Electrolysis or co-electrolysis reactor (SOEC) or fuel cell (SOFC) with electrochemical cell stacking by preassembled modules, and associated production process

Patent metadata

Field	Value
Publication number	US-11888183-B2
Application number	US-202117399782-A
Country	US
Kind code	B2
Filing date	Aug 11, 2021
Priority date	Aug 11, 2020
Publication date	Jan 30, 2024
Grant date	Jan 30, 2024

Abstract

An electrochemical device may be formed by assembly by stacking preassembled modules, each of these modules being produced as a usual stack of electrochemical cells. The manufacture of preassembled modules can make it possible to produce electrochemical devices with a large number of electrochemical cells, without the bracing problems present and excessive crushing courses that are encountered in the cell stacks according to the prior art, i.e., in a single block.

First claim

The invention claimed is:

1. An electrochemical device configured to function at high temperature, the device comprising:
a stack comprising a first and a second preassembled module, in which each preassembled module is obtained by tightening applied by a bolt system and comprises:
a stack of electrochemical cells comprising SOEC/SOFC solid oxides;
a plurality of electrical and fluidic interconnectors, each interconnector comprising a component comprising gastight electrically conductive material to convey or collect the electrical current to the stack of electrochemical cells and to convey, collect, and circulate gases on each electrode of each electrochemical cell, the interconnectors being individually arranged on either side of each of the electrochemical cells;
a first and a second stiffening plate between which the stack is arranged,
wherein the first and second stiffening plates, arranged in the stack of modules, form electrical and fluidic interconnectors between modules, the first and second stiffening plate, arranged at the ends of the stack of modules, forming electrical and fluidic connectors to convey or collect the electrical current between the electrochemical device and the exterior and to convey, collect, and circulate the gases between the electrochemical device and the exterior, wherein at least one electrical contact member is arranged between two adjacent modules with contact between their stiffening plates, and
wherein at least one seal is arranged between two adjacent modules to ensure the leaktightness around each gas inlet/outlet from one module to another.

2. The device of claim 1 , wherein the at least one electrical contact member is arranged between two adjacent modules with contact between their stiffening plates comprising a layer of a conductive ceramic material.

3. The device of claim 2 , wherein the conductive ceramic material is selected from the group consisting of:
La 0.6 Sr 0.4 Co 0.8 Fe 0.2 O 3 (LSCF);
La 0.8 Sr 0.2 Cu 0.9 Fe 0.1 O 2.5 (LSCuF);
La 0.7 Sr 0.3 CoO 3 (LSC);
Sm 0.5 Sr 0.5 CoO 3 (SSC);
SmBa 0.5 Sr 0.5 Co 2 O 5 (SBSC);
GdSrCo 2 O 5 (GSC);
La 0.65 Sr 0.3 MnO 3 (LSM);
LaBaCo 2 O 5 (LBC);
YBaCo 2 O 5 (YBC);
Nd 1.8 Ce 0.2 CuO 4 (NCC);
La 0.8 Sr 0.2 Co 0.3 Mn 0.1 Fe 0.6 O 3 (LSCMF);
La 0.98 Ni 0.6 Fe 0.4 O 3 (LNF);
La 1.2 Sr 0.8 NiO 4 (LSN);
La 0.7 Sr 0.3 FeO 3 (LSF); and
La 2 Ni 0.6 Cu 0.4 O 4 (LNC).

4. The device of claim 3 , wherein the conductive ceramic material is selected from the group consisting of LSM, LSC, LNF, and LSCF.

5. The device of claim 2 , wherein the layer of conductive ceramic material is hollowed on at least a part of its thickness.

6. The device of claim 1 , wherein the at least one electrical contact member is arranged between two adjacent modules with contact between their stiffening plates comprising a gold grid or gold bead obtained by deposition of a paste.

7. The device of claim 1 , wherein the at least one seal arranged between two adjacent modules consists of a pierced mica sheet facing each gas inlet/outlet from one module to another, optionally coated with a glass or vitroceramic bead around each gas inlet/outlet.

8. The device of claim 1 , wherein the at least one seal arranged between two adjacent modules consists of a glass or vitroceramic bead around each gas inlet/outlet.

9. The device of claim 1 , wherein a thickness of each of the stiffening plates is in a range of from 1 to 10 mm.

10. The device of claim 1 , comprising a first and a second additional end plate, known as terminal plates, which differ from the stiffening plates between which the stack of modules is arranged.

11. The device of claim 10 , wherein a thickness of each of the terminal plates is greater than 5 mm.

12. The device of claim 1 , comprising an electrical connection rod attached to each of the two stiffening plates or to each of a first and second terminal plate, arranged at the ends of the stack of modules.

13. The device of claim 12 , wherein each of the electrical connection rods is screwed into a tapping on the edge of one of the two stiffening plates or of one of two terminal plates.

14. The device of claim 12 , comprising a first, second, third, and fourth connecting rod individually attached to corners of each of the two stiffening plates or to each of a first and second terminal plate, arranged at ends of the stack of modules.

15. The device of claim 1 , wherein the at least one seal arranged between two adjacent modules comprises a pierced mica sheet facing each gas inlet/outlet from one module to another, optionally coated with a glass or vitroceramic bead around each gas inlet/outlet.

Assignees

• Commissariat Energie Atomique

Inventors

• Di Iorio Stéphane
• Monnet Thibault
• Oresic Bruno
• Szynal Philippe

Classifications

• H01M8/0217 Primary

  Complex oxides, optionally doped, of the type AMO3, A being an alkaline earth metal or rare earth metal and M being a metal, e.g. perovskites · CPC title

• C25B1/042

  by electrolysis of steam · CPC title

• C25B9/19

  with diaphragms · CPC title

• C25B9/65

  Means for supplying current; Electrode connections; Electric inter-cell connections · CPC title

• C25B9/77

  having diaphragms · CPC title