Prepreg, laminate, and molding

Patent metadata

Field	Value
Publication number	US-11878478-B2
Application number	US-202017611697-A
Country	US
Kind code	B2
Filing date	May 15, 2020
Priority date	May 23, 2019
Publication date	Jan 23, 2024
Grant date	Jan 23, 2024

Abstract

The present invention aims at providing a prepreg for producing a laminate suitable as a structural material, and a laminate, which have excellent tensile shear joining strength, fatigue joining strength, and interlaminar fractural toughness values, and can be firmly integrated with another structural member by welding. The present invention is a prepreg including the following structural components [A], [B], and [C], wherein [C] is present on a surface of the prepreg, [C] is a crystalline thermoplastic resin having a glass transition temperature of 100° C. or higher or an amorphous thermoplastic resin having a glass transition temperature of 180° C. or higher, and the reinforcing fibers [A] are present which are included in a resin area including [B] and a resin area including [C] across an interface between the two resin areas: [A] reinforcing fibers; [B] a thermosetting resin; and [C] a thermoplastic resin.

First claim

The invention claimed is:

1. A prepreg comprising the following structural components [A], [B], [C], and [E], wherein
[C] is present on a surface of the prepreg,
[C] is a crystalline thermoplastic resin having a glass transition temperature of 100° C. or higher or an amorphous thermoplastic resin having a glass transition temperature of 180° C. or higher,
the reinforcing fibers [A] are present which are included in a resin area including [B] and a resin area including [C] across an interface between the two resin areas,
[E] is included in the structural component [B], and
the structural component [E] is included in an amount of 3 parts by mass or more and 30 parts by mass or less based on 100 parts by mass of the structural component [B]:

[A] reinforcing fibers;
[B] a thermosetting resin; a-
[C] a thermoplastic resin; and
[E] a thermoplastic resin soluble in a thermosetting resin.

2. The prepreg according to claim 1 , wherein, in a planar view of the prepreg, when a cross-section perpendicular to a plane of the prepreg including the [A] is obtained from a direction of an angle different by 45 degrees to a direction of any fiber [A] included in the two resin areas, a cross-sectional curve, formed by the interface between the two resin areas closely adhering to each other, in the cross-section, has an average roughness length RSm, defined in accordance with JIS B0601 (2001), of 100 μm or less, and an average roughness height Rc of 3.5 μm or more.

3. The prepreg according to claim 2 , wherein the average roughness height Rc is 10 μm or more.

4. The prepreg according to claim 1 , wherein the resin area including the [B] and the resin area including the [C] are adjacent to each other in a layered state to form the interface.

5. The prepreg according to claim 1 , wherein the structural component [C] is selected from a polyarylene ether ketone and a polyetherimide.

6. The prepreg according to claim 5 , wherein the structural component [C] is a polyarylene ether ketone having a melting point of 200° C. to 340° C.

7. The prepreg according to claim 1 , wherein the structural component [E] is in a dissolved state.

8. The prepreg according to claim 1 , wherein the structural component [E] is a polyethersulfone or a polyetherimide.

9. The prepreg according to claim 1 , wherein the structural component [A] includes a carbon fiber having a strand tensile strength of 5.5 GPa or more.

10. A laminate wherein a prepreg according to claim 1 forms at least a part of layers in the state of a cured product.

11. The laminate according to claim 10 , wherein the structural component [C] is present on the surface.

12. The laminate according to claim 10 , wherein the structural component [C] is present between layers.

13. A molding comprising a laminate according to claim 11 , wherein the laminate is integrated with another member by joining the member to a surface of a structural component [C].

14. A laminate comprising a layer including the following structural components [A], [C], [D], and [E], wherein
[C] is a crystalline thermoplastic resin having a glass transition temperature of 100° C. or higher or an amorphous thermoplastic resin having a glass transition temperature of 180° C. or higher,
the reinforcing fibers [A] are present which are included in a resin area including [C] and a resin area including [D] across an interface between the two resin areas,
[E] is included in the structural component [D], and
the structural component [E] is included in an amount of 3 parts by mass or more and 30 parts by mass or less based on 100 parts by mass of the structural component [D]:

[A] reinforcing fibers;
[C] a thermoplastic resin;
[D] a cured product of a thermosetting resin, and
[E] a thermoplastic resin soluble in a thermosetting resin.

15. The laminate according to claim 14 , wherein, in a planar view of the laminate, when a cross-section perpendicular to a plane of the laminate including the [A] is obtained from a direction of an angle different by 45 degrees to a direction of any fiber [A] included in the two resin areas,
cross-sectional curve, formed by the interface between the two resin areas closely adhering to each other, in the cross-section, has an average roughness length RSm, defined in accordance with JIS B0601 (2001), of 100 μm or less, and an average roughness height Rc of 3.5 μm or more.

16. The laminate according to claim 1 , wherein the structural component [C] is present on the surface.

17. The laminate according to claim 14 , wherein the structural component [C] is present between layers.

18. The laminate according to claim 14 , wherein the structural component [C] is selected from a polyarylene ether ketone and a polyetherimide.

19. The laminate according to claim 18 , wherein the structural component [C] is a polyarylene ether ketone having a melting point of 200° C. to 340° C.

20. The laminate according to claim 14 , wherein the structural component [E] is in a dissolved state.

21. The laminate according to claim 14 , wherein the structural component [E] is a polyethersulfone or a polyetherimide.

22. The laminate according to claim 14 , wherein the average roughness height Rc is 10 μm or more.

23. The laminate according to claim 14 , wherein the structural component [A] includes a carbon fiber having a strand tensile strength of 5.5 GPa or more.

Assignees

• Toray Industries

Inventors

• Misumi Jun
• Honma Masato
• Shinohara Kyoko

Classifications

• B29C70/003 Primary

  characterised by the matrix material, e.g. material composition or physical properties · CPC title

• B29C70/0035

  comprising two or more matrix materials · CPC title

• B29C70/06

  Fibrous reinforcements only · CPC title

• B29C70/30

  Shaping by lay-up, i.e. applying fibres, tape or broadsheet on a mould, former or core; Shaping by spray-up, i.e. spraying of fibres on a mould, former or core · CPC title

• C08J5/04

  Reinforcing macromolecular compounds with loose or coherent fibrous material · CPC title