Processes and systems for treating sour water

Patent metadata

Field	Value
Publication number	US-11897794-B2
Application number	US-202218061147-A
Country	US
Kind code	B2
Filing date	Dec 2, 2022
Priority date	Dec 3, 2019
Publication date	Feb 13, 2024
Grant date	Feb 13, 2024

Abstract

Processes for producing olefins may include electrolyzing an aqueous solution comprising metal chloride, where electrolyzing the aqueous solution causes at least a portion of the metal chloride to undergo chemical reaction to produce a treatment composition comprising hypochlorite. The processes may further include contacting at least a portion of the treatment composition with the sour water at a pH from 8 to 12, where the sour water comprises sulfides and the contacting causes reaction of the sulfides in the sour water with the hypochlorite to produce a treated aqueous mixture comprising at least metal sulfates and metal chlorides, where the metal sulfates are present in the treated aqueous mixture as precipitated solids. The processes may further include separating the precipitated solids from the treated aqueous mixture to produce a treated effluent comprising at least the metal chloride.

First claim

What is claimed is:

1. A system for treating sour water, the system comprising:
an aqueous solution preparation system comprising an aqueous solution comprising from 15 percent by weight (wt. %) to 30 wt. % of metal chloride and from 1 wt. % to 10 wt. % of metal hydroxide based on the total weight of the aqueous solution, where a metal of the metal chloride and a metal of the metal hydroxide comprise strontium, barium, or both;
an electrolyzer disposed downstream from the aqueous solution preparation system, the electrolyzer comprising at least one anode, at least one cathode, and a power source electrically coupled to the at least one anode and the at least one cathode, the electrolyzer operable to pass an electric current through the aqueous solution to produce a treatment composition comprising hypochlorite;
a reactor downstream from the electrolyzer, where the reactor has a sour water inlet operable to introduce the sour water to the reactor, and the reactor is operable to contact at least a portion of the treatment composition comprising the hypochlorite with the sour water at a pH from 8 to 12; and
a separation device downstream from the reactor, where the separation device is operable to separate precipitated solids from a treated aqueous mixture to produce a solid product comprising metal sulfates and metal carbonates and a treated effluent comprising the metal chloride.

2. The system of claim 1 , where the treated effluent further comprises the metal hydroxide.

3. The system of claim 2 , further comprising a vacuum crystallization system downstream from the separation device, the vacuum crystallization system being operable to crystallin at least a portion of the metal chlorides and metal hydroxides in the treated effluent to form a crystallized product in the aqueous solution.

4. The system of claim 3 , further comprising a second separation device downstream from the vacuum crystallization system, in which the second separation device is operable to separate the metal chloride and the metal hydroxide from the crystallization effluent to produce a crystallized solid and an ammonium chloride solution.

5. The system of claim 4 , further comprising a recycle line fluidly coupled to the second separation device or the vacuum crystallization system and to the aqueous solution preparation system, the recycle line operable to recycle the crystallized solid back to the aqueous solution preparation system.

6. The system of claim 1 , where:
the sour water comprises sulfides and the contacting causes reaction of the sulfides in the sour water with the hypochlorite to produce the treated aqueous mixture comprising at least metal sulfates and metal chlorides, where the metal sulfates are present in the treated aqueous mixture as precipitated solids.

7. The system of claim 3 , further comprising a condenser downstream of and fluidly coupled to the vacuum crystallization system, the condenser operable to condense water vapor from a water vapor outlet of the vacuum crystallization system to produce a purified water effluent.

8. The system of claim 7 , where the condenser is fluidly coupled to the aqueous solution preparation system to pass the purified water from the condenser directly to the aqueous solution preparation system.

9. The system of claim 1 , where the metal hydroxide is operable to maintain a pH in the electrolyzer in a range of from 8 to 12.

10. The system of claim 1 , where the metal hydroxide is operable to maintain a pH in the reactor in a range of from 8 to 12.

11. The system of claim 1 , where the treatment composition is passed from the electrolyzer to the reactor.

12. The system of claim 1 , where the electrolyzer is fluidly coupled to the reactor.

13. The system of claim 1 , wherein the electrolyzer comprises a vessel, a plurality of anodes, and a plurality of cathodes, where the plurality of anodes and the plurality of cathodes are distributed throughout the vessel.

Assignees

• Saudi Arabian Oil Co

Inventors

• Raynel Guillaume Robert Jean-Francois

Classifications

• C02F1/5236 Primary

  using inorganic agents · CPC title

• C02F1/46109

  Electrodes · CPC title

• C02F1/5281

  Installations for water purification using chemical agents · CPC title

• C25B1/26

  Chlorine; Compounds thereof (by simultaneous production of alkali metal hydroxides and chlorine, oxyacids or salts of chlorine C25B1/34) · CPC title

• C02F2001/5218

  Crystallization · CPC title