Continuous compression molding machines and methods of continuous compression molding a consolidated thermoplastic matrix composite material

Patent metadata

Field	Value
Publication number	US-11904510-B2
Application number	US-202217669200-A
Country	US
Kind code	B2
Filing date	Feb 10, 2022
Priority date	Feb 10, 2022
Publication date	Feb 20, 2024
Grant date	Feb 20, 2024

Abstract

Continuous compression molding machines (CCMMs) and methods of continuous compression molding a consolidated thermoplastic matrix composite material are disclosed herein. The CCMMs include a mold, a heat zone heating structure, a consolidation zone heating structure, and a stress relaxation zone heating structure. The CCMMs also include a press structure, a demold structure, and a supply structure. The methods include providing a thermoplastic matrix composite material (TMCM) that includes a thermoplastic material to a CCMM. During the providing, the methods also include heating the TMCM within a heat zone of the CCMM, cooling and consolidating the TMCM within a consolidation zone of the CCMM, relaxing stress within the TMCM within a stress relaxation zone of the CCMM, demolding the TMCM within a demold zone of the CCMM at a mold temperature that is greater than a glass transition temperature of the thermoplastic material, and periodically compressing the TMCM.

First claim

The invention claimed is:

1. A method of continuous compression molding a consolidated thermoplastic matrix composite material, the method comprising:
providing a thermoplastic matrix composite material (TMCM), which includes a thermoplastic material, to a continuous compression molding machine (CCMM); and
during the providing:
(i) heating the TMCM, within a heat zone of the CCMM, to an initial temperature that is above a melt temperature of the thermoplastic material;
(ii) cooling and consolidating the TMCM, within a consolidation zone of the CCMM, to a subsequent temperature;
(iii) relaxing stress within the TMCM, within a stress relaxation zone of the CCMM, at a stress relaxation temperature;
(iv) demolding the TMCM from a mold of the CCMM within a demold zone of the CCMM and at a demold temperature that is greater than a glass transition temperature of the thermoplastic material; and
(v) periodically compressing the TMCM, with the mold of the CCMM, to form the TMCM to a desired shape for the consolidated thermoplastic matrix composite material.

2. The method of claim 1 , wherein the thermoplastic material is a semicrystalline thermoplastic material, wherein the subsequent temperature is below the melt temperature of the semicrystalline thermoplastic material and above the glass transition temperature of the semicrystalline thermoplastic material, and further wherein the stress relaxation temperature is below the melt temperature of the semicrystalline thermoplastic material and above the glass transition temperature of the semicrystalline thermoplastic material.

3. The method of claim 2 , wherein the stress relaxation temperature is within 10 degrees Celsius (° C.) of a peak isothermal crystallization temperature of the semicrystalline thermoplastic material.

4. The method of claim 1 , wherein the thermoplastic material is an amorphous thermoplastic material, wherein the initial temperature is greater than the glass transition temperature of the amorphous thermoplastic material, wherein the subsequent temperature is greater than the glass transition temperature of the amorphous thermoplastic material, and further wherein the stress relaxation temperature is greater than the glass transition temperature of the amorphous thermoplastic material.

5. The method of claim 1 , wherein at least one of:
(i) the initial temperature is at least 300° C. and at most 450° C.;
(ii) the subsequent temperature is at least 200° C. and at most 300° C.; and
(iii) the stress relaxation temperature is at least 200° C. and at most 300° C.

6. The method of claim 1 , wherein the stress relaxation temperature is a stress-free temperature for the thermoplastic material at which a relaxation time constant for the thermoplastic material is less than a process time for the TMCM within the CCMM.

7. The method of claim 1 , wherein a difference between the initial temperature and the stress relaxation temperature is at least 60° C. and at most 180° C.

8. The method of claim 1 , wherein:
(i) the heat zone has a heat zone temperature, which is at least the initial temperature and is selected to heat the TMCM to the initial temperature;
(ii) the consolidation zone has a consolidation zone temperature, which is at most the subsequent temperature and is selected to cool the TMCM to the subsequent temperature; and
(iii) the stress relaxation zone has a stress relaxation zone temperature, which is at most the consolidation zone temperature and is selected to maintain the TMCM at the stress relaxation temperature.

9. The method of claim 8 , wherein the consolidation zone temperature is at most 100° C. less than the stress relaxation zone temperature.

10. The method of claim 1 , wherein the providing includes periodically advancing a continuous length of the TMCM sequentially through the heat zone, the consolidation zone, the stress relaxation zone, and the demold zone, wherein the mold includes a first mold die, which defines a first mold surface, and a second mold die, which defines a second mold surface that faces toward the first mold surface, and further wherein the method includes:
(i) moving the first mold surface away from the second mold surface to permit the periodically advancing; and
(ii) moving the first mold surface toward the second mold surface during the periodically compressing.

11. The method of claim 10 , wherein the mold defines an elongate mold channel that defines the desired shape for the consolidated thermoplastic matrix composite material, wherein the first mold surface extends at least substantially parallel to a first mold surface plane along an entirety of a length of the elongate mold channel, and further wherein the second mold surface extends at least substantially parallel to a second mold surface plane along the entirety of the length of the elongate mold channel.

12. The method of claim 11 , wherein a distance between the first mold surface and the second mold surface decreases along the length of the elongate mold channel and from the heat zone to the stress relaxation zone.

13. The method of claim 1 , wherein the mold is free of shape compensation for the consolidated thermoplastic matrix composite material.

14. The method of claim 1 , wherein the mold includes a plurality of mold die regions, and further wherein the heat zone, the consolidation zone, and the stress relaxation zone each are defined by at least one corresponding mold die region of the plurality of mold die regions.

15. The method of claim 1 , wherein at least one of:
(i) the consolidation zone is free from water cooling; and
(ii) the stress relaxation zone is free from water cooling.

16. The method of claim 1 , wherein, subsequent to the demolding, the method further includes quenching the TMCM to a quench temperature that is less than the stress relaxation temperature.

17. The method of claim 1 , wherein, subsequent to the demolding, the method further includes supporting the TMCM with a support structure, wherein the support structure is a stationary support structure.

18. The method of claim 1 , wherein
the mold is configured to shape the TMCM to a desired shape for the consolidated thermoplastic matrix composite material;
the CCMM includes a heat zone heating structure configured to heat the heat zone to the initial temperature during the heating;
the CCMM includes a consolidation zone heating structure configured to heat the consolidation zone to the subsequent temperature during the cooling and consolidating;
the CCMM includes a stress relaxation zone heating structure configured to maintain the stress relaxation zone at the stress relaxation temperature during the relaxing stress;
the CCMM includes a press structure configured to periodically compress the TMCM, within the mold and during the periodically compressing, to form the TMCM to the desired shape;
the CCMM includes a demold structure configured to demold the TMCM from the mold during the demolding; and
the CCMM includes a supply structure configured to periodically advance the TMCM through the mold.

19. The method of claim 18 , wherein the consolidation zone of the mold defines a consolidation zone thickness, wherein the stress relaxation zone of the mold defines a stress relaxation zone thickness, and further wherein the stress relaxation zone thickness is less than the consolidation zone thickness.

20. The method of claim 18 , wherein the CCMM further includes a support structure configured to receive the TMCM from the demold structure and to support the TMCM.

Assignees

• Boeing Co

Inventors

• Charest Trevor David
• Cowin Aaron Ross
• Hickman Gregory James Schoepen
• Schell Justin Joseph
• Wilkerson Randall Dow

Classifications

• B29C43/265 Primary

  for making multilayered articles · CPC title

• B29C43/44

  Compression means for making articles of indefinite length · CPC title

• B29C43/52 Primary

  Heating or cooling · CPC title

• B29C70/50

  for producing articles of indefinite length, e.g. prepregs, sheet moulding compounds [SMC] or cross moulding compounds [XMC] · CPC title

• B29K2995/004

  Semi-crystalline · CPC title