Methods for electrochemical cell remediation

Patent metadata

Field	Value
Publication number	US-11876194-B2
Application number	US-202117371345-A
Country	US
Kind code	B2
Filing date	Jul 9, 2021
Priority date	Jun 19, 2015
Publication date	Jan 16, 2024
Grant date	Jan 16, 2024

Abstract

Embodiments described herein relate generally to methods for the remediation of electrochemical cell electrodes. In some embodiments, a method includes obtaining an electrode material. At least a portion of the electrode material is rinsed to remove a residue therefrom. The electrode material is separated into constituents for reuse.

First claim

The invention claimed is:

1. A method for recycling a binderless electrode material, the method comprising:
separating the binderless electrode material from a current collector with substantially no current collector material present in the binderless electrode material after separation;
rinsing the binderless electrode material with an organic solvent to remove a residue; and
separating the binderless electrode material into a first portion and a second portion based on magnetic properties of the first portion and the second portion, the separating performed using at least one of air classification, field flow fractionation, or electrophoresis, the first portion including an active material and the second portion including a conductive additive.

2. The method of claim 1 , further including:
combining a second additive with at least one of the first portion or the second portion to alter a stoichiometry and/or a crystallinity thereof.

3. The method of claim 2 , wherein the binderless electrode material is a cathode material, and the second additive is a lithium-containing additive.

4. The method of claim 1 , further including:
heating the second additive and at least one of the first portion or the second portion to produce a remediated binderless electrode material.

5. The method of claim 1 , wherein separating the binderless electrode material from the current collector further includes using at least one of a centrifuge, filtration, sieving, and sedimentation.

6. The method of claim 1 , wherein rinsing the binderless electrode material includes immersing at least a portion of the binderless electrode material in the organic solvent.

7. The method of claim 1 , wherein the residue includes at least a portion of an electrolyte salt, an electrolyte solvent, and a reaction product, including a solid electrolyte interphase material.

8. The method of claim 1 , wherein the organic solvent includes at least one of ethylmethyl carbonate, dipropyl carbonate, methyl propyl carbonate, ethyl propyl carbonate, dibutyl carbonate, butylmethyl carbonate, butylethyl carbonate, butylpropyl carbonate, y-butyrolactone, dimethoxyethane, tetrahydrofuran, 2-methyltetrahydrofuran, 4-methyl-1,3-dioxolane, diethyl ether, sulfolane, methylsulfolane, acetonitrile, propiononitrile, ethyl acetate, methyl propionate, ethyl propionate, teraglyme, and 1,3-dioxolane.

9. A method for electrode remediation, the method comprising:
mechanically separating an electrode material from a current collector, the electrode material including an active material, a conductive additive, an electrolyte salt, and an electrolyte solvent, and is substantially free of a binder and current collector material after separation;
rinsing the electrode material with a solvent to remove the electrolyte salt and the electrolyte solvent from the active material and the conductive additive; and
magnetically separating the electrode material into a first portion and a second portion, the separating performed using at least one of air classification, field flow fractionation, or electrophoresis, the first portion including the active material and the second portion including the conductive additive.

10. The method of claim 9 , wherein the electrode material is a semi-solid depleted electrode material.

11. The method of claim 9 , wherein the solvent includes at least one of ethylmethyl carbonate, dipropyl carbonate, methyl propyl carbonate, ethyl propyl carbonate, dibutyl carbonate, butylmethyl carbonate, butylethyl carbonate, butylpropyl carbonate, y-butyrolactone, dimethoxyethane, tetrahydrofuran, 2-methyltetrahydrofuran, 4-methyl-1,3-dioxolane, diethyl ether, sulfolane, methylsulfolane, acetonitrile, propiononitrile, ethyl acetate, methyl propionate, ethyl propionate, teraglyme, or 1,3-dioxolane.

12. The method of claim 9 , the method further comprising:
combining a second additive with at least one of the first portion or the second portion to alter a stoichiometry and/or a crystallinity thereof; and
heat treating the combined second additive and at least one of the first portion or the second portion to form a remediated electrode material.

13. The method of claim 9 , wherein the electrode material is rinsed prior to separating the electrode material into the first portion and the second portion.

14. A method for electrode remediation, the method comprising:
separating a semi-solid electrode material from a current collector, the semi-solid electrode material including an active material, an electrolyte salt, and an electrolyte solvent, and is substantially free of a binder and current collector material after separation;
rinsing the semi-solid electrode material with a solvent to remove the electrolyte salt and the electrolyte solvent from the active material; and
separating the semi-solid electrode material into a first portion and a second portion via at least one of air classification, field flow fractionation, or electrophoresis, the first portion including an active material and the second portion including a conductive additive.

15. The method of claim 14 , wherein the semi-solid electrode material includes at least one of LiCoO 2 (“LCO”), Li(Ni, Mn, Co)O 2 (“NMC”), LiNi 0.8 Co 0.15 Al 0.05 O 2 (“NCA”), LiMn 2 O 4 (“LMO”), LiCoPO 4 (“LCP”), or LiNiPO 4 (“LNP”).

16. The method of claim 14 , wherein the semi-solid electrode material includes at least one of LiFePO 4 (“LFP”), LiMnPO 4 (“LMP”), LiMn 1-x Fe x PO 4 (“LMFP”), or Li 4 Ti 5 O 12 (“LTO”).

17. The method of claim 14 , wherein rinsing the semi-solid electrode material includes immersing at least a portion of the semi-solid electrode material in the solvent.

18. The method of claim 14 , wherein the semi-solid electrode material is binderless.

19. The method of claim 14 , wherein the solvent includes at least one of ethylmethyl carbonate, dipropyl carbonate, methyl propyl carbonate, ethyl propyl carbonate, dibutyl carbonate, butylmethyl carbonate, butylethyl carbonate, butylpropyl carbonate, y-butyrolactone, dimethoxyethane, tetrahydrofuran, 2-methyltetrahydrofuran, 4-methyl-1,3-dioxolane, diethyl ether, sulfolane, methylsulfolane, acetonitrile, propiononitrile, ethyl acetate, methyl propionate, ethyl propionate, teraglyme, or 1,3-dioxolane.

Assignees

• 24M Tech Inc

Inventors

• Chiang Yet-Ming
• Woodford William Henry
• Yu Hiuling Zoe

Classifications

• Y02E60/10

  Energy storage using batteries · CPC title

• H01M10/54 Primary

  Reclaiming serviceable parts of waste accumulators · CPC title

• H01M6/52 Primary

  Reclaiming serviceable parts of waste cells or batteries {, e.g. recycling} · CPC title

• Y02W30/84

  Recycling of batteries or fuel cells · CPC title