System and method for separating solvent from a fluid

Patent metadata

Field	Value
Publication number	US-11872528-B2
Application number	US-202117522076-A
Country	US
Kind code	B2
Filing date	Nov 9, 2021
Priority date	Nov 9, 2021
Publication date	Jan 16, 2024
Grant date	Jan 16, 2024

Abstract

An electrochemical system has a first reservoir receiving a feed stream. The feed stream includes a solvent and a solute different than the salt. A second reservoir receives a brine stream with a higher salt concentration higher than the feed stream. Electrodes contact a loop of redox-active electrolyte material causing reversible redox reactions. The reactions cause the loop to accept a first ion from the salt in the first reservoir and drive a second ion into the brine stream in the second reservoir. Three ionic exchange membranes of alternating type define the first and second reservoirs. A concentrate stream is output from the first reservoir, the concentrate stream having a second solute concentration greater than the first solute concentration.

First claim

What is claimed is:

1. An electrochemical system, comprising:
a first reservoir receiving a feed stream, wherein the feed stream comprises a solvent, a salt having a first salt concentration in the feed stream, and a solute different than the salt at a first solute concentration;
a second reservoir receiving a brine stream, the brine stream having a second salt concentration higher than the first salt concentration;
a first electrode contacting a first solution of a first redox-active electrolyte material and configured to have a first reversible redox reaction with the first redox-active electrolyte material, and accept a first ion from the salt in the first reservoir;
a second electrode contacting a second solution of a second redox-active electrolyte material and configured to have a second reversible redox reaction with the second redox-active electrolyte material, and drive a second ion into the brine stream in the second reservoir;
an energy source configured to supply electrical potential to the first and second electrodes;
a first membrane having a first ion exchange type disposed between the first and second reservoirs;
a second membrane having a second ion exchange type, different from the first ion exchange type, disposed between the first electrode and the first reservoir;
a third membrane having the second ion exchange type disposed between the second electrode and the second reservoir;
an effluent stream comprising the solvent and a third salt concentration output from the second reservoir, wherein the solvent is removed from the first reservoir via electroosmosis and forward osmosis; and
a concentrate stream output from the first reservoir, the concentrate stream comprising a fourth salt concentration that is less than the first, second, and third salt concentrations, and a second solute concentration greater than the first solute concentration.

2. The system of claim 1 , wherein the electroosmosis involves salt ions dragging molecules of the solvent out of the first reservoir through the first and second membranes.

3. The system of claim 1 , wherein the forward osmosis is due to the brine stream in the second reservoir having a higher osmotic pressure than the feed stream in the first reservoir.

4. The system of claim 1 , wherein the fourth salt concentration is less than 0.05% by weight.

5. The system of claim 1 , wherein the solute comprises sugar.

6. The system of claim 1 , wherein the solvent is water.

7. The system of claim 1 , wherein the first solution and the second solution are the same and the first and second solutions are circulated between the first electrode and the second electrode when a charge is applied to the electrodes.

8. The system of claim 1 , wherein the first reservoir, the second reservoir, a membrane of the first type, and a membrane of the second type form a cell, and the system comprises a plurality of cells coupled together between the first and second electrodes.

9. The system of claim 1 , wherein a portion of the brine stream is fed to the first reservoir.

10. The system of claim 1 , further comprising a liquid concentrator coupled to the effluent stream and configured to regenerate the brine stream and produce a waste stream comprising the solvent.

11. The system of claim 10 , wherein the liquid concentrator is an electrochemical liquid regenerator utilizing a redox shuttle.

12. The system of claim 1 , wherein the first membrane and the second membrane have a first set of electroosmotic and osmotic transport properties and the third membrane has a second set of electroosmotic and osmotic transport properties that are different from the first set of properties, the system further comprising:
a third reservoir defined by the second membrane and a fourth membrane having the first ion exchange type and the second set of electroosmotic and osmotic transport properties, wherein a second portion of the brine stream is input to the third reservoir;
a fourth reservoir defined by the fourth membrane and a fifth membrane having the second ion exchange type and the second set of electroosmotic and osmotic transport properties, wherein a third portion of the brine stream is input to the fourth reservoir;
a second effluent stream comprising the solvent and a fifth salt concentration output from the third reservoir, wherein the solvent is moved from the first and fourth reservoirs to the third reservoir via electroosmosis and forward osmosis; and
a solvent stream comprising a sixth salt concentration output from the fourth reservoir.

13. The system of claim 12 , wherein the effluent stream and the second effluent stream are combined and recirculated as the brine stream input to the second, third, and fourth reservoirs.

14. The system of claim 12 , wherein the first, second, third and fourth reservoirs and the first, second, third, and fourth membranes form a regeneration cell, and the system comprises a plurality of regeneration cells coupled together by the fourth membrane of a first regeneration cell and the third membrane of a second regeneration cell defining the fourth reservoir of the first regeneration cell.

Assignees

• Palo Alto Res Ct Inc
• Xerox Corp

Inventors

• Beh Eugene S
• Benedict Michael

Classifications

• B01D61/58 Primary

  Multistep processes · CPC title

• B01D61/002

  Forward osmosis or direct osmosis · CPC title

• B01D61/427

  Electro-osmosis · CPC title

• C02F1/445

  by forward osmosis · CPC title

• C02F1/4698

  electro-osmosis · CPC title