Use of granite waste powder in lightweight oilwell cement systems; strength analysis

Patent metadata

Field	Value
Publication number	US-11898089-B2
Application number	US-202217900360-A
Country	US
Kind code	B2
Filing date	Aug 31, 2022
Priority date	Mar 9, 2022
Publication date	Feb 13, 2024
Grant date	Feb 13, 2024

Abstract

A method for treating a well in a hydrocarbon-producing subterranean production zone. The method for treating well-producing hydrocarbons from a subterranean production zone includes dry mixing a granite waste powder (GWP) in a form of rock aggregates and a cement to form a mixture. Then the mixture is added to the cement composition containing water, pre-hydrated sodium bentonite, calcium chloride, a dispersant, and an alcohol-based defoamer to form a cement slurry. The cement slurry is prepared at a density of from 13.5 pounds per gallon (ppg) to 14.5 ppg and contains the GWP in a range of from 5 wt. % to 20 wt. % of the cement slurry. 10 wt. % to 15 wt. % perlite is added into the cement slurry to form a ternary blend which is cured and then the cured product is injected into the well to seal the well at the subterranean production zone.

First claim

The invention claimed is:

1. A method for treating a well in a hydrocarbon-producing subterranean production zone, comprising:
dry mixing granite waste powder (GWP) and cement to form a mixture;
wherein the GWP has a D 50 diameter of from 10 μm to 100 μm; and
mixing the mixture with an aqueous composition containing water, pre-hydrated sodium bentonite, calcium chloride, a dispersant, and an alcohol-based defoamer to form a cement slurry;
wherein the cement slurry has a density of from 13.5 pounds per gallon (ppg) to 14.5 ppg and contains the GWP in a range of from 5 wt. % to 20 wt. % of the cement slurry; and
adding 10 wt. % to 15 wt. % of perlite into the cement slurry to form a ternary blend;
injecting the ternary blend into the well at the hydrocarbon-producing subterranean production zone;
curing the ternary blend to seal a wall of the well at the hydrocarbon-producing subterranean production zone; and
wherein the cured ternary blend has a compressive strength of from 30,000 pounds per square inch (psi) to 50,000 psi at an effective pressure of 15,000 psi in the well.

2. The method of claim 1 , wherein the curing takes place for approximately 48 hours; and
the GWP has a pozzolanic reaction with the cement during the curing producing a strength activity of from 100% to 110% compared to the cement.

3. The method of claim 2 , wherein the curing is at a bottomhole circulating temperature (BHCT) of 100 to 130° F., a bottomhole static temperature (BHST) of 160 to 170° F., and a bottomhole pressure (BHP) of 2550 to 2600 psi.

4. The method of claim 1 , wherein mixing the GWP and the cement to form the mixture includes blending at a speed of 20,000 to 25,000 rotations per minute (rpm).

5. The method of claim 1 , wherein the cement slurry consists of the pre-hydrated sodium bentonite, the calcium chloride, the dispersant, and the alcohol-based defoamer.

6. The method of claim 1 , wherein the ternary blend has a thickening time of from 120 minutes to 175 minutes which is measured at a BHCT of 100 to 130° F.

7. The method of claim 1 , wherein the cement has an amount of CaO of from 75 wt. % to 80 wt % of the cement, an amount of SiO 2 of from 5 wt. % to 8 wt. % of the cement, and an amount of Fe 2 O 3 of from 8 wt. % to 12 wt. % of the cement.

8. The method of claim 1 , wherein the GWP has an amount of SiO 2 of from 60 wt. % to 65 wt. % of the GWP, an amount of Fe 2 O 3 of from 15 wt. % to 21 wt. % of the GWP, and an amount of Al 2 O 3 of from 7 wt. % to 14 wt. % of the GWP.

9. The method of claim 1 , wherein the perlite has an amount of SiO 2 of from 70 wt. % to 75 wt. % of the perlite, an amount of Fe 2 O 3 of from 1 wt. % to 2 wt. % of the perlite, and an amount of Al 2 O 3 of from 9 wt. % to 15 wt. % of the perlite.

10. The method of claim 2 , wherein the cured ternary blend has a density of 3 to 4 g/cm 3 .

11. The method of claim 2 , wherein the GWP has a D 50 diameter of from 20 μm to 50 μm.

12. The method of claim 1 , wherein the cement slurry has a sonic strength of from 650 psi to 1050 psi.

13. The method of claim 1 , wherein the ternary blend has a sonic strength of from 200 psi to 1575 psi.

14. The method of claim 1 , wherein the GWP is present in the cement slurry in a range of from 5 wt. % to 15 wt. % of the cement slurry; and
the perlite is present in the cement slurry in a range of from 10 wt. % to 15 wt. % of the cement slurry perlite.

15. The method of claim 14 , wherein the ternary blend comprises:
the cement in an amount of from 80 wt. % to 85 wt. % of the ternary blend, the GWP in an amount of from 5 wt. % to 15 wt. % of the ternary blend, the perlite in an amount of from 5 wt. % to 10 wt. % of the ternary blend, the CaCl 2 in an amount of 1 to 2 wt. % of the ternary blend, the bentonite in an amount of at least 2 wt. % of the ternary blend, a defoamer mass of 0.5 to 2 g, and has a water to cement ratio of from 80% to 85%.

16. The method of claim 14 , wherein the ternary blend comprises:
the cement in an amount of from 55 wt. % to 65 wt. % of the ternary blend, the GWP in an amount of from 5 wt. % to 15 wt. % of the ternary blend, the perlite in an amount of from 5 wt. % to 10 wt. % of the ternary blend, the CaCl 2 in an amount of 1 to 2 wt. % of the ternary blend, the bentonite in an amount of at least 2 wt. % of the ternary blend, a defoamer mass of 0.5 to 2 g, and a water to cement ratio of from 75% to 80%.

17. The method of claim 14 , wherein the ternary blend comprises:
the cement in an amount of from 45 wt. % to 55 wt. % of the ternary blend, the GWP in an amount of from 5 wt. % to 15 wt. % of the ternary blend, the perlite in an amount of from 10 wt. % to 15 wt. % of the ternary blend, the CaCl 2 in an amount of 1 to 2 wt. % of the ternary blend, the bentonite in an amount of at least 2 wt. % of the ternary blend, a defoamer mass of 0.5 to 2 g, and a water to cement ratio of from 75% to 80%.

18. The method of claim 14 , wherein the perlite has a density of 2.60 to 3.5 g/cm 3 .

19. The method of claim 14 , wherein an amount of silica, alumina, and iron oxide in the ternary blend exceeds 70 wt. % based on the total weight of the ternary blend.

20. The method of claim 14 , wherein the perlite has a D 50 diameter of from 70 μm to 100 μm.

Assignees

• Univ King Fahd Pet & Minerals

Inventors

• Elkatatny Salaheldin
• Adjei Stephen

Classifications

• C09K8/48 Primary

  Density increasing or weighting additives · CPC title

• C04B14/06

  Quartz; Sand · CPC title

• C04B14/104

  Bentonite, e.g. montmorillonite · CPC title

• C04B14/18

  Perlite · CPC title

• C04B14/308

  Iron oxide · CPC title