Heterophasic polyolefin composition

Patent metadata

Field	Value
Publication number	US-11873397-B2
Application number	US-201917292063-A
Country	US
Kind code	B2
Filing date	Nov 14, 2019
Priority date	Nov 15, 2018
Publication date	Jan 16, 2024
Grant date	Jan 16, 2024

Abstract

The invention provides a polyolefin composition comprising: (i) 55 to 95 wt % of a propylene butene random copolymer having an MFR 2 of 1.0 to 20.0 g/10 min, a butene content of 1.5 to 8.0 wt % and prepared using a single site catalyst; and (ii) to 45 wt % of an ethylene based plastomer having a density of 860 to 905 kg/m 3 , an MFR 2 of 0.3 to 30 g/10 min and prepared using a single site catalyst.

First claim

The invention claimed is:

1. A polyolefin composition comprising:
(i) 55 to 95 wt % of a propylene butene random copolymer having an MFR 2 of 1.0 to 20.0 g/10 min, a butene content of 1.5 to 8.0 wt % and prepared using a single site catalyst; and
(ii) 5 to 45 wt % of an ethylene based plastomer having a density of 860 to 905 kg/m 3 , an MFR 2 of 0.3 to 30 g/10 min and prepared using a single site catalyst,
wherein the propylene butene random copolymer (i) and the ethylene based plastomer (ii) are the sole polymer components in the composition.

2. The polyolefin composition as claimed in claim 1 , wherein the propylene butene random copolymer is a multimodal copolymer comprising:
(A) 30 to 70 wt % of a propylene butene copolymer having an MFR 2 of 0.5 to 20.0 g/10 min and a butene content of 0.5 to 10.0 wt %; and
(B) 70 to 30 wt % of a propylene butene copolymer having an MFR 2 of 0.5 to 20.0 g/10 min and a butene content of 1.0 to 8.0 wt %;

wherein copolymers (A) and (B) are different.

3. The polyolefin composition as claimed in claim 1 , wherein said single site catalyst is a metallocene catalyst.

4. The polyolefin composition as claimed in claim 1 , wherein the butene content of said propylene butene copolymer is in the range 3.0 to 5.0 wt %.

5. The polyolefin composition as claimed in claim 1 , wherein said propylene butene random copolymer is substantially free of ethylene.

6. The polyolefin composition as claimed in claim 1 , wherein the ethylene based plastomer is a copolymer of ethylene and at least one C3-C10 alpha-olefin.

7. The polyolefin composition as claimed in claim 1 , wherein said composition has a flexural modulus of at least 550 MPa.

8. The polyolefin composition as claimed in claim 1 , wherein said composition has a haze of 40% or less.

9. The polyolefin composition as claimed in claim 2 , wherein the comonomer content of Fraction (B) is less than the comonomer content of Fraction (A).

10. A process of making the composition as defined in claim 1 , comprising mixing and/or blending the propylene butene random copolymer and the ethylene based plastomer.

11. The process as defined in claim 10 , wherein the propylene butene random copolymer is prepared by a process comprising:
(i) polymerising propylene and butene in a first polymerisation stage in the presence of a single site catalyst to prepare a first propylene butene copolymer having a MFR 2 from 0.5 to 20.0 g/10 min and a butene content of 0.5 to 10.0 wt %;
(ii) polymerising propylene and butene in a second polymerisation stage in the presence of said catalyst and said first propylene butene copolymer to prepare said random copolymer.

12. The process as claimed in claim 11 , wherein the first polymerisation stage is carried out in a loop reactor and the second polymerisation stage is carried out in a gas phase reactor.

13. An article comprising the polyolefin composition as defined in claim 1 .

14. The article as claimed in claim 13 , wherein said article is a film or a moulded article.

15. The process of claim 10 , wherein the mixing and/or blending comprises a step of extrusion.

16. A process of making an article comprising the polyolefin composition of claim 1 .

Assignees

• Borealis Ag

Inventors

• Wang Jingbo
• Gahleitner Markus
• Bernreitner Klaus
• Leskinen Pauli
• Hoff Matthias

Classifications

• C08L53/00 Primary

  Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers · CPC title

• C08F297/083

  the monomers being ethylene or propylene · CPC title

• C08J5/18

  Manufacture of films or sheets · CPC title

• C08F2420/00

  Metallocene catalysts · CPC title

• C08J2353/00

  Characterised by the use of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers · CPC title