Middle-pressure polymerization process for liquid ethylene copolymers

Patent metadata

Field	Value
Publication number	US-11879108-B2
Application number	US-202017600797-A
Country	US
Kind code	B2
Filing date	Mar 23, 2020
Priority date	Apr 4, 2019
Publication date	Jan 23, 2024
Grant date	Jan 23, 2024

Abstract

The present invention relates to a middle-pressure polymerization process for the preparation of a liquid ethylene copolymer which comprises in polymerized form 20 to 60 wt % of ethylene; and at least 20 wt % of an acrylate, which is selected from C1-C22 alkyl (meth)acrylate, where a monomer mix comprising the ethylene and the acrylate is polymerized at a pressure of 50 to 400 bar and in the presence of at least 2 wt % of a chain transfer agent. The invention further relates to a liquid ethylene copolymer obtainable by the polymerization process; and to a lubricant comprising the liquid ethylene copolymer obtainable by the polymerization process; and to a method for reducing friction between moving surfaces comprising the step of contacting the surfaces with the lubricant or with the ethylene copolymer.

First claim

The invention claimed is:

1. A middle-pressure polymerization process for the preparation of an ethylene copolymer which is liquid at room temperature which comprises in polymerized form
20 to 60 wt % of ethylene; and
at least 20 wt % of an acrylate, which comprises
a polar acrylate selected from C 1 -C 5 alkyl (meth)acrylate, and
an unpolar acrylate selected from C 6 -C 22 alkyl (meth)acrylate,

where a monomer mix comprising the ethylene and the acrylate is polymerized at a pressure of 50 to 400 bar and in the presence of at least 2 wt % of a chain transfer agent, where the percentage of the chain transfer agent is based on the sum of the amounts of monomers and the chain transfer agent.

2. The polymerization process according to claim 1 , where the chain transfer agents are saturated or unsaturated hydrocarbons, aliphatic ketones, aliphatic aldehydes, or hydrogen, or mixtures thereof.

3. The polymerization process according to claim 1 , where the monomer feed is polymerized in the presence of 4 to 18 wt % of the chain transfer agent.

4. The polymerization process according to claim 1 , where the polymerization process is a fed-batch process in which a reactor is partly filled with the ethylene and a solvent, followed by feeding of the acrylate, the chain transfer agent, and an initiator.

5. The polymerization process according to claim 1 , where the polymerization process is carried out at a pressure in the range from 70 to 300 bar.

6. The polymerization process according to claim 1 , where the monomer mix is polymerized in a polymerization solvent.

7. The polymerization process according to claim 1 , where the ethylene copolymer comprises in polymerized form at least 30 wt % of the acrylate.

8. The polymerization process according to claim 1 , where the polar acrylate is methyl (meth)acrylate, ethyl (meth)acrylate, n-propyl (meth)acrylate, or n-butyl (meth)acrylate.

9. The polymerization process according to claim 1 , where the unpolar acrylate is selected from C 8 -C 18 alkyl (meth)acrylate, in particular from C 8 -C 12 alkyl (meth)acrylate.

10. The polymerization process according to claim 1 , where the unpolar acrylate is selected from (meth)acrylates of n-octyl, isooctyl, 2-ethylhexyl, n-nonyl, 2-propylheptyl, n-decyl, un-decyl, dodecyl, tridecyl, tetradecyl, pentadecyl, hexadecyl, heptadecyl, octadecyl, 2-butyloctyl, 2-pentylnonyl, 2-hexyldecyl, isohexyl, isoheptyl, isooctyl, isononyl, isodecyl, isoundecyl, isododecyl, isotridecyl, isotetradecyl, isopentadecyl, isohexadecyl, isoheptadecyl, isooctadecyl and mixtures thereof.

11. The polymerization process according to claim 1 , where the ethylene copolymer comprises in polymerized form
25 to 55 wt % of ethylene,
at least 20 wt % of the polar acrylate which is selected from C 1 -C 4 alkyl (meth)acrylate, and
at least 15 wt % of the unpolar acrylate which is selected from C 6 -C 22 alkyl (meth)acrylate.

12. A liquid ethylene copolymer obtainable by the polymerization process as defined in claim 1 .

13. A lubricant comprising the liquid ethylene copolymer obtainable by the polymerization process as defined in claim 1 .

14. A method for reducing friction between moving surfaces comprising the step of contacting the surfaces with the lubricant as defined claim 13 .

15. The polymerization process according to claim 1 , where the ethylene copolymer comprises in polymerized form at least 50 wt % of the acrylate.

Assignees

• Basf Se

Inventors

• Garcia Castro Ivette
• Grabarse Wolfgang
• Strittmatter Jan
• Koschabek Rene
• Rupaner Robert

Classifications

• C10M107/28 Primary

  containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate · CPC title

• C08F210/02

  Ethene · CPC title

• C08F220/1808 Primary

  C8-(meth)acrylate, e.g. isooctyl (meth)acrylate or 2-ethylhexyl (meth)acrylate · CPC title

• C10M145/14

  Acrylate; Methacrylate · CPC title

• C08F2800/20

  as weight or mass percentages · CPC title