Perovskite materials for ionizing radiation detection and related methods

Patent metadata

Field	Value
Publication number	US-11897784-B2
Application number	US-202117644886-A
Country	US
Kind code	B2
Filing date	Dec 17, 2021
Priority date	Dec 18, 2020
Publication date	Feb 13, 2024
Grant date	Feb 13, 2024

Abstract

In accordance with the purpose(s) of the present disclosure, as embodied and broadly described herein, the disclosure, in one aspect, relates to compound Bi-poor perovskite crystals, methods for making the same, and ionizing and other electromagnetic radiation detectors constructed using the Bi-poor perovskite crystals. The Bi-poor perovskite crystals can be synthesized using melt-based growth methods and solution-based growth methods and contain no toxic heavy metals such as lead, cadmium, thallium, or mercury. Devices fabricated from the crystals maintain acceptable levels of performance over time. In some aspects, post-growth annealing can be used to improve the properties, including, but not limited to, room temperature resistivity and response to radiation.

First claim

What is claimed is:

1. A Bi-poor perovskite crystal having the formula Cs 2 AgBi x Br 6 , wherein x is less than 1.

2. An annealed Bi-poor perovskite crystal produced by the process of holding the Bi-poor perovskite crystal of claim 1 at an annealing temperature of between about 25° C. to about 450° C. for a period of from about 1 minute to about 90 days.

3. The Bi-poor perovskite crystal of claim 1 , wherein the Bi-poor perovskite crystal comprises a three-dimensional perovskite structure, a low-dimensional perovskite structure, or any combination thereof.

4. The Bi-poor perovskite crystal of claim 1 , wherein the Bi-poor perovskite crystal is substantially free of lead, cadmium, thallium, and mercury.

5. The Bi-poor perovskite crystal of claim 2 , wherein the Bi-poor perovskite crystal comprises a crystal resistivity of from about 1.0×10 5 Ω·cm to about 1.0×10 14 Ω·cm.

6. The Bi-poor perovskite crystal of claim 2 , wherein the Bi-poor perovskite crystal has a Young's modulus of from about 20 to about 45 GPa.

7. The Bi-poor perovskite crystal of claim 2 , wherein the Bi-poor perovskite crystal has a hardness as measured by indentation with a Berkovich tip of from about 0.5 GPa to about 1.5 GPa.

8. A radiation detector comprising:
(a) the Bi-poor perovskite crystal of claim 2 ; and
(b) one or more electrodes in contact with the Bi-poor perovskite crystal.

9. The radiation detector of claim 8 , wherein the Bi-poor perovskite crystal comprises a first side and a second side, and the one or more electrodes are in contact with the first side, the second side, or both.

10. The radiation detector of claim 8 , wherein the electrodes comprise gold, platinum, silver, gallium, indium, bismuth, nickel, carbon, or any combination thereof.

11. The radiation detector of claim 8 , wherein the one or more electrodes comprise one or more bias electrodes and a measurement electrode.

12. A method for detecting radiation comprising:
(a) exposing the radiation detector of claim 8 to radiation and applying a bias voltage to the bias electrodes, wherein the radiation induces an electronic signal in the detector; and
(b) measuring the electronic signal;
wherein, when radiation is present, the electronic signal includes at least one feature that is absent when radiation is absent.

13. The method of claim 12 , wherein the bias voltage is from about −10,000 V to about 10,000 V.

14. The method of claim 12 , wherein the electronic signal comprises a current, a change of measured current, or both.

15. The method of claim 12 , wherein the at least one feature comprises a peak in the energy spectrum located at about 59.5 keV.

16. The method of claim 12 , wherein the current from a detector containing an annealed perovskite crystal has an intensity of from about 2× to about 20× an intensity of the current from a detector containing an identical perovskite crystal that has not been annealed, when the same bias voltage is applied.

17. The method of claim 12 , wherein the radiation is ionizing radiation.

18. The method of claim 17 , wherein the ionizing radiation is X-ray radiation, gamma-ray radiation, alpha radiation, beta radiation, ultraviolet radiation, or any combination thereof.

19. The method of claim 17 , wherein the ionizing radiation is emitted from an Am-241 radioactive source, a Na-22 radioactive source, a Cs-137 radioactive source, a Co-57 radioactive source, a Ba-133 radioactive source, a Cd-109 radioactive source, or any combination thereof.

20. The method of claim 12 , wherein the radiation is extended UV, visible, or near infra-red (NIR) radiation having a wavelength of from about 310 nm to about 1600 nm.

Assignees

• Univ North Carolina State

Inventors

• Yang Ge
• Zhang Zheng

Classifications

• C01G29/006 Primary

  Compounds containing bismuth, with or without oxygen or hydrogen, and containing two or more other elements · CPC title

• C09K11/7435 Primary

  with alkali or alkaline earth metals · CPC title

• C30B7/14

  the crystallising materials being formed by chemical reactions in the solution · CPC title

• C30B29/12

  Halides · CPC title

• G01T1/16

  Measuring radiation intensity (G01T1/29 takes precedence {; self-powered detectors G01T3/006; using an ionisation chamber filled with a liquid or solid, e.g. frozen liquid, dielectric G01T3/008}) · CPC title