Method of producing boron trichloride

Patent metadata

Field	Value
Publication number	US-11878912-B2
Application number	US-201917052844-A
Country	US
Kind code	B2
Filing date	Jun 4, 2019
Priority date	Jun 26, 2018
Publication date	Jan 23, 2024
Grant date	Jan 23, 2024

Abstract

A method of producing boron trichloride, which includes: a metal chlorination step of bringing a gas containing chlorine gas into contact with raw boron carbide as boron carbide including, as an impurity, a metal other than boron, and allowing the metal to react with the chlorine gas in the gas containing the chlorine gas, to form a metal chloride and to obtain boron carbide containing the metal chloride; a removal step of removing the metal chloride from the boron carbide containing the metal chloride, obtained in the metal chlorination step; and a generation step of bringing a gas containing chlorine gas into contact with the boron carbide from which the metal chloride has been removed in the removal step, and allowing the boron carbide and the chlorine gas in the gas containing the chlorine gas to react with each other to generate boron trichloride.

First claim

The invention claimed is:

1. A method of producing boron trichloride, including:
a metal chlorination step of bringing a gas containing chlorine gas into contact with raw boron carbide as boron carbide comprising, as an impurity, a metal other than boron, at a temperature of 300° C. or more and 700° C. or less, and allowing the metal to react with the chlorine gas in the gas containing the chlorine gas, to form a metal chloride and to obtain boron carbide containing the metal chloride;
a removal step of removing the metal chloride from the boron carbide containing the metal chloride, obtained in the metal chlorination step; and
a generation step of bringing a gas containing chlorine gas into contact with the boron carbide from which the metal chloride has been removed in the removal step, and allowing the boron carbide and the chlorine gas in the gas containing the chlorine gas to react with each other to generate boron trichloride wherein the boron carbide and the gas containing the chlorine gas are brought into contact with each other at a temperature of 550° C. or more and 1100° C. or less in the generation step.

2. The method of producing boron trichloride according to claim 1 , wherein the metal is at least one of iron, aluminum, calcium, chromium, silicon, and titanium.

3. The method of producing boron trichloride according to claim 2 , wherein the metal comprises iron, and a content of iron contained in the boron carbide from which the metal chloride has been removed in the removal step is less than 0.30% by mass.

4. The method of producing boron trichloride according to claim 1 , wherein the raw boron carbide is a powder having a D95 of 500 μm or less, measured by a laser diffraction method, and the D95 is a particle diameter in which an integrated frequency based on a smaller particle diameter in an integrated particle size distribution based on a volume is 95%.

5. The method of producing boron trichloride according to claim 1 , wherein the gas containing the chlorine gas, used in the metal chlorination step, consists of 50% by volume or more and 100% by volume or less of the chlorine gas, and a remainder inert gas.

6. The method of producing boron trichloride according to claim 2 , wherein the raw boron carbide is a powder having a D95 of 500 μm or less, measured by a laser diffraction method, and the D95 is a particle diameter in which an integrated frequency based on a smaller particle diameter in an integrated particle size distribution based on a volume is 95%.

7. The method of producing boron trichloride according to claim 3 , wherein the raw boron carbide is a powder having a D95 of 500 μm or less, measured by a laser diffraction method, and the D95 is a particle diameter in which an integrated frequency based on a smaller particle diameter in an integrated particle size distribution based on a volume is 95%.

8. The method of producing boron trichloride according to claim 2 , wherein the gas containing the chlorine gas, used in the metal chlorination step, consists of 50% by volume or more and 100% by volume or less of the chlorine gas, and a remainder inert gas.

9. The method of producing boron trichloride according to claim 3 , wherein the gas containing the chlorine gas, used in the metal chlorination step, consists of 50% by volume or more and 100% by volume or less of the chlorine gas, and a remainder inert gas.

10. The method of producing boron trichloride according to claim 4 , wherein the gas containing the chlorine gas, used in the metal chlorination step, consists of 50% by volume or more and 100% by volume or less of the chlorine gas, and a remainder inert gas.

Assignees

• Showa Denko Kk
• Resonac Corp

Inventors

• MOURI Saki
• Kurihara Hideyuki

Classifications

• C01B35/061 Primary

  Halides · CPC title

• C01P2004/61

  Micrometer sized, i.e. from 1-100 micrometer · CPC title

• C01P2006/82

  water content · CPC title

• Y02P20/10

  Process efficiency · CPC title

• C01B32/991

  Boron carbide · CPC title