Steam reforming heated by resistance heating

Patent metadata

Field	Value
Publication number	US-11905173-B2
Application number	US-201917046475-A
Country	US
Kind code	B2
Filing date	May 15, 2019
Priority date	May 31, 2018
Publication date	Feb 20, 2024
Grant date	Feb 20, 2024

Abstract

A reactor system for carrying out steam reforming of a feed gas comprising hydrocarbons, including: a structured catalyst arranged for catalyzing steam reforming of a feed gas including hydrocarbons, the structured catalyst including a macroscopic structure of electrically conductive material, the macroscopic structure supporting a ceramic coating, wherein the ceramic coating supports a catalytically active material; a pressure shell housing the structured catalyst; heat insulation layer between the structured catalyst and the pressure shell; at least two conductors electrically connected to the macroscopic structure and to an electrical power supply placed outside the pressure shell, wherein the electrical power supply is dimensioned to heat at least part of the structured catalyst to a temperature of at least 500° C. by passing an electrical current through the macroscopic structure. Also, a process for steam reforming of a feed gas comprising hydrocarbons.

First claim

The invention claimed is:

1. A reactor system for carrying out steam reforming of a feed gas comprising hydrocarbons, said reactor system comprising:
a structured catalyst arranged for catalyzing steam reforming of said feed gas comprising hydrocarbons, said structured catalyst comprising a macroscopic structure of electrically conductive material, said macroscopic structure supporting a ceramic coating, wherein said ceramic coating supports a catalytically active material;
a pressure shell housing said structured catalyst, said pressure shell comprising an inlet for letting in said feed gas and an outlet for letting out product gas, wherein said inlet is positioned so that said feed gas enters said structured catalyst in a first end of said structured catalyst and said product gas exits said structured catalyst from a second end of said structured catalyst;
a heat insulation layer between said structured catalyst and said pressure shell; and
at least two conductors electrically connected to said structured catalyst and to an electrical power supply placed outside said pressure shell, wherein said electrical power supply is dimensioned to heat at least part of said structured catalyst to a temperature of at least 500° C. by passing an electrical current through said macroscopic structure, wherein said at least two conductors are connected to the structured catalyst at a position on the structured catalyst closer to said first end of said structured catalyst than to said second end of said structured catalyst, and wherein the structured catalyst is constructed to direct an electrical current to run from one conductor to the second end of the structured catalyst and return to a second of said at least two conductors.

2. A reactor system according to claim 1 , wherein the pressure shell has a design pressure of between 5 and 30 bar.

3. A reactor system according to claim 1 , wherein the pressure shell has a design pressure of between 30 and 200 bar.

4. A reactor system according to claim 1 , wherein the resistivity of the macroscopic structure is between 10 −5 Ω·m and 10 −7 Ω·m.

5. A reactor system according to claim 1 , where each of the at least two conductors are led through the pressure shell in a fitting so that the at least two conductors are electrically insulated from the pressure shell.

6. A reactor system according to claim 5 , wherein said pressure shell further comprises one or more inlets close to or in combination with at least one fitting in order to allow a cooling gas to flow over, around, close to, or inside at least one conductor within said pressure shell.

7. A reactor system according to claim 1 , wherein the reactor system further comprises an inner tube in heat exchange relationship with but electrically insulated from the structured catalyst, said inner tube being adapted to withdraw a product gas from the structured catalyst so that the product gas flowing through the inner tube is in heat exchange relationship with gas flowing through the structured catalyst.

8. A reactor system according to claim 1 , wherein the connection between the structured catalyst and said at least two conductors is a mechanical connection, a welded connection, a brazed connection or a combination thereof.

9. A reactor system according to claim 1 , wherein the macroscopic structure is an extruded and sintered structure or a 3D printed and sintered structure.

10. A reactor system according to claim 1 , wherein the structured catalyst comprises an array of macroscopic structures electrically connected to each other.

11. A reactor system according to claim 1 , wherein said structured catalyst has electrically insulating parts arranged to increase the length of a principal current path between said at least two conductors to a length larger than the largest dimension of the structured catalyst.

12. A reactor system according to claim 1 , wherein said structured catalyst has at least one electrically insulating part arranged to direct a current through said structured catalyst in order to ensure that for at least 70% of the length of said structured catalyst, a current density vector of the principal current path has a non-zero component value parallel to the length of said structured catalyst.

13. A reactor system according to claim 1 , wherein said macroscopic structure has a plurality of parallel channels, a plurality of non-parallel channels and/or a plurality of labyrinthic channels.

14. A reactor system according to claim 1 , wherein the reactor system further comprises a bed of a second catalyst material upstream said structured catalyst within said pressure shell.

15. A reactor system according to claim 12 , wherein said reactor system further comprises a third catalyst material in the form of catalyst pellets, extrudates or granulates loaded into the channels of said structured catalyst.

16. A reactor system according to claim 1 , further comprising a bed of fourth catalyst material placed within the pressure shell and downstream the structured catalyst.

17. A reactor system according to claim 1 , wherein the material of the macroscopic structure is chosen as a material arranged to generate a heat flux of 500 to 50000 W/m 2 by resistance heating of the material.

18. A reactor system according to claim 1 , wherein the structured catalyst comprises a first part arranged to generate a first heat flux and a second part arranged to generate a second heat flux, where the first heat flux is lower than the second heat flux, and where the first part is upstream the second part.

19. A reactor system according to claim 1 , wherein said reactor system further comprises a control system arranged to control the electrical power supply to ensure that the temperature of the gas exiting the pressure shell lies in a predetermined range and/or to ensure that the conversion of hydrocarbons in the feed gas lies in a predetermined range and/or to ensure the dry mole concentration of methane lies in a predetermined range and/or to ensure the approach to equilibrium of the steam reforming reaction lies in a predetermined range.

20. A reactor system according to claim 1 , wherein the structured catalyst within said reactor system has a ratio between the area equivalent diameter of a horizontal cross section through the structured catalyst and the height of the structured catalyst in the range from 0.1 to 2.0.

21. A reactor system according to claim 1 , wherein the height of the reactor system is between 0.5 and 7 m.

22. A process for carrying out steam reforming of a feed gas comprising hydrocarbons in a reactor system comprising a pressure shell housing a structured catalyst arranged to catalyze steam reforming of a feed gas comprising hydrocarbons, said structured catalyst comprising a macroscopic structure of an electrically conductive material, said macroscopic structure supporting a ceramic coating, where said ceramic coating supports a catalytically active material and wherein said reactor system is provided with heat insulation between said structured catalyst and said pressure shell; said process comprising the following steps:
pressurizing a feed gas comprising hydrocarbons to a pressure of at least 5 bar,
supplying said pressurized feed gas to said pressure shell through an inlet positioned so that said feed gas enters said structured catalyst in a first end of said structured catalyst;

allowing the feed gas to undergo steam reforming reaction over the structured catalyst and outletting a pro

Assignees

• Haldor Topsoe As

Inventors

• Mortensen Peter Mølgaard
• Klein Robert
• Aasberg-Petersen Kim

Classifications

• C01B3/384 Primary

  with external heating of the catalyst · CPC title

• B01J15/005 Primary

  in the presence of catalytically active bodies, e.g. porous plates · CPC title

• B01J19/2485

  Monolithic reactors · CPC title

• C01B3/40

  characterised by the catalyst · CPC title

• B01J2219/00135

  Electric resistance heaters · CPC title