Polyurethane composites produced by a vacuum infusion process
US-9580598-B2 · Feb 28, 2017 · US
US11904582B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-11904582-B2 |
| Application number | US-201715799511-A |
| Country | US |
| Kind code | B2 |
| Filing date | Oct 31, 2017 |
| Priority date | Dec 12, 2009 |
| Publication date | Feb 20, 2024 |
| Grant date | Feb 20, 2024 |
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The invention relates to the use of layer structures in the production of rotor blades for wind power plants, and to rotor blades for wind power plants.
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The invention claimed is: 1. A vacuum-assisted resin transfer moulding process for the production of layer structures for rotor blades in wind power plants, the process comprising: a. providing a mould; b. placing dry fibre mats in the mould according to a precise production plan; c. hermetically sealing the mould as a whole; d. removing the air from the mould to thereby produce an evacuated layer structure; and e. injecting into the evacuated layer structure a liquid polyurethane reaction mixture comprising: (1) a polyether polyol having a viscosity of ≤800 mPas at 25° C. (2) a di- and/or poly-isocyanate having a viscosity of ≤.250 mPas at 25° C., and (3) a catalyst, wherein the liquid polyurethane reaction mixture has a viscosity, measured 30 minutes after mixing (1) with (2), of ≤5000 mPas at 25° C.; and wherein the dry fibre mats consist of polymer fibre mats, glass fibre mats, aramid fibre mats, carbon fibre mats, or a mixture thereof. 2. The process according to claim 1 , wherein b. comprises: i. inserting a first layer of dry fibre mat which will subsequently form a layer of the rotor blade that is located on the outside; ii. inserting a spacer material comprising a plastic foam or wood on the first layer; and iii. placing a further dry fibre layer on the spacer material which will then form an inner layer. 3. The process according to claim 1 , wherein in c., the mould is sealed with a vacuum-tight film. 4. The process according to claim 2 , wherein in c., the mould is sealed with a vacuum-tight film. 5. The process according to claim 1 , wherein the di- and/or poly-isocyanate comprises diphenylmethane diisocyanate and/or polyphenylenepolymethylene polyisocyanate having an NCO content of more than 25 wt. %. 6. The process according to claim 2 , wherein the di- and/or poly-isocyanate comprises diphenylmethane diisocyanate and/or polyphenylenepolymethylene polyisocyanate having an NCO content of more than 25 wt. %. 7. The process according to claim 1 , wherein the polyether polyol comprises a polyether polyol in which at least 60% of the OH groups are secondary OH groups and which has an OH number of from 200 to 1830 mg KOH/g. 8. The process according to claim 1 , wherein the reaction mixture is applied to the fibre layers at a temperature of from 20 to 80° C. 9. The process according to claim 1 , wherein the reaction mixture is cured at a temperature of from 40 to 160° C. 10. The process according to claim 1 , wherein the di- and/or poly-isocyanate comprises diphenylmethane diisocyanate and/or polyphenylenepolymethylene polyisocyanate having an NCO content of more than 25 wt. %, and wherein the polyether polyol comprises a polyether polyol in which at least 60 % of the OH groups are secondary OH groups and which has an OH number of from 200 to 1830 mg KOH/g. 11. The process according to claim 10 , wherein the reaction mixture at 25 ° C. has a viscosity of ≤2000 mPas 3 minutes after mixing. 12. The process according to claim 10 , wherein the reaction mixture at 25 ° C. has a viscosity of ≤1000 mPas 3 minutes after mixing. 13. The process according to claim 1 , wherein the polyether polyol comprises a number of groups reactive towards isocyanate groups and the di- and/or poly- isocyanate comprises a number of isocyanate groups, and wherein a ratio of the number of isocyanate groups to the number of groups reactive towards isocyanate in the liquid polyurethane reaction mixture is in a range of 0.9 to 1.5. 14. The process according to claim 13 , wherein a ratio of a number of isocyanate groups to a number of groups reactive towards isocyanate in the liquid polyurethane reaction mixture is in a range of 1.0 to 1.2. 15. The process according to claim 13 , wherein a ratio of a number of isocyanate groups to a number of groups reactive towards isocyanate in the liquid polyurethane reaction mixture is in a range of 1.02 to 1.1.
of foam · CPC title
characterized by the resin layer, i.e. interlayer · CPC title
bonded with or embedded in a plastic substance · CPC title
characterised by features of a layer {of} foamed material · CPC title
aromatic · CPC title
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