Method for producing a multicoat paint system by postadditization of at least one basecoat with an aqueous dispersion comprising polyamides and/or amide waxes

Patent metadata

Field	Value
Publication number	US-11896998-B2
Application number	US-201917284527-A
Country	US
Kind code	B2
Filing date	Sep 30, 2019
Priority date	Oct 12, 2018
Publication date	Feb 13, 2024
Grant date	Feb 13, 2024

Abstract

Described herein is a method for producing a multicoat paint system by producing a basecoat or a plurality of directly successive basecoats directly on a substrate coated with a first coat, producing a clearcoat directly on the one or the topmost of the plurality of basecoats, and subsequently jointly curing the one or the plurality of basecoats and the clearcoat. At least one of the basecoat materials is admixed, directly before application, either with an aqueous dispersion (D1) including a polyamide (PA) having an acid number of 15 to 60 mg KOH/g or with an aqueous dispersion (D2) including a polyamide (PA) and an amide wax (AW).

First claim

What is claimed is:

1. A method for producing a multicoat paint system (M) on a substrate (S), comprising
(1) optionally producing a cured first coat (S1) on the substrate (S) by application of a composition (Z1) to the substrate (S) and subsequent curing of the composition (Z1),
(2) producing a basecoat (BL2a) or two or more directly successive basecoats (BL2-x) directly on the first coat (S1) by application of an aqueous basecoat material (bL2a) directly to the first coat (S1) or directly successive application of two or more aqueous basecoat materials (bL2-x) directly to the first coat (S1),
(3) producing a clearcoat (K) directly on the basecoat (BL2a) or on a topmost basecoat (BL2-z) by application of a clearcoat material (kL) directly to the basecoat (BL2a) or to the topmost basecoat (BL2-z),
(4) jointly curing the basecoat (BL2a) and the clearcoat (K) or the basecoats (BL2-x) and the clearcoat (K),
wherein

the basecoat material (bL2a) or at least one of the basecoat materials (bL2-x), directly prior to application, is mixed
with an aqueous dispersion (D1) comprising at least one polyamide (PA) having an acid number of 20 to 50 mg KOH/g or
with an aqueous dispersion (D2) comprising at least one polyamide (PA) and at least one amide wax (AW).

2. The method as claimed in claim 1 , wherein the substrate (S) is selected from the group consisting of metallic substrates, plastics, and mixtures thereof.

3. The method as claimed in claim 1 , wherein two directly successive basecoats (BL2-a) and (BL2-z) are produced on the cured first coat (S1) by applying the aqueous basecoat material (bL2a) directly to the first coat (S1) and directly subsequently applying a further aqueous basecoat material (bL2-z) directly to the first basecoat (BL2-a).

4. The method as claimed in claim 1 , wherein the basecoat material (bL2a) or at least one of the basecoat materials (bL2-x), are one-component coating compositions.

5. The method as claimed in claim 1 , wherein the basecoat material (bL2a) or at least one of the basecoat materials (bL2-x), comprises at least one polymer as binder, selected from the group consisting of hydroxyfunctional polyurethanes, polyesters, polyacrylates, and copolymers of these polymers.

6. The method as claimed in claim 1 , wherein the basecoat material (bL2a) or at least one of the basecoat materials (bL2-x) comprises at least one color and/or effect pigment.

7. The method as claimed in claim 1 , wherein the basecoat material (bL2a) or at least one of the basecoat materials (bL2-x), comprises at least one melamine resin as crosslinking agent.

8. The method as claimed in claim 1 , wherein the at least one polyamide (PA) in the dispersion (D1) and (D2) is a product of reaction of
a diamine having 2 to 34 carbon atoms and
a molar excess, based on the diamine, of a dicarboxylic acid having 4 to 36 carbon atoms, or of a mixture of a dicarboxylic acid having 4 to 36 carbon atoms and a monocarboxylic acid having 2 to 22 carbon atoms.

9. The method as claimed in claim 1 , wherein the at least one polyamide (PA) in the dispersion (D1) and (D2) is neutralized to an extent of 80% to 100% with a base.

10. The method as claimed in claim 1 , wherein the at least one amide wax (AW) in the dispersion (D2) is a product of reaction of
a monocarboxylic acid having 2 to 22 carbon atoms, and
a diamine having 2 to 12 carbon atoms, and/or a monoamine having 2 to 22 carbon atoms.

11. The method as claimed in claim 1 , wherein the aqueous dispersion (D2) has a weight ratio of polyamide (PA) to amide wax (AW) of 95:5 to 40:60.

12. The method as claimed in claim 1 , wherein the aqueous dispersion (D1) or (D2) is added to the basecoat material (bL2a) which is applied directly to the first coat (S1).

13. The method as claimed in claim 1 , wherein the aqueous dispersion (D1) or (D2) is added after the establishment of the slumping of the basecoat (BL2a) or of at least one of the basecoats (BL2-x), the aqueous dispersion (D1) or (D2) being added to the basecoat material (bL2a) or at least one of the basecoat materials (bL2-x) that has slipped from the underlying coat.

14. The method as claimed in claim 1 , wherein the joint curing (4) is carried out at temperatures of 100 to 250° C. for a time of 5 to 60 minutes.

15. The method as claimed in claim 1 , wherein the substrate (S) is selected from the group consisting of metallic substrates.

16. The method as claimed in claim 1 , wherein all basecoat materials (bL2-x) are one-component coating compositions.

17. The method as claimed in claim 1 , wherein all basecoat materials (bL2-x) comprise at least one polymer as binder, selected from the group consisting of hydroxy-functional polyurethanes, polyesters, polyacrylates, and copolymers of these polymers.

18. The method as claimed in claim 1 , wherein all basecoat materials (bL2-x) comprise at least one color and/or effect pigment.

19. The method as claimed in claim 1 , wherein all basecoat materials (bL2-x) comprise at least one melamine resin as crosslinking agent.

20. The method as claimed in claim 1 , wherein the aqueous dispersion (D1) has a solids content of 21 to 25 wt. %, based on a total weight of the aqueous dispersion (D1).

Assignees

• Basf Coatings Gmbh

Inventors

• Eierhoff Dirk
• Schwarz Joerg
• Hellwig Silke

Classifications

• B05D7/572 Primary

  all layers being cured or baked together · CPC title

• B05D7/14

  to metal, e.g. car bodies (involving a chemical reaction between the metal and the coating C23) · CPC title

• C08K3/013

  Fillers, pigments or reinforcing additives · CPC title

• C08K5/34922

  Melamine; Derivatives thereof · CPC title

• C08L77/06

  Polyamides derived from polyamines and polycarboxylic acids (C08L77/10 takes precedence) · CPC title