Metal-CNT composite, production method and materials therefor

Patent metadata

Field	Value
Publication number	US-11873570-B2
Application number	US-201917259211-A
Country	US
Kind code	B2
Filing date	Aug 22, 2019
Priority date	Aug 27, 2018
Publication date	Jan 16, 2024
Grant date	Jan 16, 2024

Abstract

According to a first aspect of the invention, a method for producing a metal-CNT composite material is proposed. The method includes providing a layer of CNT by depositing CNT coated with a polyphenol or poly(catecholamine) coating and filling the interstices of the carbon nanotubes layer with a metal so as to form a metal matrix, in which CNT are embedded. The filling is effected by electrode position or by electroless deposition. The polyphenol or poly(catecholamine) coating is crosslinked by metal ions, the metal ions promoting, as metal seeds, adhesion and/or growth of the metal matrix during the filling step. A further aspect of the invention relates to the metal-CNT composite obtainable by the method.

First claim

The invention claimed is:

1. A composite conductive material comprising:
a layer of carbon nanotubes,
a metal matrix filling the interstices of the carbon nanotubes layer;
wherein the carbon nanotubes comprise a graphitised or amorphous carbon coating at the interfaces with the metal matrix.

2. A method for producing a composite material, comprising:
providing a layer of carbon nanotubes by depositing, on a substrate, carbon nanotubes coated with a polyphenol coating, the polyphenol coating being a tannic acid-metal complex crosslinked by metal ions,
filling interstices of the carbon nanotubes layer with a metal so as to form a metal matrix, in which the carbon nanotubes are embedded, said filling being effected by electrodeposition or by electroless deposition;
wherein said metal ions promote, as metal seeds, at least one of adhesion and growth of the metal matrix during the filling step.

3. The method as claimed in claim 2 , wherein the coated carbon nanotubes are provided within a suspension and wherein depositing the carbon nanotubes comprises spraying the suspension on the substrate and causing the dispersion medium to evaporate, the spraying being repeated until a desired thickness of the carbon nanotubes layer is reached.

4. The method as claimed in claim 2 , wherein the metal matrix consists of a metal selected from: Cu, Ag, Au, Sn, Zn, Cd, Cr, Ni, Pt, Pb, Pd, Co, Ti, Fe, and an alloy thereof.

5. The method as claimed in claim 3 , wherein the filling of the interstices of the carbon nanotubes layer is effected by electroless deposition from an aqueous solution comprising metal ions.

6. The method as claimed in claim 5 , wherein the layer of carbon nanotubes is removed from the substrate on which it has been deposited prior to or during electroless deposition.

7. The method as claimed in claim 2 , wherein the composite material is produced as one or more electrical conductors on a substrate by using a patterning technique.

8. A method for producing a composite material, comprising:
providing a layer of carbon nanotubes by depositing, on a substrate, carbon nanotubes coated with a polyphenol coating, the polyphenol coating being crosslinked by metal ions,
filling interstices of the carbon nanotubes layer with a metal so as to form a metal matrix, in which the carbon nanotubes are embedded, said filling being effected by electrodeposition from an aqueous solution comprising metal ions;
wherein said metal ions promote, as metal seeds, at least one of adhesion and growth of the metal matrix during the filling step.

9. The method as claimed in claim 8 , wherein the coated carbon nanotubes are provided within a suspension and wherein depositing the carbon nanotubes comprises spraying the suspension on the substrate and causing the dispersion medium to evaporate, the spraying being repeated until a desired thickness of the carbon nanotubes layer is reached.

10. The method as claimed in claim 8 , wherein the metal matrix consists of a metal selected from: Cu, Ag, Au, Sn, Zn, Cd, Cr, Ni, Pt, Pb, Pd, Co, Ti, Fe, and an alloy thereof.

11. The method as claimed in claim 8 , wherein the carbon nanotubes are coated with a polydopamine coating or with a tannic acid-metal complex.

12. The method as claimed in claim 8 , comprising coating the carbon nanotubes with the polyphenol coating, the coating being carried out in a solution containing at least one of phenol and catecholamine moieties wherein initially uncoated carbon nanotubes are dispersed, the solution further containing metal ions capable of crosslinking the at least one of phenol and catecholamine moieties.

13. The method as claimed in claim 12 , wherein the carbon nanotubes are oxidized prior to dispersion in the solution containing that at least one of phenol and catecholamine moieties.

14. The method as claimed in claim 8 , wherein the composite material is produced as one or more electrical conductors on a substrate by using a patterning technique.

15. A method for producing a composite material, comprising:
providing a layer of carbon nanotubes by depositing, on a substrate, carbon nanotubes coated with a polyphenol coating, the polyphenol coating being crosslinked by metal ions,
filling interstices of the carbon nanotubes layer with a metal so as to form a metal matrix, in which the carbon nanotubes are embedded, said filling being effected by electrodeposition or by electroless deposition;
wherein said metal ions promote, as metal seeds, at least one of adhesion and growth of the metal matrix during the filling step,
wherein deposition of the metal matrix is continued when the filling of the interstices is complete, so as to form a metal capping layer on the composite material.

16. The method as claimed in claim 15 , wherein the coated carbon nanotubes are provided within a suspension and wherein depositing the carbon nanotubes comprises spraying the suspension on the substrate and causing the dispersion medium to evaporate, the spraying being repeated until a desired thickness of the carbon nanotubes layer is reached.

17. The method as claimed in claim 15 , wherein the metal matrix consists of a metal selected from: Cu, Ag, Au, Sn, Zn, Cd, Cr, Ni, Pt, Pb, Pd, Co, Ti, Fe, and an alloy thereof.

18. The method as claimed in claim 15 , wherein the carbon nanotubes are coated with a polydopamine coating or with a tannic acid-metal complex.

19. The method as claimed in claim 15 , wherein said filling is effected by electroless deposition and wherein the layer of carbon nanotubes is removed from the substrate on which it has been deposited prior to or during electroless deposition.

20. The method as claimed in claim 15 , comprising coating the carbon nanotubes with the polyphenol coating, the coating being carried out in a solution containing at least one of phenol and catecholamine moieties wherein initially uncoated carbon nanotubes are dispersed, the solution further containing metal ions capable of crosslinking the at least one of phenol and catecholamine moieties, wherein the carbon nanotubes are oxidized prior to dispersion in the solution containing that at least one of phenol and catecholamine moieties.

21. The method as claimed in claim 15 , wherein the composite material is produced as one or more electrical conductors on a substrate by using a patterning technique.

22. A method for producing a composite material, comprising:
providing a layer of carbon nanotubes by depositing, on a substrate, carbon nanotubes coated with a polyphenol coating, the polyphenol coating being crosslinked by metal ions,
filling interstices of the carbon nanotubes layer with a metal so as to form a metal matrix, in which the carbon nanotubes are embedded, said filling being effected by electrodeposition or by electroless deposition;
wherein said metal ions promote, as metal seeds, at least one of adhesion and growth of the metal matrix during the filling step; and
wherein the composite material is annealed.

23. The method as claimed in claim 22 , wherein the coated carbon nanotubes are provided within a suspension and wherein depositing the carbon nanotubes comprises spraying the suspension on the substrate and causing the dispersion medium to evaporate, the spraying being repeated until a desired thickness of the carbon nanotubes layer is reached.

24. The method as claimed in claim 22 , wherein the metal matrix consists of a metal selected from: Cu, Ag, Au, Sn, Zn, Cd, Cr, Ni, Pt, Pb, P

Assignees

• Luxembourg Inst Science & Tech List

Inventors

• DUHAIN Antoine
• Michel Marc
• Lamblin Guillaume
• Lenoble Damien

Classifications

• C25D5/56 Primary

  of plastics · CPC title

• C01B32/168 Primary

  After-treatment · CPC title

• C23C18/1662

  Use of incorporated material in the solution or dispersion, e.g. particles, whiskers, wires · CPC title

• B82Y30/00

  Nanotechnology for materials or surface science, e.g. nanocomposites · CPC title

• B82Y40/00

  Manufacture or treatment of nanostructures · CPC title