Apparatus and method for forming a multilayer extrusion comprising component layers of an electrochemical cell

Patent metadata

Field	Value
Publication number	US-11909083-B2
Application number	US-201816235403-A
Country	US
Kind code	B2
Filing date	Dec 28, 2018
Priority date	Dec 28, 2018
Publication date	Feb 20, 2024
Grant date	Feb 20, 2024

Abstract

A co-extrusion die is configured to produce a multilayer extrusion comprising component layers of an electrochemical cell. The die comprises a plurality of inlet ports configured to receive a plurality of pressurized fluids comprising at least a first metallic ink, a second metallic ink, and a polymeric ink. A plurality of channels are configured to separately transport and shape the plurality of fluids from the plurality of inlet ports to a merge section, such that the plurality of fluids flow together in the merge section to form the multilayer extrusion comprising a polymeric membrane layer disposed between and in contact with a first metallic layer and a second metallic layer. A thickness of each layer within the merge section is controllable by adjustment of a pressure of the plurality of pressurized fluids. An outlet port is configured to output the multilayer extrusion onto a substrate.

First claim

What is claimed is:

1. A co-extrusion die configured to produce a multilayer extrusion comprising component layers of an electrochemical cell, the die comprising:
a plurality of inlet ports configured to receive a plurality of pressurized fluids comprising at least a first metallic ink, a second metallic ink, and a polymeric ink, the plurality of inlet ports comprising a first inlet port oriented along a longitudinal axis of the die;
a plurality of channels comprising a first channel orientated along the longitudinal axis of the die and a plurality of additional channels each oriented at an oblique angle or a right angle to the longitudinal axis of the die, the first channel fluidically coupled to the first inlet port, the plurality of additional channels arranged in a staggered arrangement along the longitudinal axis of the die, a first set of the additional channels arranged on a first side of the first channel and a second set of the additional channels arranged on a second side of the first channel opposing the first side, and each of the plurality of additional channels comprising an outlet to the first channel;
the plurality of channels configured to separately transport and shape the plurality of fluids from the plurality of inlet ports to a merge section situated at the outlets of the plurality of channels, such that the plurality of fluids flow intact and in contact together in the merge section in a serialized manner and in accordance with the staggered arrangement to form the multilayer extrusion comprising a polymeric membrane layer disposed between and in contact with a first metallic layer and a second metallic layer;
an outlet port fluidically coupled to the merge section, the outlet port configured to output the multilayer extrusion onto a substrate of the electrochemical cell, the multilayer extrusion comprising an inner layer, an outer layer, and one or more middle layers disposed between the inner and outer layers; and
the die fluidically coupled to a plurality of pumps each separately coupled to a respective one of the plurality of inlet ports for pressurizing a respective one of the plurality of pressurized fluids, the plurality of pumps configured to adjust a pressure of the plurality of pressurized fluids, and a viscosity of the plurality of fluids is adjusted such that the one or more middle layers are reduced in thickness relative to the outer layer which is increased in thickness.

2. The die of claim 1 , wherein:
the multilayer extrusion defines layers of a membrane electrode assembly (MEA);
the first and second metallic layers define first and second electrode layers of the MEA; and
the substrate comprises a gas diffusion layer.

3. The die of claim 2 , wherein:
the plurality of inlets are configured to receive a first microporous layer ink and a second microporous layer ink; and
the plurality of channels are configured to separately transport the plurality of fluids including the first microporous layer ink and the second microporous layer ink to the merge section, such that the plurality of fluids flow together in the merge section to form the multilayer extrusion comprising, in order, a first microporous layer, the first electrode layer, the polymeric membrane layer, the second electrode layer, and a second microporous layer.

4. The die of claim 1 , wherein:
the multilayer extrusion defines layers of a proton exchange membrane (PEM); and
the first and second metallic layers are configured to have low hydrogen permeability sufficient to reduce an amount of hydrogen crossover at the polymeric membrane layer relative the PEM devoid of the first and second metallic layers.

5. The die of claim 4 , wherein:
the plurality of inlet ports are configured to receive a first electrode ink and a second electrode ink; and
the plurality of channels are configured to separately transport the plurality of fluids including the first and second electrode inks from the plurality of inlet ports to the merge section, such that the plurality of fluids flow together in the merge section to form the multilayer extrusion comprising the PEM disposed between and in contact with the first and second metallic layers, a first electrode layer in contact with the first metallic layer, and a second electrode layer in contact with the second electrode layer.

6. The die of claim 1 , wherein:
the multilayer extrusion defines layers of a battery;
the polymeric membrane defines a polymeric separator of the battery;
the first and second metallic layers define first and second electrodes of the battery; and
the substrate comprises a current collector.

7. The die of claim 1 , wherein:
the plurality of inlet ports are configured to receive a plurality of graded first metallic inks having different electrode material loading; and
the plurality of channels are configured to separately transport the plurality of fluids including the plurality of graded first metallic inks to the merge section, such that the plurality of fluids flow together in the merge section to form the multilayer extrusion comprising the polymeric membrane layer disposed between a second electrode layer and a plurality of graded first electrode layers.

8. The die of claim 7 , wherein the plurality of graded first electrode layers are situated relative to the polymeric membrane layer in an order based on electrode material loading, such that a graded first electrode layer with highest electrode material loading is closest to the polymeric membrane layer and a graded first electrode layer with lowest electrode material loading is furthest away from the polymeric membrane layer.

9. The die of claim 8 , wherein the die comprises at least three inlet ports and at least three channels respectively configured to receive and transport at least three graded first metallic inks to the merge section.

10. The die of claim 7 , wherein:
the plurality of inlet ports are configured to receive a plurality of graded second metallic inks having different electrode material loading; and
the plurality of channels are configured to separately transport the plurality of fluids including the plurality of graded second metallic inks to the merge section, such that the plurality of fluids flow together in the merge section to form the multilayer extrusion comprising the polymeric membrane layer disposed between a plurality of graded second electrode layers and the plurality of graded first electrode layers.

11. The die of claim 10 , wherein the plurality of graded second electrode layers are situated relative to the polymeric membrane layer in an order based on electrode material loading, such that a graded second electrode layer with highest electrode material loading is closest to the polymeric membrane layer and a graded second electrode layer with lowest electrode material loading is furthest away from the polymeric membrane layer.

12. The die of claim 11 , wherein the die comprises at least three inlet ports and at least three channels respectively configured to receive and transport at least three graded second metallic inks to the merge section.

13. The die of claim 1 , wherein the plurality of channels are spaced apart along a longitudinal axis of the merge section such that the plurality of fluids flow in contact together in the merge section in a specified order to form the multilayer extrusion.

14. An apparatus comprising the die of claim 1 , comprising:
a transport mechanism configured to move the substrate into contact with a surface of the multilayer extrusion;
wherein the substrate comprises a functional component of the electrochemical cell.

15. A

Assignees

• Palo Alto Res Ct Inc
• Xerox Corp

Inventors

• Murphy Kathryn F

Classifications

• B01D69/1214

  Chemically bonded layers, e.g. cross-linking · CPC title

• H01M8/1004 Primary

  characterised by membrane-electrode assemblies [MEA] (H01M8/12 takes precedence) · CPC title

• B01D69/088

  Co-extrusion; Co-spinning · CPC title

• H01M8/1086

  After-treatment of the membrane other than by polymerisation · CPC title

• Y02E60/50

  Fuel cells · CPC title