Applying silicon metal-containing bond layer to ceramic or ceramic matrix composite substrates

Patent metadata

Field	Value
Publication number	US-11878945-B2
Application number	US-202117166273-A
Country	US
Kind code	B2
Filing date	Feb 3, 2021
Priority date	Sep 10, 2015
Publication date	Jan 23, 2024
Grant date	Jan 23, 2024

Abstract

In some examples, a method may include depositing, from a slurry comprising particles including silicon metal, a bond coat precursor layer including the particles comprising silicon metal directly on a ceramic matrix composite substrate. The method also may include locally heating the bond coat precursor layer to form a bond coat comprising silicon metal. Additionally, the method may include forming a protective coating on the bond coat. In some examples, an article may include a ceramic matrix composite substrate, a bond coat directly on the substrate, and a protective coating on the bond coat. The bond coat may include silicon metal and a metal comprising at least one of Zr, Y, Yb, Hf, Ti, Al, Cr, Mo, Nb, Ta, or a rare earth metal.

First claim

The invention claimed is:

1. An article comprising:
a ceramic matrix composite substrate;
a bond coat directly on the substrate, wherein the bond coat comprises SiC particles and a silicon alloy, wherein the silicon alloy comprises silicon metal and more than 0 wt. % and less than about 30 wt. % of at least one of zirconium metal, yttrium metal, titanium metal, aluminum metal, chromium metal, niobium metal, tantalum metal, or a rare earth metal; and
a protective coating on the bond coat.

2. The article of claim 1 , wherein the bond coat comprises greater than 0 wt. % and less than about 10 wt. % of the at least one of zirconium metal, yttrium metal, titanium metal, aluminum metal, chromium metal, niobium metal, tantalum metal, or the rare earth metal.

3. The article of claim 1 , wherein the silicon alloy comprises the silicon metal and more than 0 wt. % and less than about 30 wt. % of each of at least two of zirconium metal, yttrium metal, titanium metal, aluminum metal, chromium metal, niobium metal, tantalum metal, or a rare earth metal.

4. The article of claim 1 , wherein the at least one of zirconium metal, yttrium metal, titanium metal, aluminum metal, chromium metal, niobium metal, tantalum metal, or the rare earth metal is configured to reduce a melting temperature of the bond coat.

5. The article of claim 1 , wherein the bond coat further comprises an oxidation enhancement additive, wherein the oxidation enhancement additive comprises at least one of molybdenum metal, hafnium metal, or ytterbium metal.

6. The article of claim 5 , wherein the bond coat comprises greater than 0 wt. % and less than about 10 wt. % of the oxidation enhancement additive.

7. The article of claim 5 , further comprising an oxide scale between the bond coat and the protective coating.

8. The article of claim 1 , wherein the ceramic matrix composite substrate is at least one of a blade track, an airfoil, a blade, vane, or a combustion chamber liner.

9. The article of claim 1 , wherein the bond coat comprises between about 1 vol. % and about 40 vol. % SiC particles.

10. The article of claim 9 , wherein the bond coat comprises between about 5 vol. % and about 20 vol. % SiC particles.

11. The article of claim 1 , wherein the protective coating comprises an environmental barrier coating.

12. The article of claim 11 , wherein the environmental barrier coating comprises:
a base material comprising at least one of a glass ceramic, a rare earth disilicate, a rare earth monosilicate, or a first rare earth oxide;
a first additive comprising silicon metal; and
a second additive comprising at least one of a pre-ceramic polymer, a second rare earth oxide, alumina, silica, titanium oxide, tantalum oxide, boron oxide, an alkali metal oxide, an alkali earth metal oxide, aluminum metal, or a rare earth metal.

13. The article of claim 12 , wherein the second additive is configured to react with another constituent of the environmental barrier coating to form at least one phase that has a lower melting point compared to a main phase of the environmental barrier coating.

14. The article of claim 1 , wherein the ceramic matrix composite substrate comprises a melt-infiltrated SiC—SiC ceramic matrix composite.

15. The article of claim 1 , wherein the protective coating comprises at least one of a thermal barrier coating, an abradable coating, or a calcia-magnesia-aluminosilicate-resistant layer.

16. The article of claim 1 , wherein the bond coat comprises a plurality of three-dimensional surface features defined in an outer surface of the bond coat.

17. The article of claim 1 , wherein the bond coat is deposited on the ceramic matrix composite substrate using a slurry.

Assignees

• Rolls Royce Corp
• Rolls Royce High Temperature Composites Inc

Inventors

• Shim Sungbo
• Lee Kang N
• Harris Stephen Isaiah
• Lazur Andrew Joseph

Classifications

• C04B37/006 Primary

  consisting of metals or metal salts · CPC title

• C04B41/009

  characterised by the material treated · CPC title

• C04B41/4539

  as a emulsion, dispersion or suspension · CPC title

• C04B41/4543

  by spraying, e.g. by atomising · CPC title

• C04B41/5027

  Oxide ceramics in general; Specific oxide ceramics not covered by C04B41/5029 - C04B41/5051 · CPC title