Method for manufacturing silicon timepiece components

Patent metadata

Field	Value
Publication number	US-11880165-B2
Application number	US-201916980126-A
Country	US
Kind code	B2
Filing date	Mar 19, 2019
Priority date	Mar 20, 2018
Publication date	Jan 23, 2024
Grant date	Jan 23, 2024

Abstract

Disclosed is a method including the following steps: a) providing a substrate including a first silicon layer, a second silicon layer and an intermediate silicon oxide layer therebetween; b) etching the first silicon layer in order to form the timepiece components therein; c) releasing from the substrate a wafer formed by at least all or part of the etched, first silicon layer and including the timepiece components; d) thermally oxidizing and then deoxidizing the timepiece components; e) forming by thermal oxidation or deposition a silicon oxide layer on the timepiece components; f) detaching the timepiece components from the wafer.

First claim

The invention claimed is:

1. A method of manufacturing timepiece components comprising the following steps:
a) providing a substrate comprising a first silicon layer, a second silicon layer and, in between, an intermediate silicon oxide layer,
b) etching the first silicon layer to form therein the timepiece components,
c) releasing from the substrate a wafer formed by at least all or part of the etched, first silicon layer and comprising the timepiece components,
d) thermally oxidizing and then deoxidizing the timepiece components,
e) forming by thermal oxidation or deposition a silicon oxide layer on the timepiece components, and
f) detaching the timepiece components from the wafer.

2. The method according to claim 1 , wherein the etching in step b) comprises a deep reactive ion etching.

3. The method according to claim 1 , comprising between steps d) and e) an additional step consisting of thermally oxidizing and then deoxidizing the timepiece components.

4. The method according to claim 3 , wherein step d) serves to improve the surface finish of the timepiece components and said additional step serves to adjust the stiffness of hairsprings constituting the timepiece components.

5. The method according to claim 3 , wherein during the thermal oxidation operation of said additional step the wafer is in an inverted position with respect to the thermal oxidation operation of step d).

6. The method according to claim 3 , wherein during step e) the wafer is in an inverted position with respect to the thermal oxidation operation of said additional step.

7. The method according to claim 1 , wherein during the thermal oxidation operation the wafer is supported by a support member comprising a support plate and spacers and retaining elements carried by the support plate, the spacers maintaining a gap between the wafer and the support plate, the retaining elements preventing the wafer from moving horizontally.

8. The method according to claim 7 , wherein the spacers support the wafer in areas of the wafer not comprising any timepiece component.

9. The method according to claim 7 , wherein the support plate is made of silicon, quartz or silicon carbide.

10. The method according to claim 7 , wherein the spacers and the retaining elements are made of quartz or silicon carbide.

11. The method according to claim 7 , wherein the spacers and the retaining elements are fixed to the support plate by bayonet-type connections.

12. The method according to claim 1 , wherein step c) comprises an operation of vapor-phase etching the intermediate silicon oxide layer.

13. The method according to claim 1 , wherein the wafer released in step c) is formed by a part of the etched, first silicon layer.

14. The method according to claim 1 , wherein in step b) a groove is etched in the first silicon layer in order to define the peripheral edge of the wafer to be released in step c).

15. The method according to claim 1 , wherein in step b) openings are etched in the first silicon layer around a central area where the timepiece components are etched, these openings allowing the passage of an etching agent for etching the intermediate silicon oxide layer during step c).

16. The method according to claim 1 , wherein the timepiece components comprise at least one of the following types of components: hairsprings, anchors, wheels, hands, rockers, levers, springs, balances, or parts of such components.

17. A method of manufacturing timepiece components comprising the following steps:
a) providing a substrate comprising silicon layers interleaved with silicon oxide layers,
b) etching a group of layers of the substrate to form therein the timepiece components,
c) releasing from the substrate a wafer formed by at least all or part of the group of layers and comprising the timepiece components,
d) thermally oxidizing and then deoxidizing the timepiece components,
e) forming by thermal oxidation or deposition a silicon oxide layer on the timepiece components, and
f) detaching the timepiece components from the wafer.

Assignees

• Patek Philippe Sa Geneve

Inventors

• Jeanneret Sylvain

Classifications

• G04B17/066 Primary

  Manufacture of the spiral spring (locking of the spiral spring by the regulating lever G04B18/026; spiral spring with temperature compensation G04B17/227; fixation of the spiral spring on the collet G04B17/32; mainspring G04B1/14) · CPC title

• C23C14/08

  Oxides (C23C14/10 takes precedence) · CPC title

• C23C16/401

  containing silicon · CPC title

• G04B17/22

  for the effect of variations of temperature {(alloys with small expansion coefficient C21C, C22C; adjustment of the regulator dependant on adjustment of the hands G04B18/028; depending on the difference in time with a comparison clockwork G04C11/007)} · CPC title

• G04B17/227 Primary

  composition and manufacture of the material used (composition and manufacture of hairsprings G04B17/066; of springs G04B1/145; anti-magnetic alloys G04B43/007; ferrous alloys C22C; non-ferrous alloys C22C, B22F) · CPC title