicone-acrylic polymer, from 0.1% to 3% by weight of structural units of the (meth)acrylate functional siloxane.

6. The aqueous dispersion of claim 1 , wherein the ionic monomer is selected from the group consisting of acrylic acid, methyl acrylic acid, crotonic acid, itaconic acid, maleic acid, fumaric acid, and phosphoethyl (meth)acrylate; and salts thereof.

7. The aqueous dispersion of claim 1 , wherein the soft monomer is selected from the group consisting of ethyl acrylate, butyl acrylate, butyl methacrylate, 2-ethylhexylacrylate, 2-ethylhexyl methacrylate, lauryl acrylate and lauryl methacrylate.

8. The aqueous dispersion of claim 1 , wherein the hard monomer is selected from the group consisting of methyl methacrylate, styrene, cyclohexyl methacrylate, tert-butyl methacrylate and cyclohexyl acrylate.

9. The aqueous dispersion of claim 1 , wherein the silicone-acrylic polymer has a number average molecular weight of from 8,000 to 20,000 g/mol.

10. The aqueous dispersion of claim 1 , wherein the silicone-acrylic polymer has a glass transition temperature of from −20 to 50° C.

11. The aqueous dispersion of claim 1 , wherein the silicone-acrylic polymer comprises, based on the weight of the silicone-acrylic polymer,
from 1% to 3% by weight of structural units of the (meth)acrylate functional siloxane having the structure of formula (I), from 1% to 3.5% by weight of structural units of the ionic monomer, from 35% to 70% by weight of structural units of the hard monomer, and from 25% to 60% by weight of structural units of the soft monomer,
wherein the weight ratio of structural units of the (meth)acrylate functional siloxane to residues of the alkyl thiol is 3.5 or less.

12. The aqueous dispersion of claim 1 , further comprising a styrene-acrylic polymer.

13. An aqueous coating composition comprising the aqueous dispersion of claim 1 .

14. A process of preparing an aqueous dispersion comprising a silicone-acrylic polymer with a number average molecular weight of from 5,000 to 50,000 g/mol by free-radical polymerization, comprising: polymerization of a monomer mixture in an aqueous medium in the presence of an alkyl thiol containing a C 6 -C 24 alkyl group or a substituted C 6 -C 24 alkyl group;
wherein the monomer mixture comprises, based on the total weight of the monomer mixture,
(a) from 0.1% to 6.5% by weight of a (meth)acrylate functional siloxane having the structure of formula (I),

wherein R 1 is hydrogen or a methyl group, R 2 , R 3 , R 4 , R 5 and R 6 are each independently selected from the group consisting of methyl, ethyl and benzyl groups, n is an integer in the range of from 0 to 20, p is an integer in the range of from 0 to 20, provided that n+p>5;
(b) from 0.1% to 4.5% by weight of an ionic monomer;
(c) from 30% to 75% by weight of a hard monomer; and
(d) from 20% to 65% by weight of a soft monomer;
wherein the silicone-acrylic polymer comprises residues of the alkyl thiol; and
wherein the weight ratio of structural units of the (meth)acrylate functional siloxane to residues of the alkyl thiol is less than 5.0.

Assignees

• Dow Global Technologies Llc
• Rohm & Haas

Inventors

• Zheng Baoqing
• Wu Yan
• Tang Jia
• Bohling James C
• Zhao Juan
• Wang Yujiang

Classifications

• C08L83/10 Primary

  Block- or graft-copolymers containing polysiloxane sequences (obtained by polymerising a compound having a carbon-to-carbon double bond on to a polysiloxane C08L51/08, C08L53/00) · CPC title

• C08F2/26

  anionic · CPC title

• C08F220/06

  Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof · CPC title

• C08F220/14 Primary

  Methyl esters {, e.g. methyl (meth)acrylate} · CPC title

• C08F220/1804

  C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate · CPC title