Catalyst structure and method for producing the catalyst structure

Patent metadata

Field	Value
Publication number	US-11904306-B2
Application number	US-202117167280-A
Country	US
Kind code	B2
Filing date	Feb 4, 2021
Priority date	May 31, 2017
Publication date	Feb 20, 2024
Grant date	Feb 20, 2024

Abstract

A catalyst structure includes a carrier having a porous structure composed of a zeolite type compound and at least one catalytic material existing in the carrier. The carrier has channels communicating with each other, and the catalytic material is a metal fine particle and exists at least in the channel of the carrier.

First claim

What is claimed is:

1. A method for producing a catalyst structure comprising:
baking a precursor material (B) including a precursor material (A) which is for obtaining a carrier of a porous structure composed of a zeolite compound and is impregnated with a solution containing a metal;
hydrothermally treating a precursor material (C) obtained by baking the precursor material (B); and
subjecting the hydrothermally treated precursor material (C) to reduction treatment to produce the catalyst structure that includes
the carrier having the porous structure comprising the zeolite compound having a framework, and
at least one catalytic material comprising a fine particle of the metal and existing in the carrier,

wherein the carrier has a plurality of channels communicating with each other, the channels include at least one of a one-dimensional pore, a two-dimensional pore and a three-dimensional pore defined by the framework of the zeolite compound, and a plurality of enlarged diameter portions which are different from the one-dimensional pore, the two-dimensional pore and the three-dimensional pore and are not defined by the framework of the zeolite compound, and
the catalytic materials are included in the enlarged diameter portions such that one of the enlarged diameter portions encloses one of the catalytic materials and separates the one of the catalytic materials from another of the catalytic materials.

2. The method for producing the catalyst structure according to claim 1 , comprising adding a nonionic surface active agent in an amount of 50 to 500 mass % with respect to the precursor material (A), before the baking.

3. The method for producing the catalyst structure according to claim 1 , comprising impregnating the precursor material (A) with the solution by adding the solution to the precursor material (A) separately for a plurality of times, before the baking.

4. The method for producing the catalyst structure according to claim 1 , comprising, when impregnating the precursor material (A) with the solution before the baking, adjusting an addition amount of the solution to be added to the precursor material (A) so as to be 10 to 1000 in terms of a ratio (atomic ratio Si/M) of silicon (Si) forming the precursor material (A) with respect to the metal element (M) to be contained in the solution to be added to the precursor material (A).

5. The method for producing the catalyst structure according to claim 1 , comprising mixing the precursor material (C) with a structure directing agent, in the hydrothermal treatment.

6. The method for producing the catalyst structure according to claim 1 , wherein the hydrothermal treatment is performed under a basic atmosphere.

Assignees

• Furukawa Electric Co Ltd

Inventors

• Kato Sadahiro
• Fukushima Masayuki
• Takahashi Hiroko
• BANBA Yuichiro
• Sekine Kaori
• Masuda Takao
• Nakasaka Yuta
• Yoshikawa Takuya

Classifications

• B01J35/45

  Nanoparticles · CPC title

• B01J29/89 Primary

  Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium {(B01J29/005 takes precedence)} · CPC title

• B01J23/42 Primary

  Platinum · CPC title

• B01J23/44

  Palladium · CPC title

• B01J23/462

  Ruthenium · CPC title