Preparation of titanium and titanium alloy powder for 3D printing based on fluidized bed jet milling technique

Patent metadata

Field	Value
Publication number	US-11911826-B2
Application number	US-202117200475-A
Country	US
Kind code	B2
Filing date	Mar 12, 2021
Priority date	Apr 16, 2019
Publication date	Feb 27, 2024
Grant date	Feb 27, 2024

Abstract

A method of preparation of titanium and titanium alloy powder for 3D printing is based on a fluidized bed jet milling technique. Hydride-dehydrite titanium powder and titanium alloy powder are used as main raw material powder, jet milling and shaping are carried out in shielding atmosphere of nitrogen or argon, and finally high-performance titanium and titanium alloy powder meeting the requirements of 3D printing process is obtained. The titanium and titanium alloy powder prepared using this method has a narrow particle size distribution, approximately spherical shape, and controllable oxygen content.

First claim

The invention claimed is:

1. A method of preparation of a powder for 3D printing, comprising:
1): obtain a raw material powder comprising titanium, 1,000-2,000 PPM oxygen, and a particle size of 200-800 meshes, wherein the raw material powder has an irregular morphology;
2): loading the raw material powder into a jet mill having a fluidized bed jet grinding chamber, three gas inlets each having a nozzle arranged inside the jet mill above the fluidized bed jet grinding chamber at 60-90° included angle between the nozzle and a wall surface of the grinding chamber, and a powder inlet and a powder outlet arranged at a lower end and a upper end of the fluidized bed jet grinding chamber, respectively, and a classifier wheel disposed inside the jet mill and connected to the powder outlet;
3): injecting a grinding gas into the grinding chamber through the three gas inlets, at a pressure of 0.1-10 MPa, grinding the raw material powder for 2 to 60 mins; and discharging the powder for 3D printing, wherein the classifier wheel is operated at a frequency of 0 to 60 Hz,
wherein the raw material powder is a titanium alloy powder, a hydride-dehydride titanium powder, or a mixture thereof, and
the grinding gas is argon or nitrogen.

2. The method according to claim 1 , wherein the three nozzles of the three gas inlets form a 120° included angle with each other.

3. The method according to claim 1 , wherein each gas inlet is at a negative pressure, and the powder outlet is shielded by nitrogen or argon.

4. The method according to claim 1 , wherein the frequency of the classifier wheel is 60 Hz during loading of the raw material powder and is 0 Hz during discharging of the powder for 3D printing.

Assignees

• Univ Beijing Science & Technology

Inventors

• Chen Gang
• Qin Mingli
• Tao Qiying
• Qu Xuanhui

Classifications

• B22F9/04 Primary

  starting from solid material, e.g. by crushing, grinding or milling ({C22C1/1084 takes precedence}; crushing, grinding or milling, in general, see the relevant subclasses, e.g. B02C) · CPC title

• B01J2/16

  by suspending the powder material in a gas, e.g. in fluidised beds or as a falling curtain · CPC title

• B22F1/052

  characterised by a mixture of particles of different sizes or by the particle size distribution · CPC title

• B33Y70/00

  Materials specially adapted for additive manufacturing · CPC title

• B22F2009/044

  by jet milling · CPC title