Process and system for conversion of crude oil to petrochemicals and fuel products integrating vacuum gas oil hydrotreating and steam cracking
US-10619112-B2 · Apr 14, 2020 · US
US11884608B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-11884608-B2 |
| Application number | US-202217729968-A |
| Country | US |
| Kind code | B2 |
| Filing date | Apr 26, 2022 |
| Priority date | Apr 27, 2021 |
| Publication date | Jan 30, 2024 |
| Grant date | Jan 30, 2024 |
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A system and a process for dimerizing cyclopentadiene (CPD) including producing a C 6 +C 7 rich bottoms stream and a C 5 rich side draw from a debutanizer, where the C 5 rich side draw and at least a portion of the C 6 +C 7 rich bottoms stream are directed to a dimerizer where the CPD is thermally dimerized to dicyclopentadiene (DCPD). DCPD is more stable than CPD and thus safer to handle.
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What is claimed is: 1. A system for dimerizing cyclopentadiene (CPD), the system comprising: a debutanizer comprising: a feed of C 4 -C 7 hydrocarbons; a C 4 hydrocarbons overhead stream; a C 6 +C 7 hydrocarbons rich bottoms stream; and a C 5 hydrocarbons rich side draw comprising cyclopentadiene; and a dimerizer comprising: a feed from the C 5 hydrocarbons rich side draw comprising cyclopentadiene; a feed from at least a portion of the C 6 +C 7 hydrocarbons rich bottoms stream; and a pyrolysis gasoline bottoms product stream. 2. The system of claim 1 , wherein the dimerizer is a thermal dimerizer. 3. The system of claim 1 , wherein a C 6 -C 7 hydrocarbons rich tar solvent makeup stream is drawn from the C 6 +C 7 hydrocarbons rich bottoms stream and a balance of the C 6 +C 7 hydrocarbons rich bottoms stream is directed to the dimerizer. 4. An ethylene plant comprising: A system for dimerizing cyclopentadiene (CPD), the system comprising: a debutanizer comprising: a feed of C 4 -C 7 hydrocarbons; a C 4 hydrocarbons overhead stream; a C 6 +C 7 hydrocarbons rich bottoms stream; and a C 5 hydrocarbons rich side draw comprising cyclopentadiene; and a dimerizer comprising: a feed from the C 5 hydrocarbons rich side draw comprising cyclopentadiene; a feed from at least a portion of the C 6 +C 7 hydrocarbons rich bottoms stream; and a pyrolysis gasoline bottoms product stream. 5. The ethylene plant of claim 4 , wherein the dimerizer is a thermal dimerizer. 6. The ethylene plant of claim 4 , wherein a C 6 -C 7 hydrocarbons rich tar solvent makeup stream is drawn from the C 6 +C 7 hydrocarbons rich bottoms stream and a balance of the C 6 +C 7 hydrocarbons rich bottoms stream is directed to the dimerizer.
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