Methods and process for producing polymer-metal hybrid components bonded by C—O-M bonds

Patent metadata

Field	Value
Publication number	US-11890788-B2
Application number	US-202117323647-A
Country	US
Kind code	B2
Filing date	May 18, 2021
Priority date	May 20, 2020
Publication date	Feb 6, 2024
Grant date	Feb 6, 2024

Abstract

Methods of producing polymer-metal hybrid components that are bonded by C—O-M bonds at the interface using at least one of the hot pressing, rolling, and injection molding methods to create chemical bond formation conditions at the polymer and metal interface. When the thermal cycle and compressive pressure specified herein is combinationally created at the polymer and metal interfaced, strong C—O-M bonds forms at the interface and strongly bonds the metal and polymer together through the reaction carbonyl groups (C═O) in polymer and the metal surface. For polymers lacking enough carbonyl groups, new functional groups can be in-situ generation through introducing distributed air pockets at the polymer-metal interface for forming 3-dimensional distributed C—O-M bonds at the interface.

First claim

What is claimed is:

1. A method of producing polymer-metal hybrid components that are bonded by C—O-M bonds at a polymer-metal interface, where M represents an element in the metal to be joined, the method comprising:
providing the metal and the polymer;
forming distributed air pockets on at least one surface of the metal using a scratching tool with multiple scribe tips to produce distributed scratching grooves 0.2-0.5 mm in depth on the at least one surface of the metal that traps air at the polymer metal interface, the scratching tool is driven to rotate and travel along the at least one surface;
applying compressive pressure to a polymer-metal interface after the step of forming distributed air pockets on at least one surface of the metal, the applied compressive pressure being higher than a flow resistance of the softened polymer at the polymer-metal interface;
heating the polymer-metal interface to an interfacial temperature above a glass transition temperature of the polymer and maintaining the compressive pressure at the polymer-metal interface to generate intimate atomic contact between the metal and the polymer to create substantially C—O-M chemical bonds along the polymer-metal interface; and
reducing the interfacial temperature below the polymer melting temperature before 5% of the polymer has pyrolyzed to avoid breaking of the C—O-M chemical bonds.

2. The method according to claim 1 , wherein the step of providing the metal and the polymer comprises overlapping the metal and the polymer, and the method further comprises rolling the overlapped metal and polymer during the step of maintaining the interfacial temperature above the glass transition temperature of the polymer.

3. The method according to claim 1 , wherein the step of providing the metal and the polymer comprising overlapping the metal and the polymer.

4. The method according to claim 3 further comprising rolling the overlapped metal and polymer during the step of maintaining the interfacial temperature above the glass transition temperature of the polymer.

5. The method according to claim 4 , wherein the step of heating the polymer-metal interface to an interfacial temperature is performed before the step of rolling.

6. The method according to claim 4 , wherein the step of heating the polymer-metal interface to an interfacial temperature and the step of rolling are performed simultaneously.

7. The method according to claim 1 , wherein the step of providing the metal and the polymer comprising positioning the metal in a mold and injecting polymer into the mold.

8. The method according to claim 7 , wherein the step of heating the polymer-metal interface is performed by heating the polymer and injecting polymer into the mold.

9. The method according to claim 7 , wherein the metal comprises distributed air pockets along at least a portion of a surface thereof.

10. The method according to claim 9 wherein the C—O-M chemical bond are formed from new functional groups created by the reaction of polymer and air trapped within the distributed air pockets.

11. The method according to claim 1 wherein the polymer contains functional groups and is applied on a surface of the metal prior to the step of applying compressive pressure to the polymer-metal interface.

12. The method according to claim 1 wherein the C—O-M chemical bonds are formed from carbonyl groups (C═O) within the polymer.

13. The method according to claim 1 wherein the C—O-M chemical bonds are three-dimensionally distributed along the polymer-metal interface.

14. The method according to claim 1 , wherein the step of applying compressive pressure and the step of heating the polymer-metal interface to the interfacial temperature are achieved using discrete systems.

15. The method according to claim 1 , wherein the step of applying compressive pressure and the step of heating the polymer-metal interface to the interfacial temperature are achieved using a unitary system.

16. The method according to claim 1 , wherein the step of heating the polymer-metal interface to the interfacial temperature above the glass transition temperature of the polymer comprises heating the polymer-metal interface to the interfacial temperature above the glass transition temperature of the polymer and below a flash ignition temperature of the polymer and below a metal melting temperature of the metal.

Assignees

• Univ Michigan Regents

Inventors

• Liu Fengchao
• Dong Pingsha

Classifications

• B29C43/183 Primary

  the preformed layer being a lining, e.g. shaped in the mould before compression moulding, or a preformed shell adapted to the shape of the mould · CPC title

• B29C43/34

  Feeding the material to the mould or the compression means {(B29C43/085 takes precedence)} · CPC title

• B29C43/46

  Rollers · CPC title

• B29C65/64

  Joining a non-plastics element to a plastics element, e.g. by force (B29C65/44 takes precedence) · CPC title

• B29C66/022

  Mechanical pre-treatments, e.g. reshaping · CPC title