Slurry with rare earth oxide particles

Patent metadata

Field	Value
Publication number	US-11912583-B2
Application number	US-202117521129-A
Country	US
Kind code	B2
Filing date	Nov 8, 2021
Priority date	Aug 31, 2018
Publication date	Feb 27, 2024
Grant date	Feb 27, 2024

Abstract

A slurry of a dispersion medium and rare earth oxide particles. The particles having a volume basis median particle size D50 of up to 50 nm. The rare earth oxide particles having a dispersity index S of up to 1, the dispersity index S being determined according to the formula (1):(D90−D10)/D50  (1)wherein D10, D50 and D90 are cumulative 10%, 50% and 90% diameters in volume basis particle size distribution, respectively.

First claim

The invention claimed is:

1. A slurry comprising a dispersion medium and rare earth oxide particles wherein the particles have a volume basis median particle size D50 of up to 50 nm, and the rare earth oxide particles have a dispersity index S of up to 1, the dispersity index S being determined according to the formula (1):
( D 90− D 10)/ D 50  (1)

wherein D10, D50 and D90 are cumulative 10%, 50% and 90% diameters in volume basis particle size distribution, respectively.

2. The slurry of claim 1 wherein the rare earth oxide particles have a volume basis median particle size D50 of up to 20 nm.

3. The slurry of claim 1 wherein the rare earth oxide particles have a volume basis median particle size D50 of up to 10 nm.

4. A slurry comprising a dispersion medium and rare earth oxide particles wherein the particles have a volume basis median particle size D50 of up to 50 nm, and the rare earth comprises at least one selected from the group consisting of Y, Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu.

5. The slurry of claim 4 wherein the rare earth further comprises at least one selected from the group consisting of La, Ce, Pr, Nd, Sm and Eu.

6. The slurry of claim 4 wherein the rare earth oxide particles have a dispersity index S of up to 1, the dispersity index S being determined according to the formula (1):
( D 90− D 10)/ D 50  (1)

wherein D10, D50 and D90 are cumulative 10%, 50% and 90% diameters in volume basis particle size distribution, respectively.

7. The slurry of claim 4 wherein the rare earth oxide particles have a volume basis median particle size D50 of up to 20 nm.

8. The slurry of claim 4 wherein the rare earth oxide particles have a volume basis median particle size D50 of up to 10 nm.

9. A slurry comprising a dispersion medium and rare earth oxide particles wherein the particles have a volume basis median particle size D50 of up to 50 nm, and the rare earth oxide particles are prepared by the steps of:
heating an aqueous solution containing rare earth metal ions and urea to form rare earth compound particles by reaction of a hydrolysis product of urea, and the rare earth metal ions,
separating a precipitate of the rare earth compound particles generated in the heating step from the solution by a solid-liquid separation,
firing the obtained solid component in an atmosphere containing oxygen to form a rare earth oxide,
wherein in the heating step, heating the aqueous solution into which an acetylene glycol-ethylene oxide adduct is added, and
wherein the rare earth comprise at least one selected from the group consisting of Y, Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu.

10. The slurry of claim 9 wherein rare earth further comprises at least one selected from the group consisting of La, Ce, Pr, Nd, Sm and Eu.

11. The slurry of claim 9 wherein the acetylene glycol-ethylene oxide adduct has the structure represented by the following structural formula:

wherein m is 0 or an integer number of 1 to 5, n is 0 or an integer number of 1 to 5, and at least one of m and n is 1 or more.

12. The slurry of claim 9 wherein the rare earth oxide particles have a dispersity index S of up to 1, the dispersity index S being determined according to the formula (1):
( D 90− D 10)/ D 50  (1)

wherein D10, D50 and D90 are cumulative 10%, 50% and 90% diameters in volume basis particle size distribution, respectively.

13. The slurry of claim 9 wherein the rare earth oxide particles have a volume basis median particle size D50 of up to 20 nm.

14. The slurry of claim 9 wherein the rare earth oxide particles have a volume basis median particle size D50 of up to 10 nm.

Assignees

• Shinetsu Chemical Co

Inventors

• Wataya Kazuhiro

Classifications

• C01F17/10 Primary

  Preparation or treatment, e.g. separation or purification · CPC title

• C01F17/206 Primary

  oxide or hydroxide being the only anion · CPC title

• C01F17/218

  Yttrium oxides or hydroxides · CPC title

• C01F17/224

  Oxides or hydroxides of lanthanides · CPC title

• C01F17/229

  Lanthanum oxides or hydroxides · CPC title