Integrated process for upgrading C6+ and C8+ non-aromatics in pygas to BTX

Patent metadata

Field	Value
Publication number	US-11879103-B2
Application number	US-202217567502-A
Country	US
Kind code	B2
Filing date	Jan 3, 2022
Priority date	Jan 3, 2022
Publication date	Jan 23, 2024
Grant date	Jan 23, 2024

Abstract

In accordance with one or more embodiments of the present disclosure, a method for producing aromatic compounds from pyrolysis gasoline includes splitting the pyrolysis gasoline into a stream comprising non-aromatic hydrocarbons and a stream comprising paraffinic hydrocarbons and aromatic hydrocarbons; aromatizing the stream comprising paraffinic hydrocarbons and aromatic hydrocarbons, thereby converting the stream comprising paraffinic hydrocarbons and aromatic hydrocarbons to a first stream comprising benzene-toluene-xylenes (BTX); hydrotreating the first stream comprising BTX in a selective hydrotreatment unit, thereby producing a de-olefinated stream comprising BTX; hydrodealkylating and transalkylating the de-olefinated stream comprising BTX in a hydrodealkylation-transalkylation unit, thereby producing a second stream comprising BTX, the second stream comprising BTX having a greater amount of benzene and xylenes than the first stream comprising BTX; and processing the second stream comprising BTX in an aromatics recovery complex, thereby producing the aromatic compounds comprising benzene, toluene, and xylenes.

First claim

What is claimed is:

1. A method for producing aromatic compounds from pyrolysis gasoline comprising olefinic hydrocarbons, paraffinic hydrocarbons, and aromatic hydrocarbons, the method comprising:
splitting the pyrolysis gasoline into a stream comprising the olefinic hydrocarbons and a stream comprising the paraffinic hydrocarbons and the aromatic hydrocarbons;
aromatizing the stream comprising the paraffinic hydrocarbons and the aromatic hydrocarbons in an aromatization unit, thereby converting the stream comprising the paraffinic hydrocarbons and the aromatic hydrocarbons to a first stream comprising benzene-toluene-xylenes (BTX);
hydrotreating the first stream comprising BTX in a selective hydrotreatment unit, thereby producing a de-olefinated stream comprising BTX;
hydrodealkylating and transalkylating the de-olefinated stream comprising BTX in a hydrodealkylation-transalkylation unit, thereby producing a second stream comprising BTX, the second stream comprising BTX having a greater amount of benzene and xylenes than the first stream comprising BTX; and
processing the second stream comprising BTX in an aromatics recovery complex, thereby producing the aromatic compounds from the pyrolysis gasoline, the aromatic compounds comprising benzene, toluene, and xylenes;
wherein the olefinic hydrocarbons comprise C 6 olefinic hydrocarbons, the paraffinic hydrocarbons comprise C 6 and C 6 + paraffinic hydrocarbons, and the aromatic hydrocarbons comprise C 6 and C 6 + aromatic hydrocarbons.

2. The method of claim 1 , wherein the olefinic hydrocarbons comprise C 8 olefinic hydrocarbons, the paraffinic hydrocarbons comprise C 8 and C 8 + paraffinic hydrocarbons, and the comprise C 8 and C 8 + aromatic hydrocarbons.

3. The method of claim 1 , wherein the processing further produces a raffinate stream.

4. The method of claim 3 , further comprising:
adding the stream comprising the olefinic hydrocarbons to the raffinate stream.

5. The method of claim 1 , further comprising:
recycling the toluene to the hydrodealkylation-transalkylation unit.

6. The method of claim 1 , wherein the processing produces a stream comprising C 9 -C 10 aromatic compounds, and the method further comprises:
recycling at least a portion of the C 9 -C 10 aromatic compounds to the hydrodealkylation-transalkylation unit.

7. The method of claim 1 , wherein the selective hydrotreatment unit comprises a reactor selected from the group consisting of a fixed-bed reactor, an ebullated-bed reactor, a moving bed reactor, a slurry bed reactor, and a combination of two or more thereof, and the reactor comprises a catalyst composition comprising an active-phase metal on a support.

8. The method of claim 7 , wherein:
the active-phase metal is selected from the group consisting of nickel, molybdenum, tungsten, platinum, palladium, rhodium, ruthenium, gold, and a combination of two or more of these; and
the support is selected from the group consisting of amorphous alumina, crystalline silica-alumina, alumina, silica, and a combination of two or more thereof.

9. A method for producing aromatic compounds from pyrolysis gasoline comprising olefinic hydrocarbons, paraffinic hydrocarbons, and aromatic hydrocarbons, the method comprising:
processing the pyrolysis gasoline in an aromatics recovery complex, thereby producing a stream comprising the paraffinic hydrocarbons, and one or more streams comprising benzene, toluene, and xylenes;
aromatizing the stream comprising the paraffinic hydrocarbons in an aromatization unit, thereby converting the stream comprising the paraffinic hydrocarbons to a first stream comprising benzene-toluene-xylenes (BTX);
hydrotreating the first stream comprising BTX in a selective hydrotreatment unit, thereby producing a de-olefinated stream comprising BTX;
hydrodealkylating and transalkylating the de-olefinated stream comprising BTX in a hydrodealkylation-transalkylation unit, thereby producing a second stream comprising BT:X, the second stream comprising B TX having a greater amount of benzene and xylenes than the first stream comprising B TX; and
processing the second stream comprising BTX in an aromatics recovery complex, thereby producing the aromatic compounds from the pyrolysis gasoline, the aromatic compounds comprising benzene, toluene, and xylenes.

10. The method of claim 9 , wherein the olefinic hydrocarbons comprise C 6 olefinic hydrocarbons and the paraffinic hydrocarbons and the comprise C 6 and C 6 + paraffinic and aromatic hydrocarbons.

11. The method of claim 9 , wherein the olefinic hydrocarbons comprise C 8 olefinic hydrocarbons and the paraffinic hydrocarbons and the comprise C 8 and C 8 + paraffinic and aromatic hydrocarbons.

12. The method of claim 9 , wherein the processing produces a stream comprising C 9 -C 10 aromatic compounds, and the method further comprises:
recycling at least a portion of the C 9 -C 10 aromatic compounds to the hydrodealkylation-transalkylation unit.

13. The method of claim 9 , wherein the selective hydrotreatment unit comprises a reactor selected from the group consisting of a fixed-bed reactor, an ebullated-bed reactor, a moving bed reactor, a slurry bed reactor, and a combination of two or more thereof, and the reactor comprises a catalyst composition comprising an active-phase metal on a support.

14. The method of claim 13 , wherein:
the active-phase metal is selected from the group consisting of nickel, molybdenum, tungsten, platinum, palladium, rhodium, ruthenium, gold, and a combination of two or more of these; and
the support is selected from the group consisting of amorphous alumina, crystalline silica-alumina, alumina, silica, and a combination of two or more thereof.

15. A method for producing aromatic compounds from pyrolysis gasoline comprising olefinic hydrocarbons, paraffinic hydrocarbons, and aromatic hydrocarbons, the method comprising:
processing the pyrolysis gasoline in an aromatics recovery complex, thereby producing a stream comprising the paraffinic hydrocarbons, and one or more streams comprising benzene, toluene, and xylenes;
aromatizing the stream comprising the paraffinic hydrocarbons in an aromatization unit, thereby converting the stream comprising the paraffinic hydrocarbons to a first stream comprising benzene-toluene-xylenes (BTX);
hydrotreating the first stream comprising BTX in a selective hydrotreatment unit, thereby producing a de-olefinated stream comprising BTX;
processing the de-olefinated stream comprising BTX in the aromatics recovery complex,
thereby producing the aromatic compounds from the pyrolysis gasoline, the aromatic compounds comprising benzene, toluene, xylenes, and C 9 -C 10 aromatic compounds;
sending the toluene and the C 9 -C 10 aromatic compounds to a hydrodealkylation-transalkylation unit, thereby producing a second stream comprising BTX, the second stream comprising BTX having a greater amount of benzene and xylenes than the first stream comprising BTX; and
processing the second stream comprising BTX in the aromatics recovery complex, thereby producing one or more product streams, each of the one or more product streams comprising one or more of benzene, toluene, xylenes, and C9-C10 aromatic compounds.

16. The method of claim 15 , wherein the olefinic hydrocarbons comprise C 6 olefinic hydrocarbons and the paraffinic hydrocarbons and the comprise C 6 and C 6 + paraffinic and aromatic hydrocarbons.

17. The method of claim 15 , wherein the olefinic hydrocarbons comprise C 8 olefinic hydrocarbons and the paraffinic hydrocarbons and the comprise C 8 and C 8

Assignees

• Saudi Arabian Oil Co

Inventors

• Al-Mana Noor Nasser
• Zhang Zhonglin
• Al-Ghamdi Sameer
• Koseoglu Omer Refa
• Shaikh Sohel

Classifications

• C10G69/12 Primary

  including at least one polymerisation or alkylation step · CPC title

• C10G2300/104

  Light gasoline having a boiling range of about 20 - 100 °C · CPC title

• C10G2400/30

  Aromatics · CPC title

• C10G29/205

  by reaction with hydrocarbons added to the hydrocarbon oil · CPC title

• C10G69/00

  Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process (C10G67/00 takes precedence) · CPC title