Product of low benzene content de-aromatized distillates for specialty applications

Patent metadata

Field	Value
Publication number	US-11866658-B2
Application number	US-202218084099-A
Country	US
Kind code	B2
Filing date	Dec 19, 2022
Priority date	Dec 18, 2021
Publication date	Jan 9, 2024
Grant date	Jan 9, 2024

Abstract

A process for the production of ultralow aromatic specialty distillate from different refinery streams particularly high sulfur streams. The process produces de-aromatized distillates with benzene content below 1 ppmw. Hydrocarbon feedstock having boiling temperature in the range of 90 and 350° C., preferably 140 and 320° C. The hydrocarbon feedstocks are obtained from any petroleum-refinery or bio-refinery or any other source producing hydrocarbon streams.

First claim

We claim:

1. A process for production of de-aromatize distillate from a hydrocarbon feedstock, the process comprising:
a) treating the hydrocarbon feedstock over a hydrotreating catalyst under hydrogen, in a hydrotreating reactor system (Reactor-1) for converting hetero-atom contaminants into their respective hydrides;
b) flashing an effluent from the Reactor-1 in a high-pressure separator (HPS), and withdrawing an off-gas containing un-reacted hydrogen along with gaseous inorganic and organic compounds from a top of the HPS and a liquid hydrocarbon from a bottom of the HPS;
c) flashing the liquid hydrocarbon in a low-pressure separator (LPS) to remove dissolved gases and a lighter hydrocarbon fraction having a boiling temperature below 90° C.;
d) processing an LPS effluent in a splitter and separating the LPS effluent into two fractions: i) a top fraction consisting of a hydrocarbon stream having a boiling temperature in a range of 70-140° C., wherein the top fraction is condensed and collected in a reflux drum as a hydrocarbon liquid, and ii) a bottom cut fraction consisting of a hydrocarbon stream having a boiling temperature in a range of 140° C.-340° C.;
e) feeding a portion of the hydrocarbon liquid to the splitter as a reflux stream and recycling the remaining part of the hydrocarbon liquid to the Reactor-1 as a recycle stream;
f) withdrawing a product stream with benzene content less than 1 ppmw from the reflux drum;
g) hydrogenating the bottom cut fraction in a Reactor-2 over a hydrotreating catalyst under hydrogen to obtain a Reactor-2 effluent; and
h) fractionating the Reactor-2 effluent from step g) containing a hydrocarbon stream having a boiling point in a range between 120-340° C. into narrow cuts in a fractionator to obtain de-aromatized distillates, wherein, a topmost cut has an aromatic content below 30 ppm and a bottom most cut has an aromatic content below 1000 ppmw.

2. The process as claimed in claim 1 , wherein the hydrocarbon feedstock comprises streams having boiling temperature in a range of 90° C.-350° C.

3. The process as claimed in claim 1 , wherein the hydrocarbon feedstock has a sulfur content in a range of 0.1-1.5 wt %, and a nitrogen content in a range of 50-1000 ppmw.

4. The process as claimed in claim 1 , wherein the hydrocarbon feedstock has an aromatic content in a range of 5-40 wt %, a di-aromatic content of ≤3 wt %, and a poly-aromatics content of ≤0.001 wt %.

5. The process as claimed in claim 1 , wherein the Reactor-1 is operated at:
a. a weighted average bed temperature (WABT) of catalyst in a range of 250-450° C.;
b. a hydrogen partial pressure in a range of 30-120 kg/cm 2 g;
c. a linear Hourly Space Velocity (LHSV) in a range of 0.2-4 h −1 ; and
d. a hydrocarbon to hydrogen ratio in a range of 300-1200 Nm 3 /m 3 .

6. The process as claimed in claim 1 , wherein the high-pressure separator (HPS) is maintained at a pressure in a range of 35-140 kg/cm 2 g, and at a temperature in a range of 260-350° C.

7. The process as claimed in claim 1 , wherein a top part of the low-pressure separator (LPS) functions as a separator and a bottom part of the low-pressure separator loaded with a hydrogenation catalyst acts as a reactor.

8. The process as claimed in claim 1 , wherein the LPS is operated at a temperature in a range of 150-270° C., at a pressure in a range of 9-27 kg/cm 2 g, and with a residence time in a range of 40-15 minutes.

9. The process as claimed in claim 7 , wherein the hydrogenation catalyst comprises metals selected from nickel, palladium, platinum, or a combination thereof, wherein the metal is supported on an alumina support.

10. The process as claimed in claim 1 , wherein two LPS are provided in a lead lag arrangement.

11. The process as claimed in claim 1 , wherein the top fraction has a boiling temperature in a range of 90-120° C., and a benzene content of ≤20 ppmw, and an aromatic content of ≤30 ppmw.

12. The process as claimed in claim 1 , wherein the bottom cut fraction has a boiling temperature in a range of 120 and 320° C., and a benzene content ≤0.1 ppmw, and an aromatic content ≤2 wt %.

13. The process as claimed in claim 1 , wherein the recycle stream, the reflux stream, and the product stream are in a ratio in a range of 5:7:1-20:7:1.

14. The process as claimed in claim 1 , wherein the benzene content in the product stream of step f) is ≤0.1 ppmw, and the aromatic content is ≤10 ppmw.

15. The process as claimed in claim 1 , wherein the bottom cut fraction of step g) is hydrogenated in the Reactor-2 at a weighted average bed temperature (WABT) in a range of 150-300° C., an average hydrogen partial pressure in a range of 20-75 kg/cm 2 g, a Linear hourly space velocity (LHSV) in a range of 1.5-4 h −1 and a hydrocarbon to hydrogen ratio in a range of 300-1200 Nm 3 /m 3 .

16. The process as claimed in claim 1 , wherein the effluent of the Reactor-2 has an aromatic content of ≤10 ppmw.

17. The process as claimed in claim 1 , wherein the effluent of the Reactor-2 is fractionated into cut-1 and cut-2, wherein the cut-1 has 20 ppmw by UV of aromatics, a boiling point in a range of 130-200° C., and a flash point of at least 50° C., and wherein the cut-2 has 96 ppmw by UV of aromatics, a boiling point in a range of 200-300° C., and a flash point of at least 70° C.

18. The process as claimed in claim 1 , wherein the topmost cut has a boiling temperature in a range of 140-240° C., and an aromatic content of ≤10 ppmw.

19. The process as claimed in claim 1 , wherein the bottom most cut has a boiling temperature in a range of 220-320° C., and an aromatic content of ≤30 ppmw.

Assignees

• Indian Oil Corp Ltd
• Indian Oil Corp Ltd

Inventors

• Hima Bindu Vasamsetty Naga Veera
• Sarkar Mainak
• Butley Ganesh Vitthalrao
• Karumanchi Ramesh
• Kumar Sarvesh
• Sau Madhusudan
• RAMAKUMAR Sankara Sri Venkata

Classifications

• C10G67/14 Primary

  including at least two different refining steps in the absence of hydrogen · CPC title

• B01D3/148

  in combination with at least one evaporator · CPC title

• C10G2300/1048

  Middle distillates · CPC title

• C10G2300/1096

  Aromatics or polyaromatics · CPC title

• C10G2300/202

  Heteroatoms content, i.e. S, N, O, P · CPC title