Porous ceramic supports for resistively heated hybrid gas sorbents

Patent metadata

Field	Value
Publication number	US-11883793-B2
Application number	US-202117349574-A
Country	US
Kind code	B2
Filing date	Jun 16, 2021
Priority date	Jun 16, 2021
Publication date	Jan 30, 2024
Grant date	Jan 30, 2024

Abstract

A porous sorbent ceramic product includes a three-dimensional structure having an electrically conductive ceramic material, wherein the conductive ceramic material has an open cell structure with a plurality of intra-material pores, a sorbent additive primarily present in the intra-material pores of the conductive ceramic material for adsorption of a gas, and at least two electrodes in electrical communication with the conductive ceramic material.

First claim

What is claimed is:

1. A porous sorbent ceramic product comprising:
a three-dimensional structure comprising an electrically conductive ceramic material, wherein the conductive ceramic material has an open cell structure with a plurality of intra-material pores;
a sorbent additive present in the intra-material pores of the conductive ceramic material for adsorption of a gas; and
at least two electrodes in electrical communication with the conductive ceramic material.

2. The product as recited in claim 1 , wherein the three-dimensional structure is characterized as exhibiting sufficient joule heating upon application of an electrical current thereto to drive adsorbed gas from the sorbent additive.

3. The product as recited in claim 1 , comprising a plurality of inter-material pores, wherein an average diameter of the inter-material pores is in a range of about 100 microns to about 1 millimeter.

4. The product as recited in claim 1 , wherein an average diameter of the intra-material pores is in a range of greater than 0 nanometers to less than 10 microns.

5. The product as recited in claim 1 , wherein the conductive ceramic material has at least one physical property selected from the group of physical properties consisting of: a thermal conductivity of the ceramic material is in a range of greater than 1 to about 100 W/mK, an electrical conductivity of the ceramic material is in a range of greater than 1 to about 1000 reciprocal ohm per centimeter, and a surface area of the three-dimensional structure is in a range of greater than 1 to about 500 m 2 /g.

6. The product as recited in claim 1 , wherein the sorbent additive is present in a range of greater than 20 weight percent to less than 70 weight percent of a combined weight of the sorbent additive and ceramic material.

7. The product as recited in claim 1 , the sorbent additive is selected from the group consisting of: an organic molecule, an oligomer, a polymer, an aromatic polymer, a non-aromatic polymer, and a co-polymer.

8. The product as recited in claim 1 , wherein the sorbent additive is selected from the group consisting of: an amine-containing sorbent additive, a hydroxyl-containing sorbent additive, a carbonate-containing sorbent additive, a phosphate containing sorbent additive, and a combination thereof.

9. The product as recited in claim 8 , the sorbent additive being the amine-containing sorbent additive comprising: a structure selected from the group consisting of:
a branched structure, a linear structure, and a dendritic structure; and
a molecular weight in a range of 10 2 to 10 5 daltons.

10. The product as recited in claim 9 , wherein the amine-containing sorbent additive is selected from the group consisting of: poly(alkylamine), poly(ethylenimine), poly(propylenimine), poly(vinylamine), poly(allylamine), and a combination thereof.

11. The product as recited in claim 1 , wherein the conductive ceramic material includes at least one material selected from the group consisting of: a metal carbide, a metalloid carbide, a metal boride, a metalloid boride, a metal oxide, a metalloid oxide, a metal nitride, a metalloid nitride, a metal silicide, and a combination thereof.

12. A porous sorbent ceramic product comprising:
a three-dimensional structure comprising an electrically conductive ceramic material, wherein the conductive ceramic material has an open cell structure with a plurality of intra-material pores;
a sorbent additive present in the intra-material pores of the conductive ceramic material for adsorption of a gas; and
at least two electrodes in electrical communication with the conductive ceramic material, wherein the three-dimensional structure has a pre-defined geometric arrangement of features comprising:
a plurality of filaments comprising the conductive ceramic material having the intra-material pores, and,
a plurality of inter-material pores defined between adjacent filaments, wherein the inter-material pores form continuous channels from one side of the structure to the other side of the structure.

13. The product as recited in claim 1 , wherein the at least two electrodes are positioned for application of an electrical current to the ceramic material to cause joule heating of the conductive ceramic material thereto to drive adsorbed gas from the sorbent additive.

14. The product as recited in claim 1 , wherein the electrodes comprise a material that is different than the electrically conductive ceramic material.

15. The product as recited in claim 12 , wherein the three-dimensional structure is characterized as exhibiting sufficient joule heating upon application of an electrical current thereto to drive adsorbed gas from the sorbent additive.

16. The product as recited in claim 12 , wherein an average diameter of the inter-material pores is in a range of about 100 microns to about 1 millimeter.

17. The product as recited in claim 12 , wherein an average diameter of the intra-material pores is in a range of greater than 0 nanometers to less than 10 microns.

18. A method of forming the product as recited in claim 1 , the method comprising:
forming a three-dimensional ceramic support, wherein the three-dimensional ceramic support comprises an electrically conductive ceramic material configured for joule heating,
heating the three-dimensional ceramic support at a temperature for an effective duration of time to result in the conductive ceramic material having a plurality of intra-material pores; and
incorporating a sorbent additive into the intra-material pores of the conductive ceramic material.

19. The method as recited in claim 18 , wherein the electrically conductive ceramic material has a porosity in a range of 25% to 70%.

20. The method as recited in claim 18 , wherein incorporating the sorbent additive includes:
immersing the ceramic support in a mixture of the sorbent additive suspended in a solvent; and
drying the ceramic support to remove the solvent by evaporation.

Assignees

• L Livermore Nat Security Llc

Inventors

• Ellebracht Nathan C
• Baker Sarah E
• Duoss Eric B
• Pang Simon Hoching
• Stolaroff Joshuah K

Classifications

• B01J20/262 Primary

  obtained otherwise than by reactions only involving carbon to carbon unsaturated bonds, e.g. obtained by polycondensation (macromolecular compounds obtained otherwise than by reactions only involving unsaturated carbon-to-carbon bonds per se C08G) · CPC title

• B01D53/62

  Carbon oxides · CPC title

• B01D53/82

  with stationary reactants · CPC title

• B01D53/96

  Regeneration, reactivation or recycling of reactants · CPC title

• B01J20/0251

  Compounds of Si, Ge, Sn, Pb (B01J20/10 takes precedence) · CPC title