TOC analyzer and method for moistening a binder in a TOC analyzer

Patent metadata

Field	Value
Publication number	US-11867681-B2
Application number	US-202117645158-A
Country	US
Kind code	B2
Filing date	Dec 20, 2021
Priority date	Dec 21, 2020
Publication date	Jan 9, 2024
Grant date	Jan 9, 2024

Abstract

A TOC analyzer for determining a carbon content of a sample includes: a processing unit for removing carbon dioxide gas from the carrier gas before the oxidation of the sample, wherein the processing unit has a binder for binding the carbon dioxide gas from the carrier gas, wherein a defined water content is provided within the binder, wherein the processing unit is configured for moistening the binder by means of water vapor contained in the carrier gas; a condensation unit for condensing the water vapor resulting from the vaporization and/or oxidation of the sample to form a condensate, wherein the condensation unit has an outlet for the condensate toward a moistening unit; and the moistening unit for moistening the carrier gas by means of the condensate. A method for moistening a binder using such a TOC analyzer is further disclosed.

First claim

We claim:

1. A TOC analyzer for determining a carbon content of a sample, wherein the sample contains at least one analyte and water, the analyzer comprising:
an inlet adapted to convey a carrier gas, wherein the carrier gas is provided as to transport a carbon dioxide gas resulting from oxidation of the sample to an analysis unit;
a processing unit configured to remove carbon dioxide gas from the carrier gas before the oxidation of the sample, wherein the processing unit includes a binder selected for binding the carbon dioxide gas from the carrier gas, wherein a defined water content is provided within the binder, wherein the processing unit is further configured to moisten the binder using water vapor contained in the carrier gas;
a high-temperature furnace configured to vaporize and/or oxidize the sample at a high temperature to form water vapor and carbon dioxide gas;
an injection unit adapted to inject the sample into the high-temperature furnace;
a condensation unit configured to condense the water vapor resulting from the vaporization and/or oxidation of the sample to form a condensate, wherein the condensation unit includes an outlet for the condensate and is connected to a moistening unit;
the moistening unit, which is adapted to moistening the carrier gas using the condensate; and
the analysis unit, which is configured to determine the carbon content of the sample based on the carbon dioxide gas resulting from the oxidation of the sample.

2. The analyzer of claim 1 , wherein the binder comprises soda lime.

3. The analyzer of claim 1 , wherein the carrier gas is ambient air, compressed air, nitrogen, or a mixture of gas comprising nitrogen and oxygen.

4. The analyzer of claim 1 , wherein the outlet of the condensation unit is configured as a valve or siphon.

5. The analyzer of claim 1 , further comprising a pump configured to facilitate transporting the condensate from the condensation unit into the moistening unit.

6. The analyzer of claim 1 , wherein the moistening unit is pipe-like or hose-like such that the carrier gas and the condensate can be guided past one another.

7. The analyzer of claim 1 , wherein the moistening unit includes a vessel configured to collect the condensate and to enable the carrier gas to be guided through the vessel.

8. The analyzer of claim 7 , wherein the vessel of the moistening unit includes a drain configured such that excess condensate can be discharged from the vessel.

9. The analyzer of claim 7 , wherein the vessel is configured at least in part as a siphon.

10. The analyzer of claim 7 , wherein the vessel includes a fill level sensor configured to determine and/or monitor the fill level of the condensate within the vessel.

11. The analyzer of claim 10 , the moistening unit includes a suction device arranged on the vessel such that, when a predefined fill level of the condensate is exceeded, the condensate is at least partially suctioned out of the vessel.

12. The analyzer of claim 1 , wherein the condensation unit is adapted to be cooled.

13. A method for moistening a binder in a TOC analyzer, the method comprising:
injecting and vaporizing and/or oxidizing a sample in the high-temperature furnace;
condensing water vapor resulting from the vaporization and/or oxidation of the sample in a condensation unit as a condensate;
discharging the condensate into the moistening unit;
moistening the carrier gas using the condensate in the moistening unit; and
moistening the binder using the moistened carrier gas in a processing unit configured to remove carbon dioxide gas from the carrier gas before the oxidation of the sample, wherein the processing unit includes the binder, which is selected for binding the carbon dioxide gas from the carrier gas,
wherein the processing unit is further configured to moisten the binder using water vapor contained in the carrier gas to a defined water content.

Assignees

• Endress Hauser Conducta Gmbh Co Kg
• Endress Hauser Se Co Kg

Inventors

• Schweitzer Daniel
• Kathe Ulrich
• Ingelmann Michael

Classifications

• G01N33/1846 Primary

  Total carbon analysis · CPC title

• G01N31/12

  using combustion (G01N25/20 takes precedence) · CPC title