Self-organized and electrically conducting PEDOT polymer matrix for applications in sensors and energy generation and storage

Patent metadata

Field	Value
Publication number	US-11905609-B2
Application number	US-202117394711-A
Country	US
Kind code	B2
Filing date	Aug 5, 2021
Priority date	Feb 23, 2016
Publication date	Feb 20, 2024
Grant date	Feb 20, 2024

Abstract

The present invention relates to a one-step process for preparation of “in-situ” or “ex-situ” self-organized and electrically conducting polymer nanocomposites using thermally initiated polymerization of a halogenated 3,4-ethylenedioxythiophene monomer or its derivatives. This approach does not require additional polymerization initiators or catalysts, produce gaseous products that are naturally removed without affecting the polymer matrix, and do not leave by-product contaminants. It is demonstrated that self-polymerization of halogenated 3,4-ethylenedioxythiophene monomer is not affected by the presence of a solid-state phase in the form of nanoparticles and results in formation of 3,4-polyethylenedioxythiophene (PEDOT) nanocomposites.

First claim

What is claimed is:

1. An electrochemical polymerization method, comprising:
forming an ionic-electrically conducting nanocomposite from a halogenated 3,4-ethylenedioxythiophene (EDOT) or EDOT derivatives mixed with a polar aprotic solvent and solid-state phase 1D or 2D nanostructures using “in-situ” self-polymerization.

2. The method of claim 1 , wherein the electrically conducting nanocomposite is a conducting and self-polymerized 3D nanocomposite matrix.

3. The method of claim 1 , wherein the electrically conducting nanocomposite is formed from 2,5-dibromo-3,4-ethylenedioxythiophene (DBEDOT) or DBEDOT derivative.

4. The method of claim 1 , wherein the self polymerization is a one-step polymerization process.

5. The method of claim 1 , wherein the polar aprotic solvent is an organic solvent.

6. The method of claim 1 , wherein the halogenated monomer EDOT forms a homogeneous solution with an organic solvent in presence of a solid-state phase introduced to the solution in the form of solid-state nanoparticles.

7. The method of claim 1 , wherein an organic solvent in the presence of the halogenated monomer EDOT mixed with the solid-state nanostructures evaporates during the self-organized polymerization process resulting in formation of a solid-state nanocomposite.

8. The method of claim 3 , further comprising:
removing gaseous products from the forming electrically conducting nanocomposite thereby naturally forming the solid-state nanocomposite.

9. The method of claim 2 , further comprising:
processing the nanocomposites without cleaning or separation processes.

10. The method of claim 1 , further comprising:
thermally initiating self-polymerization of the nanocomposite in a temperature range from 50° C. to 90° C.

11. The method of claim 1 , wherein a time period for self-polymerization of the nanocomposite ranges based on a weight percent of the solid-state phase and film thickness.

12. The method of claim 1 , further comprising:
forming a 3D nanocomposite from the halogenated EDOT monomer or EDOT derivatives with one or more catalytically or non-catalytically active metal- or non-metal-based solid-state phases in the form of a nanoparticle.

13. The method of claim 1 , wherein the nanostructures comprise carbon, silicon, a metal, a metal alloy, a metal oxide, a ceramic, a semiconductor, or combination thereof.

14. The method of claim 1 , wherein the nanostructures comprise nanotubes or nanorods.

15. The method of claim 1 , further comprising:
forming electrodes from the self-polymerizing nanocomposites, wherein an electrochemical storage cell, fuel cell, electrolyzer, supercapacitor includes one or more of the electrodes.

16. The method of claim 1 , further comprising:
controlling optical transparency of the self-polymerizing nanocomposites for producing optically transparent nanocomposites, wherein a solar cell, photovoltaic cell include the optically transparent nanocomposites.

17. The method of claim 1 , wherein an electrical stability of the self-polymerizing nanocomposites has a voltage range from 0.05 to 4.5 V.

Assignees

• South Dakota Board Of Regents

Inventors

• Smirnova Alevtina
• Mcgraw Michael
• Kolla Praveen

Classifications

• C25B11/055 Primary

  characterised by the substrate or carrier material · CPC title

• C25B3/00 Primary

  Electrolytic production of organic compounds · CPC title

• C08G61/121

  derived from organic halides · CPC title

• C08G61/126

  with a five-membered ring containing one sulfur atom in the ring · CPC title

• H01G9/028

  Organic semiconducting electrolytes, e.g. TCNQ · CPC title