Process for the production of urea formaldehyde concentrate

Patent metadata

Field	Value
Publication number	US-11873268-B2
Application number	US-202017420025-A
Country	US
Kind code	B2
Filing date	Mar 5, 2020
Priority date	Mar 15, 2019
Publication date	Jan 16, 2024
Grant date	Jan 16, 2024

Abstract

Parallel co-production process for the production of methanol and urea product from a hydrocarbon containing feed-stock by means of primary and secondary reforming, intermediary methanol and ammonia formation and conversion of the ammonia to urea product and catalytic oxidation of methanol to formaldehyde.

First claim

The invention claimed is:

1. A process for the production of a urea formaldehyde concentrate from a hydrocarbon feedstock comprising steps of:
(a) producing a synthesis gas containing hydrogen, carbon monoxide, carbon dioxide and nitrogen by steam reforming the hydrocarbon feedstock in a primary reforming stage and subsequently in a secondary reforming stage;
(b) splitting the synthesis gas from step (a) into a methanol synthesis gas and an ammonia synthesis gas;
(c) subjecting the ammonia synthesis gas from step (b) in series to a high temperature water gas shift and a low temperature water gas shift conversion;
(d) removing at least part of the carbon dioxide from the ammonia synthesis gas from step (c) to obtain a carbon dioxide depleted ammonia synthesis gas;
(e) subjecting the carbon dioxide depleted ammonia synthesis gas from step (d) to catalytic methanation to remove the unconverted carbon monoxide to obtain a purified ammonia synthesis gas;
(f) catalytically converting the nitrogen and hydrogen in the purified ammonia synthesis gas from step (e) in an ammonia synthesis stage and withdrawing an effluent containing ammonia;
(g) passing at least part of the ammonia containing effluent to a urea synthesis stage, converting the ammonia in the effluent to urea product by reaction with at least part of the carbon dioxide being removed from the synthesis gas in step (d), and preparing an aqueous urea solution from the urea product;
(h) catalytically converting the carbon monoxide, carbon dioxide and hydrogen of the methanol synthesis gas from step (b) in a once-through methanol synthesis stage and withdrawing an effluent containing methanol and an effluent containing nitrogen, hydrogen and unconverted carbon monoxide and carbon dioxide;
(i) recycling the effluent containing nitrogen, hydrogen and un-converted carbon monoxide and carbon dioxide: (i) to a fuel header as fuel to the primary reforming stage in step (a) and/or (ii) to the low temperature shift conversion in step (c);
(j) subjecting the effluent containing methanol to distillation and withdrawing purified methanol from the distillation;
(k) oxidizing at least a part of the purified methanol from step (j) to formaldehyde;
(l) absorbing the formaldehyde from step (k) in an absorber with water and the aqueous urea solution prepared from the urea product in step (g) to obtain the urea formaldehyde concentrate,
wherein the effluent containing nitrogen, hydrogen and unconverted carbon monoxide and carbon dioxide in step (i) is recycled to the low temperature shift conversion in step (c) with an ejector using main flow from the high temperature water gas shift as motive flow and the effluent as suction flow.

2. The process of claim 1 , further comprising admixing the urea formaldehyde concentrate to urea pellets or granulate.

3. The process according to claim 1 , the methanol synthesis stage in step (h) is performed in at least one methanol reactor containing one or two fixed beds comprising a methanol catalyst.

Assignees

• Haldor Topsoe As
• Topsoe As

Inventors

• Symreng Marcus
• Han Pat A

Classifications

• C07C273/04 Primary

  from carbon dioxide and ammonia · CPC title

• C01B3/025

  Preparation or purification of gas mixtures for ammonia synthesis · CPC title

• C01B3/382

  Processes with two or more reaction steps, of which at least one is catalytic, e.g. steam reforming and partial oxidation · CPC title

• C01C1/0488

  Processes integrated with preparations of other compounds, e.g. methanol, urea or with processes for power generation · CPC title

• C07C29/152

  characterised by the reactor used · CPC title