Disinfecting materials with intense pulsed light and catalytic microwave-assisted decontamination

Patent metadata

Field	Value
Publication number	US-11890386-B2
Application number	US-202016818795-A
Country	US
Kind code	B2
Filing date	Mar 13, 2020
Priority date	Mar 15, 2019
Publication date	Feb 6, 2024
Grant date	Feb 6, 2024

Abstract

Disinfecting particulate material includes combining the particulate material with a photocatalyst to yield a mixture, irradiating the mixture for a length of time with pulses from a light source having broadband emission spectrum between 190 nm-1100 nm to yield an irradiated mixture, and separating the photocatalyst from the disinfected mixture to yield the disinfected particulate matter. Irradiating the mixture inactivates microorganisms in the mixture to yield a disinfected mixture. A system for disinfecting particulate material includes a pulsed light source having a broadband emission spectrum in a range between about 190 nm and about 1100 nm, a chamber defining a cavity optically coupled to the pulsed light source, a humidifier, a fan, and one or more sensors. The chamber includes a conveyor configured to accept the particulate material and arranged such that the pulses emitted by the pulsed light source irradiate the particulate material on the conveyor.

First claim

What is claimed is:

1. A method of disinfecting particulate material, the method comprising:
combining the particulate material with a photocatalyst to yield a mixture;
irradiating the mixture for a length of time with pulses from a light source having broadband emission spectrum between 190 nm-1100 nm to yield an irradiated mixture, wherein irradiating the mixture inactivates microorganisms in the mixture to yield a disinfected mixture; and
separating the photocatalyst from the disinfected mixture to yield the disinfected particulate matter,
wherein the photocatalyst is disposed on a substrate to yield a photocatalytic substrate, the substrate comprises a polymer, a metal, or a metal oxide, and a weight ratio of the photocatalyst to the photocatalytic substrate is in a range of 1:1 to 1:100.

2. The method of claim 1 , wherein the particulate mixture comprises a particulate food product or pharmaceutical product.

3. The method of claim 2 , wherein the particulate mixture comprises grains, dried dairy products, flour, seasonings, seeds, or any combination thereof.

4. The method of claim 1 , wherein the microorganisms comprise bacteria, fungi, viruses, protozoa, algae, spores associated therewith, or any combination thereof.

5. The method of claim 1 , wherein the substrate is selected from the group consisting of polyethylene, quartz, silica, stainless steel, polystyrene, silicon carbide, aluminum oxide, and zirconium oxide.

6. The method of claim 1 , wherein irradiating the mixture for a length of time comprises conveying the mixture under the pulsed ultraviolet radiation.

7. The method of claim 6 , wherein the length of time is in a range of about 1 second to about 60 seconds.

8. The method of claim 1 , wherein a frequency of the pulses is in a range of about 0.1 Hz to about 20 Hz.

9. The method of claim 1 , wherein a duration of pulses is in a range of about 50 μs to about 70,000 μs.

10. The method of claim 1 , wherein a voltage of the pulses is in a range of about 1000 V to about 3000 V.

11. The method of claim 1 , wherein an energy of the pulses is up to about 2500 J/pulse.

12. The method of claim 1 , wherein the photocatalyst comprises titanium dioxide.

13. A system for disinfecting particulate material, the system comprising:
a pulsed light source having a broadband emission spectrum in a range between about 190 nm and about 1100 nm;
a chamber defining a cavity optically coupled to the pulsed light source, wherein the chamber comprises a conveyor configured to accept the particulate material and arranged such that the pulses emitted by the pulsed light source irradiate the particulate material on the conveyor;
a vibratory feeder configured to deliver the particulate material to the chamber;
a volumetric feeder configured to adjust a feed rate of the particulate material to the conveyor;
a humidifier;
a fan; and
one or more sensors.

14. The system of claim 13 , further comprising a controller operatively coupled to the pulsed light source, the conveyor, the humidifier, the fan, and the one or more sensors.

15. The system of claim 13 , wherein the one or more sensors comprises at least one of a temperature sensor, a humidity sensor, and an anemometer.

16. The system of claim 13 , wherein a frequency of the pulses emitted by the pulsed light source is in a range of about 0.1 Hz to about 20 Hz.

17. The system of claim 13 , wherein a duration of the pulses emitted by the pulsed light source is in a range of about 50 μs to about 70,000 μs.

18. The system of claim 13 , wherein a voltage of the pulses emitted by the pulsed light source is in a range of about 1000 V to about 3000 V.

19. The system of claim 13 , wherein an energy of the pulses emitted by the pulsed light source is up to about 2500 J/pulse.

20. The system of claim 13 , wherein the conveyor comprises a photocatalyst and is configured to be irradiated with pulses emitted by the pulsed light source.

21. The system of claim 13 , further comprising a surface coated with, including, or formed of a photocatalyst, wherein the surface is configured to reflect or concentrate pulses emitted by the pulsed light source to enhance disinfection of the particulate material on the conveyor.

22. The method of claim 1 , wherein the substrate comprises magnetic particles.

23. The method of claim 22 , wherein separating the photocatalyst from the disinfected mixture comprises application of a magnetic field to facilitate removal of the photocatalytic substrate from the disinfected particulate matter.

24. The method of claim 1 , wherein the photocatalyst comprises TiO 2 and the substrate comprises Al 2 O 3 .

Assignees

• Univ Minnesota

Inventors

• Ruan Rongsheng
• Cheng Yanling
• Zhou Nan
• Chen Dongjie
• Peng Peng
• Wang Yunpu
• Zhang Renchuan
• Schiappacasse Charles
• Chen Ling

Classifications

• A61L2/088 Primary

  using photocatalysts or photosensitisers · CPC title

• A61L2/10 Primary

  Ultraviolet [UV] radiation · CPC title

• A23B2/05

  by heating using irradiation or electric treatment (drying or kilning A23B2/90) · CPC title

• A23B11/162

  by sonic or ultrasonic waves · CPC title

• A23B2/08

  using microwaves or dielectric heating · CPC title