Systems and process for controlling a sulfur extraction from a hydrocarbon stream

Patent metadata

Field	Value
Publication number	US-11898103-B2
Application number	US-202217820275-A
Country	US
Kind code	B2
Filing date	Aug 17, 2022
Priority date	Oct 29, 2021
Publication date	Feb 13, 2024
Grant date	Feb 13, 2024

Abstract

Systems and processes for removing sulfur compounds from a hydrocarbon stream. Sulfur compounds are extracted from a hydrocarbon feed stream with a caustic stream to provide a treated hydrocarbon stream and a rich caustic stream. The sulfur compounds in the rich caustic stream are oxidized in the presence of a catalyst to provide a lean caustic stream. The lean caustic stream is returned to extract sulfur from the hydrocarbon stream. Data such as a concentration of sulfurs species and degree of caustic saturation with the sulfur species in the rich caustic stream may be provided by a sensor, compared against other real-time or historical data and used to provide a recommended adjustment to process conditions associated with an extraction unit, or an oxidation unit, or both.

First claim

What is claimed is:

1. A process for removing sulfur compounds from a hydrocarbon stream, the process comprising:
extracting sulfur compounds with a caustic stream from a hydrocarbon feed stream to provide a treated hydrocarbon stream and a rich caustic stream;
obtaining a data, regarding the rich caustic stream, comprising a concentration of sulfurs species and degree of caustic saturation with the sulfur species in the rich caustic stream;
oxidizing the sulfur compounds in the rich caustic stream in a presence of a catalyst to provide a lean caustic stream;
comparing the data regarding the rich caustic stream to a second data; and,
based on the comparing, recommending at least one change to an operating condition associated with the process for removing sulfur compounds from the hydrocarbon stream.

2. The process of claim 1 , further comprising:
implementing the at least one change to the operating condition.

3. The process of claim 1 , further comprising:
obtaining a data regarding the lean caustic stream, wherein the second data comprises the data regarding the lean caustic stream.

4. The process of claim 1 , wherein the second data comprises a concentration of sulfurs species and degree of caustic saturation with the sulfur species in the lean caustic stream.

5. The process of claim 1 , further comprising:
obtaining a supplemental data regarding one or more process conditions associated with the process for removing sulfur compounds from the hydrocarbon stream,
wherein recommending the at least one change to the operating condition associated with the process is further based on the supplemental data.

6. The process of claim 5 , wherein the supplemental data comprises:
data relating to a spent air, or
data relating to the hydrocarbon feed stream, or
data relating to the treated hydrocarbon stream, or
any combination thereof.

7. The process of claim 1 , wherein the at least one change to the operating condition associated with the process comprises:
an adjustment of an amount of caustic mixed with the hydrocarbon feed stream,
or an adjustment of an amount of catalyst added to the rich caustic stream, or
an adjustment to an amount of oxidant mixed with the rich caustic stream, or
an adjustment to an amount of fresh caustic added to the process, or
an adjustment to an amount of water added to the process, or
an adjustment to an operating temperature of an oxidation unit, or
any combination thereof.

8. A process for controlling removal of sulfur compounds from a hydrocarbon stream with a caustic stream to provide a treated hydrocarbon stream and a rich caustic stream, the process comprising:
obtaining a data, regarding the rich caustic stream, comprising a concentration of sulfurs species and degree of caustic saturation with the sulfur species in the rich caustic stream;
oxidizing the sulfur compounds in the rich caustic stream in a presence of a catalyst to provide a lean caustic stream;
obtaining a data regarding the lean caustic stream;
comparing the data regarding the rich caustic stream to the data regarding the lean caustic stream; and,
based on the comparing, recommending at least one change to an operating condition associated with the process for controlling removal of sulfur compounds from a hydrocarbon stream.

9. The process of claim 8 , wherein the at least one change to the operating condition associated with the process comprises:
an adjustment of an amount of caustic mixed with the hydrocarbon stream, or an
adjustment of an amount of catalyst added to the rich caustic stream, or
an adjustment to an amount of oxidant mixed with the rich caustic stream, or
an adjustment to an amount of fresh caustic added to the process for controlling removal of sulfur compounds from a hydrocarbon stream, or
an adjustment to an amount of water added to the process for controlling removal of sulfur compounds from a hydrocarbon stream, or
an adjustment to an operating temperature of an oxidation unit, or any combination thereof.

10. The process of claim 9 , wherein the data regarding the lean caustic stream comprises a concentration of sulfurs species and degree of caustic saturation with the sulfur species in the lean caustic stream.

11. The process of claim 8 , further comprising:
obtaining a supplemental data regarding one or more process conditions for the process for controlling removal of sulfur compounds from a hydrocarbon stream,
wherein recommending the at least one change to the operating condition associated with the process is further based on the supplemental data.

12. The process of claim 11 , wherein the supplemental data comprises:
data relating to a spent air, or
data relating to the hydrocarbon stream, or
data relating to the treated hydrocarbon stream, or
any combination thereof.

Assignees

• Uop Llc

Inventors

• Trucko Jessy E
• Shi Yili
• Lehuta Keith

Classifications

• C10G19/08

  Recovery of used refining agents · CPC title

• C10G27/12

  with oxygen-generating compounds, e.g. per-compounds, chromic acid, chromates (plumbites or plumbates C10G19/06) · CPC title

• C10G53/14

  including at least one oxidation step · CPC title

• C10G27/04 Primary

  with oxygen or compounds generating oxygen · CPC title

• C10G21/30 Primary

  Controlling or regulating · CPC title