Copper and nitrogen treated sorbent and method for making same

Patent metadata

Field	Value
Publication number	US-11872539-B2
Application number	US-202117446532-A
Country	US
Kind code	B2
Filing date	Aug 31, 2021
Priority date	Aug 31, 2020
Publication date	Jan 16, 2024
Grant date	Jan 16, 2024

Abstract

Carbonaceous material that is activated to form precursor activated carbon is further enhanced by doping with copper and nitrogen and calcining. The resultant sorbent material has excellent catalytic properties which are useful in the field of fluid purification.

First claim

The invention claimed is:

1. A method of manufacturing a sorbent material, the method comprising:
providing a carbonaceous material;
activating the carbonaceous material to form a precursor activated carbon;
doping the precursor activated carbon by contacting the precursor activated carbon with a copper source and a nitrogen source to thereby form a doped precursor activated carbon;
wherein the copper source comprises copper sulfate pentahydrate, CuSO 4 ·5H 2 O, or copper (II) carbonate hydroxide, CuCO 3 (OH) 2 , and the nitrogen source comprises one or more of urea, CO(NH 2 ) 2 , ammonium carbonate, (NH 4 ) 2 CO 3 , or aqueous ammonium hydroxide, NH 4 OH (nominally aq, 28 wt. %);
calcining the doped precursor activated carbon in a calcining atmosphere that does not cause any substantial oxidation or activation of the doped precursor activated carbon to thereby form a sorbent material.

2. The method of claim 1 , wherein the copper source comprises copper sulfate pentahydrate, CuSO 4 ·5H 2 O, and the nitrogen source comprises one or more of urea, CO(NH 2 ) 2 , ammonium carbonate, (NH 4 ) 2 CO 3 , or aqueous ammonium hydroxide, NH 4 OH (nominally aq, 28 wt. %).

3. The method of claim 2 , wherein the copper source comprises copper sulfate pentahydrate, CuSO 4 ·5H 2 O, and the nitrogen source comprises urea, CO(NH 2 ) 2 .

4. The method of claim 1 , wherein the copper source comprises copper (II) carbonate hydroxide, CuCO 3 (OH) 2 , and the nitrogen source comprises one or more of urea, CO(NH 2 ) 2 , ammonium carbonate, (NH 4 ) 2 CO 3 , or aqueous ammonium hydroxide, NH 4 OH (nominally aq, 28 wt. %).

5. The method of claim 1 , wherein calcining is performed at a temperature of about 850° C. to about 1050° C. in a N 2 atmosphere.

6. The method of claim 1 , further comprising oxidizing the precursor activated carbon prior to doping.

7. The method of claim 1 , wherein doping the precursor activated carbon is performed in a single stage process, the single stage process including a single step of contacting the precursor activated carbon with both a copper source and a nitrogen source.

8. The method of claim 5 , wherein contacting the precursor activated carbon with the copper source and the nitrogen source is performed with a single aqueous solution that contains both the copper source and the nitrogen source.

9. The method of claim 6 , wherein the precursor activated carbon is dried after it is contacted with the single aqueous solution containing the copper source and the nitrogen source.

10. The method of claim 1 , wherein calcining is performed at a temperature of about 600° C. to about 1000° C. in a N 2 atmosphere.

11. The method of claim 1 , wherein calcining is performed at a temperature of about 700° C. to about 1000° C. in a N 2 atmosphere.

12. The method of claim 1 , wherein calcining is performed at a temperature of about 850° C. to about 1000° C. in a N 2 atmosphere.

13. The method of claim 1 , further comprising oxidizing the precursor activated carbon prior to doping.

Assignees

• Calgon Carbon Corp

Inventors

• Mazzoccoli Jason P
• Walker Ryan W
• Tramposch Walter G

Classifications

• B01J2220/4825

  Polysaccharides or cellulose materials, e.g. starch, chitin, sawdust, wood, straw, cotton · CPC title

• B01J20/06

  comprising oxides or hydroxides of metals not provided for in group B01J20/04 · CPC title

• B01J20/02 Primary

  comprising inorganic material · CPC title

• B01J20/324 Primary

  containing free carbon, e.g. activated carbon · CPC title

• B01J6/001

  Calcining · CPC title