Spinel-based oxides containing magnesium, aluminum and titanium and methods of forming articles having same

Patent metadata

Field	Value
Publication number	US-11891340-B2
Application number	US-201916514876-A
Country	US
Kind code	B2
Filing date	Jul 17, 2019
Priority date	Jul 23, 2018
Publication date	Feb 6, 2024
Grant date	Feb 6, 2024

Abstract

The disclosed technology generally relates dielectric materials, and more particularly to a combination of co-fireable dielectric materials that can be attached to each other without the use of adhesives. In an aspect, a composite article comprises a magnetic portion comprising a nickel zinc ferrite. The composite article additionally comprises a non-magnetic portion contacting the magnetic portion, the non-magnetic portion comprising a spinel-structured oxide comprising Mg2-xAl2xTi1-xO4 and having a dielectric constant between about 7 and 14, wherein 0<x≤1.

First claim

The invention claimed is:

1. A composite article comprising:
a magnetic portion comprising a nickel zinc ferrite; and
a non-magnetic portion contacting the magnetic portion, the non-magnetic portion comprising a spinel-structured oxide comprising Mg 2-x Al 2x Ti 1-x O 4 and having a dielectric constant between about 7 and 14, wherein 0<x<1.

2. The composite article of claim 1 , wherein the magnetic portion has a dielectric constant between 5 and 10.

3. The composite article of claim 1 , wherein the magnetic portion forms an inner portion and the non-magnetic portion forms an outer portion surrounding the inner portion.

4. The composite article of claim 3 , wherein the inner portion has a shape of a disc formed in and contacting an opening formed through the outer portion, and wherein the inner portion and the outer portion are held together without an adhesive therebetween.

5. The composite article of claim 1 , wherein the spinel-structured oxide comprises a solid solution of MgAl 2 O 4 and Mg 2 TiO 4 .

6. The composite article of claim 1 , wherein the non-magnetic spinel-structured oxide further comprises Al 2 O 3 in the amount greater than zero and less than or equal to about 10 percent on the basis of a total weight of the spinel-structured oxide.

7. The composite article of claim 1 , wherein the non-magnetic spinel-structured oxide further comprises ZnTiO 3 in the amount greater than zero and less than or equal to about 10 percent on the basis of a total weight of the spinel-structured oxide.

8. The composite article of claim 1 , wherein the spinel-structured oxide has a density between 3.498 g/cc and 3.569 g/cc.

9. A composite article comprising:
a magnetic portion comprising nickel zinc ferrite; and
a non-magnetic portion comprising a solid solution comprising MgAl 2 O 4 and Mg 2 TiO 4 , the solid solution having a spinel crystal structure and a ratio of magnesium (Mg): aluminum (Al): titanium (Ti) that is represented as (2−x):(2x):(1−x) and 0<x<1.

10. The composite article of claim 9 , wherein the magnetic portion forms an inner portion and the non-magnetic portion forms an outer portion surrounding the inner portion.

11. The composite article of claim 10 , wherein the inner portion has a shape of a disc formed in and contacting an opening formed through the outer portion.

12. The composite article of claim 11 , wherein the non-magnetic portion wraps around the non-magnetic portion with sufficient compressive force such that the non-magnetic portion and the non-magnetic portion are attached to each other without an adhesive.

13. The composite article of claim 9 , wherein the non-magnetic portion has a dielectric constant between about 7 and 14.

14. The composite article of claim 9 , wherein the magnetic portion has a dielectric constant between about 5 and 10.

15. The composite article of claim 9 , wherein the non-magnetic portion further comprises Al2O3 in the amount greater than zero and less than or equal to about 10 weight percent.

16. The composite article of claim 9 , wherein the non-magnetic portion further comprises ZnTiO 3 in the amount greater than zero and less than or equal to about 10 weight percent.

17. A radio frequency (RF) circulator comprising:
a disk-shaped magnetic portion; and
a non-magnetic portion surrounding the disk-shaped magnetic portion, the non-magnetic portion comprising a spinel-structured oxide comprising MgAl 2 O 4 and Mg 2 TiO 4 , the spinel-structured oxide having a ratio of magnesium (Mg): aluminum (Al): titanium (Ti) that is represented as (2−x):(2x):(1−x) and 0<x<1.

18. The RF circulator of claim 17 , wherein the non-magnetic portion has a higher dielectric constant relative to the magnetic portion.

19. The RF circulator of claim 18 , wherein the non-magnetic portion wraps around the non-magnetic portion with sufficient compressive force such that the non- magnetic portion and the non-magnetic portion are attached to each other without an adhesive.

20. The RF circulator of claim 17 , wherein the spinel-structured oxide further comprises one or both of Al 2 O 3 and ZnTiO 3 each in the amount greater than zero and less than or equal to about 10 percent on the basis of a total weight of the spinel-structured oxide.

Assignees

• Skyworks Solutions Inc

Inventors

• Hill Michael David
• Cruickshank David Bowie
• Firor David Martin
• Macfarlane Iain Alexander
• Shunkwiler Jeffrey Alan
• Jiang John Jianzhong

Classifications

• C04B35/465 Primary

  based on alkaline earth metal titanates · CPC title

• B32B18/00

  Layered products essentially comprising ceramics, e.g. refractory products · CPC title

• C04B35/265

  Compositions containing one or more ferrites of the group comprising manganese or zinc and one or more ferrites of the group comprising nickel, copper or cobalt · CPC title

• C04B35/2658

  Other ferrites containing manganese or zinc, e.g. Mn-Zn ferrites · CPC title

• C04B35/64

  Burning or sintering processes (C04B33/32 takes precedence {; powder metallurgy B22F}) · CPC title