Polymer dispersant for well cementing

Patent metadata

Field	Value
Publication number	US-11898087-B2
Application number	US-202117529382-A
Country	US
Kind code	B2
Filing date	Nov 18, 2021
Priority date	Nov 18, 2021
Publication date	Feb 13, 2024
Grant date	Feb 13, 2024

Abstract

The present disclosure concerns a cement dispersant for cement compositions wherein the cement dispersant is a polynaphthalene sulfonate salt having a weight average molecular weight of from 2500 g/mol to 3000 g/mol. The cement compositions are of from 10 weight percent to 70 weight percent of a cement precursor based on the total weight of the cement composition, from 5 weight percent to 70 weight percent water based on the total weight of the cement composition, and from 0.001 percent by weight of cement (BWOC) to 1.0 percent BWOC the cement dispersant. The cement dispersant provides improved rheological properties, allowing for good cement dispensing and increased presence of weighting agents.

First claim

What is claimed is:

1. A cement composition comprising:
from 10 weight percent to 70 weight percent cement precursor based on the total weight of the cement composition;
from 5 weight percent to 70 weight percent water based on the total weight of the cement composition; and
from 0.001 percent by weight of cement (BWOC) to 1.0 percent BWOC cement dispersant, where the cement dispersant comprises a polynaphthalene sulfonate salt having a weight average molecular weight of from 2500 g/mol to 3000 g/mol and wherein the cement dispersant comprises from 92 weight percent to 95 weight percent polynaphthalene sulfonate based on the total weight of the cement dispersant.

2. The cement composition of claim 1 , where the polynaphthalene sulfonate salt has a weight average molecular weight of from 2700 g/mol to 2800 g/mol.

3. The cement composition of claim 1 , wherein the polynaphthalene sulfonate salt has a weight average molecular weight of 2774 g/mol.

4. The cement composition of claim 1 , wherein the polynaphthalene sulfonate salt comprises one or more cations selected from the group consisting of sodium, lithium, potassium, ammonium, and combinations of these.

5. The cement composition of claim 4 , wherein the polynaphthalene sulfonate salt is sodium polynaphthalene sulfonate.

6. The cement composition of claim 1 , wherein the cement dispersant further comprises formaldehyde, acetone, or both.

7. The cement dispersant of claim 6 , wherein the cement dispersant comprises from 5 weight percent (wt. %) to 8 wt. % water based on the total weight of the cement dispersant.

8. The cement composition of claim 1 , where the cement precursor is an American Petroleum Institute (API) Class G cement.

9. The cement composition of claim 1 , further comprising a weighting agent selected from sand, barite (barium sulfate), hematite, calcium carbonate, siderite, ilmenite, silica sand, manganese oxide (MnO), hausmanite (manganese tetroxide (Mn 3 O 4 )), zinc oxide, zirconium oxide, iron oxide, fly ash, or any combination thereof.

10. The cement composition of claim 1 , further comprising at least one additive selected from the group consisting of an expansion additive, a silica sand, a cement retarder, a defoamer, a gelling agent, and combinations of these.

11. The cement composition of claim 1 , further comprising:
from greater than 0 percent BWOC to less than or equal to 10 percent BWOC of an expansion additive;
from greater than 0 percent BWOC to less than or equal to 20 percent BWOC silica sand;
from greater than 0 percent BWOC to less than or equal to 5 percent BWOC defoamer; and
from greater than 0 percent BWOC to less than or equal to 10 percent BWOC gelling agent.

12. The cement composition of claim 1 , further comprising about 16% BWOC silica sand, about 0.005% BWOC expansion additive, about 16% BWOC weighting additive; 0.0001% BWOC defoamer; 0.003% BWOC cement retarder and about 20% BWOC water.

13. The cement composition of claim 1 , where the cement composition has a plastic viscosity (PV) of from 1 centepoise (cP) to 200 cP at room temperature prior to curing of the cement composition.

14. The cement composition of claim 1 , where the cement composition has a 10 second gel strength greater than or equal to 4 pounds of force per 100 square feet (lb f /100 ft 2 ), as determined according to the method in the API Recommended Practice for Cementing.

15. The cement composition of claim 1 , where the cement composition has a yield point (YP) of from 5.5 pounds of force per 100 square feet (lb f /100 ft 2 ) to 17.5 lb f /100 ft 2 at room temperature within 20 minutes of preparing the cement composition.

16. The cement composition of claim 1 , wherein the cement dispersant consists of polynaphthalene sulfonate salt, water, acetone and formaldehyde.

17. A method for cementing a wellbore, the method comprising:
dispensing a cement composition into an annulus defined between a tubular string and an inner wall of a wellbore or between two tubular strings, where the cement composition comprises:
from 10 weight percent to 70 weight percent cement precursor based on the total weight of the cement composition;
from 5 weight percent to 70 weight percent water based on the total weight of the cement composition; and
from 0.001 percent by weight of cement (BWOC) to 1.0 percent BWOC cement dispersant, where the cement dispersant comprises a polynaphthalene sulfonate salt having a weight average molecular weight of from 2500 g/mol to 3000 g/mol and wherein the cement dispersant comprises from 92 weight percent to 95 weight percent polynaphthalene sulfonate based on the total weight of the cement dispersant; and
allowing the cement composition to cure in the annulus to form a cured cement, where the cement dispersant increases the rheological properties.

18. The method of claim 17 , further comprising drilling a portion of a wellbore and placing a tubular string in the wellbore.

19. The method of claim 17 , further comprising preparing the cement composition by:
combining the cement precursor and water to prepare a cement slurry;
combining the cement retarder with the cement slurry to produce the cement composition; and
mixing the cement composition to obtain a homogeneous mixture.

Assignees

• Saudi Arabian Oil Co

Inventors

• Alanqari Khawlah A
• Wagle Vikrant
• Al-Yami Abdullah
• Al-Safran Ali

Classifications

• C09K8/467 Primary

  containing additives for specific purposes · CPC title

• C09K8/48

  Density increasing or weighting additives · CPC title

• C04B28/02

  containing hydraulic cements other than calcium sulfates · CPC title

• C04B24/223

  Sulfonated melamine-formaldehyde condensation products · CPC title

• C04B2103/408

  Dispersants · CPC title