Catalyst separation process

Patent metadata

Field	Value
Publication number	US-11878296-B2
Application number	US-202117781950-A
Country	US
Kind code	B2
Filing date	Jan 25, 2021
Priority date	Jan 31, 2020
Publication date	Jan 23, 2024
Grant date	Jan 23, 2024

Abstract

A process for separating a catalyst component from a catalyst-containing slurry by centrifugation including separating the catalyst component from the mother liquor of the catalyst-containing slurry using a stacked disc centrifuge equipped with an auto-discharging functionality. The solids discharge from the stacked disc centrifuge is enhanced by adding a washing solution to the bowl and the solids discharge chute of the stacked disc centrifuge.

First claim

What is claimed is:

1. A process for separating a fine catalyst component from a catalyst-containing slurry by separating the catalyst component from the mother liquor of the catalyst-containing slurry, the process comprising:
(a) providing a stacked disc centrifuge equipped with an auto-discharging functionality;
(b) providing a catalyst-containing slurry comprising a mixture of: (i) at least one catalyst compound that is a double metal cyanide; and (ii) at least one liquid component;
(c) feeding the catalyst-containing slurry to the stacked disc centrifuge of step (a);
(d) centrifuging, for a predetermined period of time, the catalyst-containing slurry to form a cake material of catalyst solids in the centrifuge and a centrate; wherein the centrate is removed substantially continuously from the centrifuge during this centrifuging step (d) and the catalyst solids content in the cake material is from 10 weight percent to 40 weight percent; and
(e) removing the cake material from the centrifuge after the centrifugation of step (d).

2. The process of claim 1 , further including:
(f) washing the cake material of step (e) with a wash solution substantially simultaneously during the step (e) of removing the cake material from the centrifuge to remove any undesired components from the cake material.

3. The process of claim 2 , wherein the washing step of step (f) is carried out using water, butanol, polyether polyol or mixtures thereof as the wash solution.

4. The process of claim 1 , wherein the at least one liquid component is water.

5. The process of claim 1 , wherein the feeding rate of the catalyst-containing slurry to the centrifuge is from 0.001 liters per hour to 300 liters per hour.

6. The process of claim 1 , including further operating the centrifuge at a centrifugal force of from 6,000 G-force to 14,000 G-force.

7. The process of claim 1 , including further discharging isolated solids from the centrifuge at predetermined intervals in a time period of from 5 minutes to 60 minutes.

8. The process of claim 1 , wherein the resultant centrate produced from the centrifugation is visibly clear with a total suspended solids loss of from 0.005 weight percent to 0.2 weight percent.

9. The process of claim 1 , further including:
(g) injecting a washing liquid into the centrifuge after the centrifugation step (d) and prior to removing step (e).

10. A catalyst product produced by the process of claim 1 .

Assignees

• Dow Global Technologies Llc

Inventors

• Kumbhalkar Mrunmayi
• Chen Wu
• Murdoch Brian
• Shi Haifeng
• Zhao Lin

Classifications

• B01J38/72 Primary

  including segregation of diverse particles · CPC title

• B01J27/26

  Cyanides · CPC title

• B01J27/28

  Regeneration or reactivation · CPC title

• B01J37/009 Primary

  Preparation by separation, e.g. by filtration, decantation, screening · CPC title

• B01D21/262

  by using a centrifuge · CPC title