High-purity oxygen production system

Patent metadata

Field	Value
Publication number	US-11879685-B2
Application number	US-202017023290-A
Country	US
Kind code	B2
Filing date	Sep 16, 2020
Priority date	Sep 18, 2019
Publication date	Jan 23, 2024
Grant date	Jan 23, 2024

Abstract

Certain embodiments of the present invention lies in providing a high-purity oxygen production system which is capable of supplying liquid nitrogen in order to supply the cold required by a high-purity oxygen production apparatus, without the use of a costly conventional liquefaction apparatus.
A high-purity oxygen production system in accordance with an embodiment can include: an air separation apparatus including a main heat exchanger, a medium-pressure column and a low-pressure column; and a high-purity oxygen production apparatus including a nitrogen compressor, a nitrogen heat exchanger and at least one (high-purity) oxygen rectification column, an oxygen-containing stream serving as a starting material for high-purity oxygen is supplied from the low-pressure column to the high-purity oxygen production apparatus, and liquid nitrogen obtained from the medium-pressure column is supplied to the high-purity oxygen production apparatus in order to replenish cold heat required for operation of the high-purity oxygen production apparatus.

First claim

We claim:

1. A high-purity oxygen production system comprising:
an air separation apparatus including a main heat exchanger, a medium-pressure column and a low-pressure column; and
a high-purity oxygen production apparatus including a nitrogen compressor, a nitrogen heat exchanger and at least one high-purity oxygen rectification column,
wherein the low-pressure column is in fluid communication with the high-purity oxygen production apparatus such that the system is configured to supply an oxygen-containing stream serving as a starting material for high-purity oxygen from the low-pressure column to the high-purity oxygen production apparatus, and
wherein the medium-pressure column is in fluid communication with the high-purity oxygen production apparatus such that the system is configured to supply liquid nitrogen obtained from the medium-pressure column to the high-purity oxygen production apparatus in order to replenish refrigeration required for operation of the high-purity oxygen production apparatus,
wherein the high-purity oxygen production system further comprises a nitrogen expansion line and a nitrogen expander, wherein the nitrogen expansion line is in fluid communication with an intermediate section of the nitrogen heat exchanger and is configured to receive nitrogen after being compressed in the nitrogen compressor by sending a partially cooled and pressurized nitrogen steam to the nitrogen expander to form an expanded nitrogen steam, wherein the nitrogen expansion line is further configured to send the expanded nitrogen steam to a cold end of the nitrogen heat exchanger and then recycled back to the nitrogen compressor.

2. The high-purity oxygen production system according to claim 1 ,
wherein the main heat exchanger is configured to cool an air feed;
wherein the medium-pressure column is in fluid communication with a cold end of the main heat exchanger and is configured to receive the starting material air from the main heat exchanger, the medium-pressure column having a medium-pressure column bottom in which a first rectification liquid is collected, a medium-pressure column rectification portion for rectifying the starting material air, and a medium-pressure column top arranged above the medium-pressure column rectification portion,
wherein the low-pressure column is arranged above the medium-pressure column, the low-pressure column having a low-pressure column bottom inside or below which is arranged a nitrogen condenser that is configured to condense a gas drawn from the medium-pressure column top and conducted by a circulation line and in which a second rectification liquid is collected, a low-pressure column rectification portion that is configured to rectify the first rectification liquid drawn from the medium-pressure column bottom, and a low-pressure column top to which is introduced at least a portion of a condensed stream condensed in the nitrogen condenser.

3. The high-purity oxygen production system according to claim 1 , wherein the at least one high-purity oxygen rectification column further comprises:
a first oxygen rectification column having: a first oxygen rectification column rectification portion to which the second rectification liquid drawn from the low-pressure column bottom is introduced at an intermediate portion thereof or therebelow, a first oxygen rectification column bottom arranged below the first oxygen rectification column rectification portion, and a first oxygen rectification column top arranged above the first rectification column rectification portion;
a first oxygen evaporator arranged inside or below the first oxygen rectification column bottom, the first oxygen evaporator causing evaporation of a rectification liquid falling from the first oxygen rectification column rectification portion and the second rectification liquid which has been introduced;
a first oxygen condenser arranged inside or above the first oxygen rectification column top, wherein a first oxygen rectification gas drawn from an upper portion of the first oxygen rectification column rectification portion is cooled and liquefied by first liquid nitrogen condensed in the first oxygen evaporator, and is returned to the first oxygen rectification column rectification portion;
a second oxygen rectification column having a second oxygen rectification column bottom, a second oxygen rectification column rectification portion arranged above the second oxygen rectification column bottom, and a second oxygen rectification column top arranged above the second oxygen rectification column rectification portion;
a second oxygen evaporator arranged inside or below the second oxygen rectification column bottom, the second oxygen evaporator causing evaporation of a rectification liquid falling from the second oxygen rectification column rectification portion; and
a second oxygen condenser arranged inside or above the second oxygen rectification column top, wherein the second oxygen condenser is configured to cool and liquefy a second oxygen rectification gas drawn from an upper portion of the second oxygen rectification column rectification portion by means of second liquid nitrogen sent to the second oxygen condenser, and returns the cooled and liquefied gas to the second oxygen rectification column rectification portion;
wherein the nitrogen heat exchanger is configured to receive a nitrogen-rich gas drawn from a space above the second oxygen condenser in the second oxygen rectification column top;
wherein the nitrogen compressor is configured to compress the nitrogen-rich gas drawn from the space above the second oxygen condenser in the second oxygen rectification column top;
wherein the high-purity oxygen production apparatus further comprises:
a line configured to recirculate a compressed nitrogen-rich gas compressed in the nitrogen compressor to the nitrogen heat exchanger, and introducing the nitrogen-rich gas to a space below the first oxygen evaporator in the first oxygen rectification column bottom; and
a branch line which branches from the line and is configured to introduce the nitrogen-rich gas to a space below the second oxygen evaporator in the second oxygen rectification column bottom.

4. The high-purity oxygen production system according to claim 1 , wherein the high-purity oxygen production apparatus comprises:
a high-purity oxygen tank for storing high-purity oxygen extracted in a liquid;
a pressurizer for evaporating a portion of high-purity liquid oxygen and pressurizing the high-purity liquid oxygen; and
a liquid nitrogen buffer for storing liquid nitrogen.

5. The high-purity oxygen production system according to claim 1 , wherein the high-purity oxygen production apparatus comprises:
a line for supplying liquid nitrogen from the medium-pressure column of the air separation apparatus to a liquid nitrogen buffer;
a liquid nitrogen flowmeter which is provided on the line and measures a flow rate of liquid nitrogen; and
a control valve for controlling an amount measured by the liquid nitrogen flowmeter to a predetermined amount or a predetermined range.

6. The high-purity oxygen production system according to claim 1 , wherein a high-purity oxygen liquid pressurized in a high-purity oxygen tank is introduced to the main heat exchanger in the air separation apparatus and evaporated, and extracted as high-purity oxygen gas.

7. A method for producing high-purity oxygen, the method comprising the steps of:
providing an air separation apparatus including a main heat exchanger, a medium-pressure column and a low-pressure column;
providing a high-purity oxygen production apparatus including a nitrogen compressor, a nitrogen heat exchanger and at least one high-purity oxygen rectification column;
supplying an oxygen-containing stream servi

Assignees

• Air Liquide

Inventors

• Hirose Kenji

Classifications

• F25J3/04745

  Krypton and/or Xenon · CPC title

• F25J1/0017 Primary

  Oxygen · CPC title

• F25J1/0012

  Primary atmospheric gases, e.g. air · CPC title

• F25J1/0015

  Nitrogen · CPC title

• F25J3/04024

  of purified feed air, so-called boosted air · CPC title