Solids-packed apparatus for performance of endothermic reactions with direct electrical heating
US-2021051770-A1 · Feb 18, 2021 · US
US11904290B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-11904290-B2 |
| Application number | US-201917265623-A |
| Country | US |
| Kind code | B2 |
| Filing date | Aug 5, 2019 |
| Priority date | Aug 6, 2018 |
| Publication date | Feb 20, 2024 |
| Grant date | Feb 20, 2024 |
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An apparatus contains at least one pressure-rated apparatus shell and at least one modular framework system containing ceramic fiber composite materials and arranged within the apparatus shell. A modular lining apparatus includes the modular framework system and refractory bricks. The apparatus can be used for high-temperature reactors, especially electrically heated high-temperature reactors.
Opening claim text (preview).
The invention claimed is: 1. An apparatus, comprising: at least one pressure-rated apparatus shell; and at least one modular framework system comprising two different types of framework elements and being arranged within the apparatus shell; wherein multiple transverse elements form at least one prism or one cylinder and multiple lateral elements project into the interior of the prism or cylinder; wherein the multiple transverse elements and the multiple lateral elements can be inserted into one another and/or can be connected with the aid of one or more connecting elements; wherein a material of the framework elements comprises a ceramic fiber composite material. 2. The apparatus according to claim 1 , wherein the at least one modular framework system is self-supporting. 3. The apparatus according to claim 1 , wherein the material of the framework elements comprises an oxidic fiber composite material. 4. The apparatus according to claim 1 , wherein the transverse elements take the form of corrugated, angled, or flat sheets or of cylindrical shells, and the lateral elements take the form of corrugated or flat sheets. 5. The apparatus according to claim 1 , wherein the apparatus has multiple layers formed from transverse elements and arranged one on top of another. 6. The apparatus according to claim 1 , wherein multiple parallel transverse elements or transverse elements in the form of concentric elliptical arcs in a radial direction are used, and in a top view these are arranged as concentric polygons, or concentric ellipses. 7. The apparatus according to claim 1 , wherein separating elements can be inserted into gaps between adjacent transverse elements in a circumferential direction. 8. The apparatus according to claim 1 , wherein flat sheets can be interleaved between two layers of transverse elements arranged one on top of the other. 9. The apparatus according to claim 1 , wherein the apparatus is supported by a foundation and is connected thereto by a disconnectable connection. 10. The apparatus according to claim 1 , wherein the apparatus has a lining of refractory bricks and; or catalysts arranged within the modular framework system. 11. The apparatus according to claim 10 , wherein the framework system can be divided into boxes, wherein a box is understood to mean the region enclosed by two parallel transverse elements or transverse elements in a form of concentric elliptical arcs that are adjacent in a radial direction and the corresponding lateral elements, and wherein there is a gap between adjacent transverse elements in a circumferential direction wherein a separating element can be advantageously inserted into this gap; and wherein the boxes are each filled with 1 to 2000 refractory bricks or with catalysts; and wherein the bricks are arranged in a form of layers in the vertical and horizontal directions and there is a gap between the bricks and framework elements that bound the box. 12. The apparatus according to claim 10 , wherein the lining of refractory bricks comprises a brick assembly comprising multiple brick packings arranged successively in a radial direction and comprising (i) foamed ceramic and (ii) sintered cast or extruded ceramic; or (i) foamed ceramic, (ii) sintered cast or extruded ceramic, and (iii) compressed ceramic fibers; or (i) foamed ceramic, (ii) sintered cast or extruded ceramic, (iii) compressed ceramic fibers, and (iv) vacuum-formed fiberboards or boards comprising microporous fumed silica. 13. The apparatus according to claim 10 , wherein a gap between the bricks and adjacent framework elements and/or a gap between brick packings that are adjacent in a circumferential direction is at least partly filled with insulation mats. 14. The apparatus according to claim 1 , wherein there is a continuous gap between the modular framework system and the pressure-rated apparatus shell. 15. The apparatus according to claim 14 , wherein the gap is purged by a directed gas stream. 16. A method of reacting compounds, the method comprising: preparing compounds in the apparatus according to claim 1 , wherein a preparation is selected from the group consisting of preparation of synthesis gas by reforming hydrocarbons with steam and/or carbon dioxide, preparation of hydrogen and carbon as coproducts by pyrolysis of hydrocarbons, preparation of hydrogen cyanide from methane and ammonia or from propane and ammonia, preparation of olefins by steamcracking of hydrocarbons, coupling of methane to give ethylene, acetylene and/or benzene, preparation of olefins by dehydrogenation of alkanes, preparation of styrene by dehydrogenation of ethylbenzene, preparation of diolefins by dehydrogenation of alkanes or olefins, preparation of aldehydes by dehydrogenation of alcohols, preparation of carbon monoxide by Boudouard reaction from carbon dioxide and carbon, and preparation of hydrogen and oxygen by water thermolysis over catalysts.
Hydrogen production from non-carbon containing sources, e.g. by water electrolysis · CPC title
Stationary reactors without moving elements inside (B01J19/08, B01J19/26 take precedence; with stationary particles B01J8/02) · CPC title
Component parts of these vessels not mentioned in B01J3/004, B01J3/006, B01J3/02 - B01J3/08; Measures taken in conjunction with the process to be carried out, e.g. safety measures · CPC title
Multiwall, strip or filament wound vessels (for pressurised gas vessels F17C1/06; for making them B29) · CPC title
Pyrolysis reactions (of hydrocarbons C10G9/00) · CPC title
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