Olefin polymer and method for producing olefin polymer

Patent metadata

Field	Value
Publication number	US-11912796-B2
Application number	US-201916977599-A
Country	US
Kind code	B2
Filing date	Jan 25, 2019
Priority date	Apr 20, 2018
Publication date	Feb 27, 2024
Grant date	Feb 27, 2024

Abstract

Provided is a novel olefin polymer which is excellent in lightness and moldability, has high rigidity and yields molded products excellent in flexural elasticity. The olefin polymer includes a propylene initial polymerization product formed in the presence of an olefin polymerization catalyst which is a contact reaction product of an olefin polymerization solid catalyst component containing a titanium atom, a magnesium atom, a halogen atom and an internal electron donating compound, at least one organoaluminum compound selected from the compounds of the general formula (I), and a first external electron donating compound; and a polypropylene part formed of a propylene polymerization product formed in the presence of the olefin polymerization catalyst and a second external electron donating compound higher in adsorption to the surface of the olefin polymerization solid catalyst component than the first external electron donating compound.

First claim

The invention claimed is:

1. A method for producing an olefin polymer, comprising:
forming a propylene initial polymerization product in the presence of an olefin polymerization catalyst which is a contact reaction product of:
an olefin polymerization solid catalyst component containing a titanium atom, a magnesium atom, a halogen atom and an internal electron donating compound, and
a preliminary polymerization step comprising adding a first external donating compound and at least one organoaluminum to the solid catalyst component;
wherein the at least one organoaluminum compound selected from compounds of general formula (I):
R 1 p AlQ 3-p   (I)

wherein R 1 is an alkyl group having 1 to 6 carbon atoms, Q is a hydrogen atom or a halogen atom, p is a real number of more than 0 and not more than 3, R 1 s may be the same or different when two or more R 1 s exist, and Qs may be the same or different when two or more Qs exist, and
wherein the first external electron donating compound is one or more organosilicon compounds having a Si—C bond and represented by the following general formula (II):
R 2 Si(OR 3 ) 3   (II)

wherein R 2 is a vinyl group, an allyl group, an aralkyl group, a cycloalkyl group having 3 to 12 carbon atoms, a phenyl group, or an alkylamino group having 1 to 12 carbon atoms, R 3 is an alkyl group having 1 to 4 carbon atoms, a cycloalkyl group having 3 to 6 carbon atoms, a phenyl group, a vinyl group, an allyl group or an aralkyl group, and R 3 s may be the same or different, or one or more aminosilane compounds having a Si—N—C bond and represented by the following general formula (III):
R 4 2 Si(NR 5 R 6 )(NR 7 R 8 )  (III)

wherein R 4 is an alkyl group having 1 to 12 carbon atoms, a vinyl group, an allyl group, an aralkyl group, a cycloalkyl group having 3 to 12 carbon atoms, or a phenyl group, R 4 s may be the same or different, and R 5 , R 6 , R 7 and R 8 are each independently hydrogen, an alkyl group having 1 to 4 carbon atoms, a cycloalkyl group having 3 to 6 carbon atoms, a phenyl group, a vinyl group, an allyl group or an aralkyl group, and may be the same or different; and
further forming a polypropylene part by polymerizing propylene,
adding a second external electron donating compound to a reaction system after the preliminary polymerization step, wherein the second external electron donating compound is added in such a manner that a ratio of time for addition of the second external electron donating compound to a total polymerization time is 5 to 95%, and wherein the second external electron donating compound is higher in adsorption to a surface of the olefin polymerization solid catalyst component than the first external electron donating compound, and
wherein the resulting olefin polymer is a propylene-based block copolymer.

2. The method for producing an olefin polymer according to claim 1 , wherein the internal electron donating compound is one or more selected from dicarboxylic acid esters, diethers, decarbonates, ether carboxylic acid esters or ether carbonates.

3. The method for producing an olefin polymer according to claim 1 , wherein the second external electron donating compound is one or more silane compounds represented by the following general formula (IV):
R 9 2 Si)(OR 10 ) 2   (IV)

wherein R 9 is an alkyl group having 1 to 12 carbon atoms, a vinyl group, an allyl group, an aralkyl group, a cycloalkyl group having 3 to 12 carbon atoms, or a phenyl group, R 10 is an alkyl group having 1 to 4 carbon atoms, a cycloalkyl group having 3 to 6 carbon atoms, a phenyl group, a vinyl group, an allyl group or an aralkyl group, R 9 s may be the same or different, and R 10 s may be the same or different.

4. The method for producing an olefin polymer according to claim 1 , wherein the first external electron donating compound is one or more selected from phenyltrialkoxysilanes, allyltrialkoxysilanes, cycloalkyltrialkoxysilanes, or (alkylamino)trialkoxysilanes.

5. The method for producing an olefin polymer according to claim 1 , wherein the second external electron donating compound is one or more selected from diphenyldialkoxysilanes, dialkyldialkoxysilanes, phenylalkyldialkoxysilanes, di(cycloalkyl)dialkoxysilanes or (cycloalkyl)alkyldialkoxysilanes.

6. The method for producing an olefin polymer according to claim 1 , wherein an amount of the second external electron donating compound added is 0.1 to 10 mol per 1 mol of the first external electron donating compound added.

7. The method for producing an olefin polymer according to claim 1 , wherein a resulting olefin polymer is polypropylene.

Assignees

• Toho Titanium Co Ltd

Inventors

• Uozumi Toshiya
• Morioka Tetsuya
• Kurosaki Keiichi
• Ishikawa Teppei

Classifications

• C08F10/06 Primary

  Propene · CPC title

• C08F210/06

  Propene · CPC title

• C08F297/08

  polymerising mono-olefins · CPC title

• C08F2/001

  Multistage polymerisation processes characterised by a change in reactor conditions without deactivating the intermediate polymer (C08F295/00, C08F297/00 take precedence) · CPC title

• C08F4/656

  with silicon or compounds thereof · CPC title